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The co-crystal of iron(II) complex hydrate with hydroxybenzoic acid: [Fe(Phen)3]Cl(p-hydroxybenzoate).2(p-hydroxybenzoic acid).7H2O

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Crystal of [Fe(Phen)3]Cl(PHB).2(PHBH).7H2O (1) is triclinic, space group P-1 with a = 12.0388(11) Å, b = 15.5286(14) Å, c = 15.7794(14) Å, α = 89.759(2)°, β = 75.818(2)°, γ = 71.900(2)° and Z = 2, (phen = phenanthroline, PHBH = p-hydroxybenzoic acid, PHB = p-hydroxybenzoate anion). The phen in adjacent Fe(phen)3 2+ cations are π–π interacted forming offset face to face (OFF) motifs. Juxtaposition of four phen ligands from two cations encapsulate an R2 2(8) dimeric unit of H-bonded PHBH molecules within a centrosymmetric box froming a filled aryl box motif (FAB). Alternation of OFF and FAB motifs form {OFF⋯FAB}∞ strands. The Fe(phen)3 2+ cation engages its phen ligands in π–π and/or CH–π interactions with two crystalographically different PHBH molecules and one PHB anion. Seven water molecules and a chloride anion per iron(II) trisphenanthroline cation fill empty spaces in the structure forming a hydrophilic cluster. Extensive intermolecular H-bond interactions occur between water molecules, chloride anions, PHBH molecules, and PHB anions. Thermal analysis of (1) was done under N2(g). The TG, and dTG curves revealed the expected mass losses. All associated processes are endothermic as shown in the DSC curve.

