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A new family of energetic ionic liquids 1-amino-3-alkyl-1,2,3-triazolium nitrates

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A new class of energetic ionic liquids based upon 1-amino-3-alkyl-1,2,3-triazolium nitrates (alkyl = methyl, ethyl, n-propyl, 2-propenyl, and n-butyl) has been synthesized and characterized by vibrational spectra, multinuclear NMR, elemental as well as contaminant analyses, and DSC studies. A single crystal X-ray study was carried out for 1-amino-3-methyl-1,2,3-triazolium nitrate and the details will be presented.

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Scheme 1.
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Acknowledgments

The authors would like to thank Michael Berman (AFOSR) and Michael Huggins (AFRL/PRS), Ronald Channell (AFRL/PRSP) and Wayne Kalliomaa (AFRL/PRSP) as well as Dr. George Schmidt (XD20/NASA MSFC) and Dr. Charles Schafer (XD20/NASA MSFC) for financial support and encouragement of this work

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Authors and Affiliations

  1. ER22 Propulsion Research Center, George Marshall Space Flight Center, Alabama, USA

    Gregory Drake

  2. ERC, Inc., Huntsville, USA

    Greg Kaplan

  3. AFRL/PRSP, Space and Missile Division, Propulsion Directorate, Air Force Research Laboratory, Edwards Air Force Base, California, 93524, USA

    Greg Kaplan, Leslie Hall, Tommy Hawkins & Joann Larue

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  1. Gregory Drake
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Drake, G., Kaplan, G., Hall, L. et al. A new family of energetic ionic liquids 1-amino-3-alkyl-1,2,3-triazolium nitrates. J Chem Crystallogr 37, 15–23 (2007). https://doi.org/10.1007/s10870-005-9021-0

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  • DOI: https://doi.org/10.1007/s10870-005-9021-0

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