Skip to main content
SpringerLink
Log in

Crystal structure of a novel inner salt 4-guanidino-2-hydroxybenzoic acid

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The guanidinium compound 4-guanidino-2-hydroxybenzoic acid, crystallizes in the orthorhombic space group Pbac with a = 8.090(2) