Aimed at the analysis of hydrogen bond interactions, the molecular structure of biphenyl-2, 2′-dimethanol (C14H14O2) has been determined by X-ray crystallographic techniques. The compound crystallizes in the monoclinic space group P21/n with unit cell parameters: a =12.811(4) Å, b=5.009(4) Å, c=18.591(14) Å, and β=109.24(5)°, Z=4, V=1126.3(13) Å3. The magnitude of the interring torsion angle is 87.5°. There are O–H\(\cdots \)O and C–H\(\cdots \)π interactions which leads the structure to architectural supramolecular synthon.
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Rajnikant Verma is thankful to Dr. Sandeep Kumar, senior scientist, Raman Research Institute, Bangalore, for making the sample available through Aldrich Chemical Company. The Department of Science and Technology, Government of India is acknowledged for providing funding under a sponsored research project no. SR/S2/CMP-47/2003.
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Supplementary material CCDC 283068 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk@data_request/cif or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, United Kingdom; Fax: +44-1223-336033; e-mail: data_request@ccdc.cam.ac.uk.
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Rajnikant, Dinesh, Sharma, B. et al. Analysis of O–H\(\cdots \)O and C–H\(\cdots \)π interactions in biphenyl-2,2′-dimethanol: a supramolecular structure. J Chem Crystallogr 36, 331–336 (2006). https://doi.org/10.1007/s10870-006-9068-6
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DOI: https://doi.org/10.1007/s10870-006-9068-6