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References

  1. Barton, J.K. Science 1986, 233, 727.

    Article  CAS  Google Scholar 

  2. Naing, K.; Takashani, M.; Tanigchi, M.; Yamagishi, A. Inorg. Chem. 1995, 34, 350.

    Article  CAS  Google Scholar 

  3. Zelenko, O.; Gallagher, J.; Sigman, D.S. Angew. Chem. Int. Ed. Engl 1997, 36(24) 2776.

    Article  CAS  Google Scholar 

  4. Sammes, P.C.; Yahioglu, G. Chem. Soc. Rev. 1994, 327.

  5. Sigman, D.; Graham, D.R.; D’Aurora, V.; Stern, A.M. J. Biol. Chem. 1979, 254(12) 269.

    Google Scholar 

  6. Liu, F.; Wang, K.; Bai, G.; Zhang, Y.; Gao, L. Inorg. Chem. 2004, 43, 1799.

    Article  CAS  Google Scholar 

  7. Mie, H.Y.; Barton, J.K. J. Am. Chem. Soc. 1986, 108, 7414.

    Article  Google Scholar 

  8. Zhabotinskii, A.M.; Rovinskii, A.B. Theor. Exp. Chem. 1979, 15, 25.

    Google Scholar 

  9. Noyes, R.M. J. Am. Chem. Soc. 1980, 102, 4644.

    Article  CAS  Google Scholar 

  10. Ganathisubramanian, N.; Noyes, R.M. J. Phys. Chem. 1982, 86, 5158.

    Article  Google Scholar 

  11. Kovalenko, A.S.; Tikhonova, L.P.; Roizman, O.M.; Protopov, E.V. Theor. Exp. Chem. 1980, 16, 46.

    Article  CAS  Google Scholar 

  12. Jwo, J.J.; Noyes, R.M. J. Am. Chem. Soc. 1975, 97, 5422.

    Article  CAS  Google Scholar 

  13. Smoes, M.L. J. Chem. Phys. 1979, 79, 4669.

    Article  Google Scholar 

  14. Shakhashiri, B.Z, Gordon, B.Z. J. Am. Chem. Soc. 1969, 91, 1103.

    Article  CAS  Google Scholar 

  15. Singh, C.M.; Mishra, H.C.; Upadnyyay, R.N. J. Indian chem. Soc. 1979, 56, 835.

    CAS  Google Scholar 

  16. Yatsimirskii, K.B.; Tikhonova, L.P. Coord. Chem. Rev. 1985, 63, 241.

    Article  CAS  Google Scholar 

  17. Beck, M.T. Coord. Chem. Rev. 1968, 3, 91

    Article  CAS  Google Scholar 

  18. Johansson, L. Chem. Scr. 1976, 9, 30

    CAS  Google Scholar 

  19. Johansson, L. Chem. Scr. 1976, 10, 72

    CAS  Google Scholar 

  20. Johansson, L. Chem. Scr. 1976, 10, 149

    CAS  Google Scholar 

  21. Deng, R.M.K.; Simon, S.; Dillon, K.B.; Goeta, A.E. Acta Cryst. 2001, C57, 4.

    CAS  Google Scholar 

  22. Johansson, L.; Molund, M.; Oskarsson, A. Inorg. Chim. Acta 1978, 31, 117.

    Article  CAS  Google Scholar 

  23. Baker, J.; Engelhardt, L.M.; Figgis, B.N.; White, A.H. J. C. S. Dalton 1975, 530.

  24. Russell, V.; Scudder, M.; Dance, I. J. Chem. Soc., Dalton Trans. 2001, 789.

  25. Fujiwara, T.; Iwamoto, E.; Yamamoto, Y. Inorg. Chem. 1984, 23, 115,

    Article  CAS  Google Scholar 

  26. Dance, I.G. The Crystal as a Supramolecular Entity ed. G.R. Desiraju, John Willey, New York, 1996; pp 137–333.

  27. Horn, C.; Scudder, M.L.; Dance, I.G. Cryst Eng Comm 2000, 2(36) 196.

    Google Scholar 

  28. Koh, L.L.; Xu, Y.; Hsieh, A.K.; Song, B.; Wu, F.; Ji, L. Acta Cryst. 1994, C50, 884.

    CAS  Google Scholar 

  29. Zalkin, A.; Templeton, D.H.; Ueki, T. Inorg. Chem. 1973, 12, 1641.

    Article  CAS  Google Scholar 

  30. Li, J.; Wei, J.; Wu, X.; Zhu, N.; Zhang, Y. Cryst. Res. Technol. 1993, 28, 11.

    Article  CAS  Google Scholar 

  31. Han, Q.; Jian, F.; Lu, L.; Yang, X.; Wang, X. J. Coord. Chem. 2002, 55(6) 633.

    Article  CAS  Google Scholar 

  32. Boys, D.; Escobar, C.; Wittke, O. Acta Cryst. 1984, C40, 1359.

    CAS  Google Scholar 

  33. Anderson, P.O. J. Chem. Soc., Dalton Trans. 1973, 1237.

  34. Deacon, G.B.; Raston, C.L.; Tunaley, D.; White, A.H. Aust. J. Chem. 1979, 32, 2195.

    Article  CAS  Google Scholar 

  35. Goodwin, H.A.; Kepert, D.L.; Patrick, J.M.; Skelton, B.W.; White, A.H. Aust. J. Chem. 1984, 34, 1817.

    Article  Google Scholar 

  36. Rund, J.V. Acta Cryst. 1980, B36, 3103.

    CAS  Google Scholar 

  37. Li, J.; Wei, J.; Wu, X.; Zhu, N.; Zhang, Y. Cryst. Res. Technol. 1993, 28, 11.

    Article  CAS  Google Scholar 

  38. Jorgensen, W.L.; Severance, D.L. J. Am. Chem. Soc. 1990, 112, 4768.

    Article  CAS  Google Scholar 

  39. Janiak, C. J. Chem. Soc., Dalton Trans. 2000, 3885.

  40. Claessens, C.G.; Stoddart, J.F. J. Phys. Org. Chem. 1997, 10, 254.

    Article  CAS  Google Scholar 

  41. Kabbani, A.T.; Zaworotko, M.J.; Abourahma, H.; Walsh, R.D.; Hammud, H.H. J. Chem. Crystallogr. 2004, 34(11) 749.

    Article  CAS  Google Scholar 

  42. Horn, C.; Dance, I.G.; Scudder, M.I. Cryst Eng Comm. 2001, 3(2), 9.

    Google Scholar 

  43. Horn, C.; Berben, L.; Chow, H.; Scudder, M.I.; Dance, I.G. Cryst Eng Comm. 2002, 4(2), 7.

    Google Scholar 

  44. Sundholm, D.; Sundberg, M.R.; Uggla, R. J. Phys. Chem. A. 1998, 102(36), 7137.

    Article  CAS  Google Scholar 

  45. Suezawa, H.; Hashimoto, T.; Tsuchinaga, K.; Yuzuri, T.; Sakakibara, K.; Hirota, M.; Nishio, M. J. Chem. Soc., Perkin Trans. 2000, 2, 1243.

