The solution-phase reaction of a metal iodide with 1, 3-bis(4-pyridyl)propane (bpp) yields a new organic-inorganic hybrid framework, [(CuI2)2(N,N-dimethyl-bpp)] n (1), which is made up of organic cations [dimethyl-bpp]2+ and an infinite [Cu2I4] n 2− anion chain; The cluster 1 obtained via the reaction between polyiodide complexes and organic N-donor ligand suggests that this simple synthetic approach is likely to be applicable to the construction of polymeric clusters.
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This research was funded by the Henan Province Excellent Young Foundation(No. 0612002800) and the China Postdoctoral Science Foundation(2003033525).
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CCDC-253123 contains the crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html [or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: +44-1223-336-033; E-mail: deposit@ccdc.cam.ac.uk].
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Jiao, X., Niu, Y., Zhang, H. et al. Reactivity of polyiodide toward 1, 3-bis(4-pyridyl)propane (bpp): synthesis and structure of an organic-inorganic hybrid compound [(CuI2)2(N,N′-dimethyl-bpp)] n . J Chem Crystallogr 36, 685–689 (2006). https://doi.org/10.1007/s10870-006-9118-0
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DOI: https://doi.org/10.1007/s10870-006-9118-0