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Synthesis and structure of chiral ligand [(S)-1-(((S)-1-methylpyrrolidin-2-yl) methyl) pyrrolidin-2-yl] diphenylmethanol

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The title compound (C23H30N2O), a chiral ligand, has been successfully synthesized from a natural proline. FTIR spectrum has been discussed. DFT (B3LYP) method has been used to determine the structure. With the basis set of the 6–311G* quality, the DFT calculated bond parameters and harmonic vibrations are predicted in very good agreement with experimental data.

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Scheme 1
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Notes

  1. The crystallographic information file is deposited with the Combridge Crystallographic Data Center as CCDC 232207.

References

  1. (a) Ciril, J.; Mirela, P.; Antoni, R.; Miquel P. J. Org. Chem. 2003, 68, 3130–3138. (b) Joshi, S. N.; Malhotra S. V. Tetrahedron: Asymmetry 2003, 14, 1763–1766. (c) Alexander, J. A.; Marson, C.M. Tetrahedron: Asymmetry 2001, 12, 1547–1550.

  2. Corey, E.J.; Hannon, F.J. Tetrahedron Lett. 1987, 28, 44, 5233–5236.

    Article  Google Scholar 

  3. Lait, S.M.; Parvez, M.; Keay B.A. Tetrahedron: Asymmetry 2003, 14, 749–756.

    Article  CAS  Google Scholar 

  4. Izumi, W.; Yuko, T.; Yasuhiro, K. Tetrahedron 2002, 58, 8095–8097.

    Article  Google Scholar 

  5. Tang, Z.; Jiang, F.; Gong, L.Z.; Jiang, Y.Z. J. Am. Chem. Soc. 2003, 125, 5262–5263.

    Article  CAS  Google Scholar 

  6. Michel, P.; Christian, B.; Remy, T. Fr. Demande FR 2750334 A1 2 Jan 1998, p. 15

  7. Kanthb, J.V.; Perisasamy, M. Tetrahedron 1993, 49, 5127–5132.

    Article  Google Scholar 

  8. Frisch, M.J., Trucks, G.W., Schlege, H.B., et al., GAUSSIAN 98, Rev. A. 6 PA, 1998.

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Authors and Affiliations

  1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, 1 Shizi St. Suzhou, Suzhou, Jiangsu, 215006, P. R. China

    Qiu Li-Hua, Zhou Wei-Qun, Shen Zong-Xuan & Zhang Ya-Wen

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  1. Qiu Li-Hua
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  2. Zhou Wei-Qun
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  3. Shen Zong-Xuan
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  4. Zhang Ya-Wen
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Correspondence to Zhou Wei-Qun.

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Li-Hua, Q., Wei-Qun, Z., Zong-Xuan, S. et al. Synthesis and structure of chiral ligand [(S)-1-(((S)-1-methylpyrrolidin-2-yl) methyl) pyrrolidin-2-yl] diphenylmethanol. J Chem Crystallogr 37, 181–186 (2007). https://doi.org/10.1007/s10870-006-9130-4

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  • DOI: https://doi.org/10.1007/s10870-006-9130-4

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