    Google Scholar 

  46. Umezawa, Y.; Tsuboyama, S.; Honda, K.; Uzawa, J.; Nishio, M.; Bull. Chem. Soc. Jpn. 1998, 71, 1207.

    Article  CAS  Google Scholar 

  47. Takahashi, O.; kohomo, Y.; Iwasaki, S.; Saito, K.; Iwaoka, M.; Tomoda, S.; Umezawa, Y.; Tsuboyama, S.; Nishio, M. Bull. Chem. Soc. Jpn. 2001, 74, 2421

    Article  CAS  Google Scholar 

  48. Suezawa, H.; Yoshida, T.; Umezawa, Y.; Tsuboyama, S.; Nishio, M. Eur. J. Inorg. Chem. 2002, 3148.

  49. Steiner, T.; Desiraju, G.R. Chem. Commun. 1998, 891.

  50. Dubler, E.; Haring, U.K; Scheller, H.; Baltzer, P.; Sigel, H. Inorg. Chem. 1984, 23, 3785.

    Article  CAS  Google Scholar 

  51. Bogdanovic, G.A.; Spasojevic-de Brie, A.; Zaric, S.D. Eur. J. Inorg. Chem. 2002, 1599.

  52. Nishio, M. Cryst Eng Comm 2004, 6(27), 130.

    CAS  Google Scholar 

  53. Tsuzuki, S.; Honda, K.; Uchimaru, T.; Mikami, M.; Tanabe, K. J. Am. Chem. Soc. 2002, 124, 104.

    Article  CAS  Google Scholar 

  54. Grover, J.R.; Walters, E.A.; Hui, E.T. J. Phys. Chem. 1987 91, 3233.

    Article  CAS  Google Scholar 

  55. Lehn, J.-M. Supramolecular Chemistry: Concept and Perspectives; VCH: Weinheim, 1995; pp 89–135.

    Google Scholar 

  56. Glidewell, C.; Howie, R.A.; Low, J.N.; Skakle, J.M.S.; Wardell, S.V.; Wardell, J.L. Acta Crystallogr. 2002, B58, 864.

    CAS  Google Scholar 

  57. Tong, M-L.; Li, W.; Chen, X-M.; Zheng, S-L.; Ng, S.W. Acta Crystallogr. 2002, C58, m232.

    CAS  Google Scholar 

  58. Garden, S.J.; Fontes, S.P.; Wardell, J.L.; Skakle, J.M.S.; Low, J.N.; Glidewell, C. Acta Crystallogr. 2002, B58, 701.

    CAS  Google Scholar 

  59. Hartshorn, C.M.; Steel, P. J. Inorg. Chem. 1996, 35, 6902.

    Article  CAS  Google Scholar 

  60. Cozzi, F; Siegel, J.S. Pure Appl. Chem. 1995, 67, 683.

    CAS  Google Scholar 

  61. Horn, C.; Ali, B.F.; Dance, I.G.; Scudder, M.L.; Craig, D.C. Cryst Eng Comm. 2000, 2, 6.

    Google Scholar 

  62. Lindsey, J.S. New. J. Chem. 1991, 15, 153.

    CAS  Google Scholar 

  63. Braga, D.; Grepioni, F.; Desiraju, G.R. Chem. Rev. 1998, 98, 1375.

    Article  CAS  Google Scholar 

  64. Konig, E.; Ritter, G.; Kulshreshia, S.K. Chem. Rev. 1985, 85, 219.

    Article  CAS  Google Scholar 

  65. Konig, E. Prog. Inorg. Chem. 1987, 35, 527.

    Google Scholar 

  66. Kamalakshmi, D.; Reddy, K.R.N.; Padmavathy, D.; Rajasekharam, M.V.; Arulsamy, N.; Hodgson, D.J. Inorg. Chim. Acta 1999, 284, 158.

    Article  Google Scholar 

  67. George, T.A.; Hammud, H.H.; Isber, S. Poyhedron 2006, 25, 2721.

    Article  CAS  Google Scholar 

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Acknowledgment

Thanks to University of South Florida, Tampa for X-ray facilities.

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Authors and Affiliations

  1. Department of Chemistry, University of South Florida, Tampa, Florida, 33620, USA

    Michael J. Zaworotko

  2. Chemistry Department, Beirut Arab University, Beirut, 11-5020, Lebanon

    Hassan H. Hammud

  3. Institute of Applied Physics, Academy of Sciences of Moldova, Kishinev, MD, 2028, Moldova

    Victor Ch. Kravtsov

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  1. Michael J. Zaworotko
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Correspondence to Hassan H. Hammud.

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Supplementary Material

CCDC-281055 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK.

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Zaworotko, M.J., Hammud, H.H. & Kravtsov, V.C. The co-crystal of iron(II) complex hydrate with hydroxybenzoic acid: [Fe(Phen)3]Cl(p-hydroxybenzoate).2(p-hydroxybenzoic acid).7H2O. J Chem Crystallogr 37, 219–231 (2007). https://doi.org/10.1007/s10870-006-9174-5

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