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Synthesis and crystal structures of two new complexes [M(OH2)(HDPA)2]·3H2O (M = Mn, Co)

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Two new transition metal complexes of [M(OH2)(HDPA)2]·3H2O (M=Mn(1); M=Co(2)) (H2DPA, 2,6-pyridine-dicarboxylic acid) have been prepared at room temperature from the reaction of MCl2·6H2O (M=Mn or Co) and H2DPA in the mixed solvent of H2O and EtOH in the presence of piperazine, and were characterized by X-ray analysis, elemental analysis. X-ray analysis reveals that the coordination geometries of Mn2+ and Co2+ are of octahedron and severely distorted square-based pyramid, respectively. Crystal data: [Mn(OH2)(HDPA)2]·3H2O (1), Mr=459.23, monoclinic, P2(1)/n, a=7.0056(3), b=(23.8125(12), c=10.7444(3) Å, β=99.834(2)°, Z=4, V=1766.28(13) Å3, R 1=0.0586, wR 2=0.1448 [I>2σ(I)]; Co(OH2)(HDPA)2]·3H2O (2), Mr=463.22, monoclinic, P2(1)/n, a=7.0014(2), b=23.8346(7), c=10.7212(4) Å, β=99.8540(10)°, Z=4, V=1762.71(10) Å3, R 1=0.0474, wR 2=0.1366 [I>2σ(I)].

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References

  1. Poowell, J.F. Biochemistry 1953, 54, 205–207.

    Google Scholar 

  2. Pocker, Y.; Fong, C.T.O. Biochemistry 1980, 16, 2045–2049.

    Article  Google Scholar 

  3. Scapin, G.; Reddy, S.G.; Zheng, R.; Blanchard, J.S. Biochemstry. 1997, 36, 15081–15092.

    Article  CAS  Google Scholar 

  4. Scapin, G.; Reddy, S.G.; Zheng, R.; Blanchard, J.S. J. Am. Chem. Soc. 2000, 122, 11692–11702.

    Google Scholar 

  5. Scapin, G.; Reddy, S.G.; Zheng, R.; Blanchard, J.S. Cryst. Growth Des. 2004, 4, 1203–1209.

    Google Scholar 

  6. Scapin, G.; Reddy, S.G.; Zheng, R.; Blanchard, J.S. Chem. Mater. 2004, 16, 4916–4927.

    Google Scholar 

  7. Church, B.S.; Halvorson, H. Nature 1959, 183, 124–125.

    Article  CAS  Google Scholar 

  8. Kim, Y.; Lee, E.; Jung, D.Y. Chem. Mater. 2001, 13, 2684–2696.

    Article  CAS  Google Scholar 

  9. Ma, C.B.; Chen, C.N.; Liu, Q.T.; Liao, D.Z.; Li, L.C. Eur. J. Inorg. Chem. 2003, 1227–1231.

  10. Macdonald, J.C.; Tzy-Jiun, M.Luo; Palmore, G.T.R. Cryst. Growth Des. 2004, 4, 1203–1207.

    Article  CAS  Google Scholar 

  11. Ma, C.B.; Fan, C.; Chen, C.N.; Liu, Q.T. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2002, 58, m553.

    Article  Google Scholar 

  12. Xie, C.Z.; Zhang, Z.F.; Liu, X.W.; Wang, X.Q.; Kou, H.Z.; Shen, G.Q.; Shen, D.Z. Inorg. Chem. Commun. 2004, 7, 1037–1041.

    Article  CAS  Google Scholar 

  13. Yang, L.Q.; Crans, D.C.; Miller, S.M.; la Cour, A.; Anderson, O.P.; Kaszynski, P.M. Inorg. Chem. 2002, 41, 4859–4871.

    Article  CAS  Google Scholar 

  14. Mogjimi, A.; Ranjbar, M.; Aghabozorg, H.; Jalali, F.; Shamsipur, M.; Chadha, K.K. Can. J. Chem. 2002, 80, 1687–1692.

    Article  Google Scholar 

  15. Tong, M.L.; Hung, K.L.; Chen, X.M.; Huang, R.B.; Thomas, C.W.M. J. Chem. Soc., Dalton Trans. 1999, 3657–3569.

  16. Macdonald, J.C.; Tzy-Jiun, M.L.; Palmore, G.T.R. Cryst. Growth Des. 2004, 4, 1203–1205.

    Article  CAS  Google Scholar 

  17. Hunter, C.A.; Sanders, J.K.M. J. Am. Chem. Soc. 1990, 112, 5525–5527.

    Article  CAS  Google Scholar 

  18. Deverreux, M.; Mccan, M.; Leon, V.; Mckee, V.; Ball, R.J. Polyhedron 2002, 21, 1063.

    Article  Google Scholar 

  19. Ma, C.B.; Chen, C.N.; Chen, F.; Hang, X.F.; Zhu, H.P.; Liu, Q.T.; Liao, D.Z.; Li, L.C. Bull. Chem. Soc. Jpn. 2003, 76, 301–307.

    Article  CAS  Google Scholar 

  20. Limburg, J.; Brudvig, G.W.; Crabtree, R.H. J. Am. Chem. Soc. 1997, 119, 2761–2762.

    Article  CAS  Google Scholar 

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Acknowledgments

The work was supported by the financial support of Liaocheng University (31801) and Professor Jianmin Dou

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  1. Department of Chemistry, Liaocheng University, Liaocheng, P. R. China

    Ying Liu, Jianmin Dou, Daqi Wang, Dacheng Li & Zhaoping Gao

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  1. Ying Liu
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Correspondence to Ying Liu.

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Liu, Y., Dou, J., Wang, D. et al. Synthesis and crystal structures of two new complexes [M(OH2)(HDPA)2]·3H2O (M = Mn, Co). J Chem Crystallogr 36, 613–618 (2006). https://doi.org/10.1007/s10870-006-9079-3

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