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Synthesis and crystal structure of cyanohydrin trimethylsilyl ether of o-chlorobenzoylferrocene

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The cyanohydrin trimethylsilyl ether of o-chlorobenzoylferrocene has been synthesized by the addition of trimethylsilyl cyanide (TMSCN) in methylene chloride in the presence of zinc iodide. Its structure was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic, space group P21/n with the following crystallographic parameters: a = 9.480(3) Å, b = 22.319(6) Å, c = 9.783(3) Å, β = 101.197(4)°, μ = 0.943 mm − 1, V=2030.5(10) Å3, Z=4, F(0 0 0) = 880, D calc=1.386 mg/m3, T=293(2) K, 1.82° ≤ θ ≤ 26.40°, the final R factor: R 1=0.0366, wR 2=0.0802.

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Acknowledgment

Financial support from the National Natural Science Foundation of China (Grant no. 20062004) is gratefully acknowledged.

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  1. College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot, 010021,, P.R. China

    Hai-Ying Zhao, Zhan-Xi Bian & Bao-Guo Li

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  1. Hai-Ying Zhao
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  2. Zhan-Xi Bian
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  3. Bao-Guo Li
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Correspondence to Zhan-Xi Bian.

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Zhao, HY., Bian, ZX. & Li, BG. Synthesis and crystal structure of cyanohydrin trimethylsilyl ether of o-chlorobenzoylferrocene. J Chem Crystallogr 36, 413–417 (2006). https://doi.org/10.1007/s10870-005-9037-5

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