Four phosphonium rhenates(VII) were prepared and crystallized: (A) 1,2-bis (triphenylphosphonium)ethane rhenate(VII) (Pī, a=8.298(2), b=10.638(3), c= 11.242(3) Å, α=64.96(2), β=80.49(2), γ=88.17(2)°), (B) methyltriphenylphosphonium rhenate(VII) (Pca21, a=15.096(3), b=12.627(3), c=19.353(3) Å), (C) benzyltriphenylphosphonium rhenate(VII) (Pī, a=9.648(2), b=11.689(2), c=20.806(3) Å, α=88.44(2), β=84.63(2), γ=77.33(3)°), and (D) orthorhombic form of (iodomethyl)triphenylphosphonium rhenate(VII) (Pca21, a=14.952(3), b=13.120(3), c=20.603(4) Å). Each crystal structure consists of separate phosphonium cations and rhenate(VII) anions. In A centrosymmetric 1,2-bis(triphenylphosphonium)ethane cations form layers perpendicular to [011]. In B the cations are set in chains along [100] forming layers perpendicular to [001]. In C two symmetrically-independent cations form double columns along [100] and these columns are arranged in puckered layers perpendicular to [001]. D is almost isomorphous to B. The crystal structures are stabilised by weak C–H⋯O hydrogen bonds as well as phenyl rings interactions. In all crystal structures supramolecular motifs of phenyl rings embraces could be distinguished.
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Crystallographic data for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-294810; CCDC-294811; CCDC-29812; CCDC-294813. Copies of available material can be obtained, free of charge, on application to the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK, (fax: +44-(0) 1223-336033 or e-mail: deposit@ccdc.cam.ac.uk).
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Hołyńska, M., Lis, T. Structure of phosphonium rhenates(VII). J Chem Crystallogr 37, 275–284 (2007). https://doi.org/10.1007/s10870-006-9172-7
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DOI: https://doi.org/10.1007/s10870-006-9172-7