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Synthesis and crystal structure of a new composite complex between a hepta-coordinate ytterbium(III) and a heteropoly molybdic anion: [Yb(DMSO)7]H[SiMo12O40] (DMSO = dimethyl sulfoxide)

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Abstract

A new composite complex of the general formula [Yb(DMSO)7]H[SiMo12O40] has been synthesized from H4SiMo12O40⋅nH2O, YbCl3 and DMSO in mixed solvent of acetonitrile and water and characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. Singe crystal X-ray structure analysis shows that it belongs to monoclinic system, space group P21/c, with a = 11.685(2) Å, b = 14.969(3) Å, c = 35.037(7) Å, β = 98.50(3)∘, and Z = 4. There is one [Yb(DMSO)7]3+ coordinated cation and one [SiMo12O40]4− polyanion in one structure unit. The organic ligands (DMSO) do coordinate directly with ytterbium(III) to form a distorted pentagonal bipyramid complex ion by coordination bond, then combines to the SiMo12O404− anion by static electric force. The results of IR and X-ray diffraction show that there is strong interaction between polyoxometalate and organic donors.

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References

  1. (a) Pope, M.T. Heteropoly and Iso poly Oxometalates; Springer-Verlag: Berlin, 1983

    Google Scholar 

  2. (b) Luo, Q.H.; Howell, R.C.; Dankova, M.; Bartis, J. Inorg. Chem. 2001, 40, 1894.

    Article  PubMed  Google Scholar 

  3. Hill, C.L.; Guest Ed. Chem. Rev. 1998, 98, 1–389.

    Article  PubMed  Google Scholar 

  4. Attanasio, D.; Bellitto, C.; Bonamico, M.; Fares, V.; Patrizo, S. Synth. Met. 1991, 41, 2289.

    Article  Google Scholar 

  5. Coronado, E.; Gomez-Garcia, C. J. Chem. Rev. 1998, 98, 273.

    Article  Google Scholar 

  6. Niu, J.Y.; You, X.Z.; Duan, C.Y.; Fun, H.K.; Zhou, Z.Y. Inorg. Chem. 1996, 14, 4211.

    Article  Google Scholar 

  7. Niu, J.Y.; Wang, J.P.; Chen, W.; Kennard, C.H.L.; Byriel, K. A. J. Coord. Chem. 2001, 53, 153.

    Google Scholar 

  8. Niu, J.Y.; Wang, J.P.; Thomas, C.W.; Zhou, Z.Y.; You, X.Z. Polyhedron 1996, 22, 3963.

    Google Scholar 

  9. Niu, J.Y.; Wu, Q.; Wang, J.P. J. Chem. Soc., Dalton Trans. 2002, 2512.

  10. Wang, J.P.; Wu, Q.; Niu, J.Y. Sci. China (B) 2002, 32, 210.

    Google Scholar 

  11. Siedle, A.R.; Newmark, R.A.; Lyon, P.A.; Hunt, S.L.; Day, V.W. Inorg. Chim. Acta. 1997, 259, 241.

    Article  Google Scholar 

  12. You, W.S.; Wang, E.B.; Xu, Y.; Li, Y.G.; Xu, L.; Hu, C.W. Inorg. Chem. 2001, 40, 5468.

    Article  PubMed  Google Scholar 

  13. Xi, X.D.; Wang, G.; Liu, B.F.; Dong, S.J. Electrochem. Acta. 1995, 40, 1025.

    Article  Google Scholar 

  14. Gall, P.; Gautier, R.; Halet, J.F.; Gougeon, P. Inorg. Chem. 1999, 38, 4455.

    Article  PubMed  Google Scholar 

  15. Pope, M.T.; Sadakane, M.; Dickman, M.H. Angew. Chem., Int. Ed. 2000, 39, 2914.

    Google Scholar 

  16. Cao, R.; Sun, D.F.; Liang, Y.C.; Hong, M.C.; Tatsumi, K.; Shi, Q. Inorg. Chem. 2002, 41, 2087.

    Article  PubMed  Google Scholar 

  17. Wang, J.P.; Han, Q.X.; Niu, J.Y. Acta Chim. Sinia. 2002, 60, 1445.

    Google Scholar 

  18. Rocchiccioli-Deltcheer, C.; Fournier, M.; Franck, R.; Thouvenot, R. Inorg. Chem. 1983, 22, 207.

    Article  Google Scholar 

  19. G.M.Sheldrick, SHELXL-93, Program for the Refinement Crystal Structures, University of Gottingen, Germany, 1993.

    Google Scholar 

  20. Keggin, J.F. Nature 1933, 131, 908.

    Google Scholar 

  21. Gu, Y.D.; Ding, J.P. Chem. J. Chin. Universities 1990, 11, 115.

    Google Scholar 

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475001, P. R. China

    Jing-Ping Wang, Qiu-Xia Han & Jing-Yang Niu

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  1. Jing-Ping Wang
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  2. Qiu-Xia Han
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  3. Jing-Yang Niu
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Correspondence to Jing-Yang Niu.

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Wang, JP., Han, QX. & Niu, JY. Synthesis and crystal structure of a new composite complex between a hepta-coordinate ytterbium(III) and a heteropoly molybdic anion: [Yb(DMSO)7]H[SiMo12O40] (DMSO = dimethyl sulfoxide). J Chem Crystallogr 35, 629–634 (2005). https://doi.org/10.1007/s10870-005-6160-2

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  • DOI: https://doi.org/10.1007/s10870-005-6160-2

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