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Crystal structures of two monoamine-coordinated zinc complexes obtained via solid-vapor reaction

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The solid-vapor reaction properties of [Zn(p-NH2C6H4SO3)2(H2O)2] n and alkyl monoamines were investigated. Two of the resulting complexes, [Zn(C2H5NH2)4](p-H2NC6H4 SO3)2 and [Zn(n-C3H7NH2)4](p-H2NC6H4SO3)2, grew into single crystals in situ during the solid-vapor reaction process and their structures were characterized by single-crystal structural analysis.

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Acknowledgements

We thank the financial support from the National Natural Sciences Foundation of China (Grant No. 20271053).

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Correspondence to Jiwen Cai.

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Crystallographic data for [Zn(C2H5NH2)4] (p-H2NC6H4SO3)2 and [Zn(n-C3H7NH2)4](p-H2NC6H4SO3)2 have been deposited with the Cambridge Crystallographic Data Center as supplementary publication number CCDC 295597 and CCDC 295598. Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44(0)-1223-336033 or e-mail: Deposit@ccdc.cam.ac.uk).

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Liu, P., Lian, ZX. & Cai, J. Crystal structures of two monoamine-coordinated zinc complexes obtained via solid-vapor reaction. J Chem Crystallogr 36, 673–678 (2006). https://doi.org/10.1007/s10870-006-9116-2

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  • DOI: https://doi.org/10.1007/s10870-006-9116-2

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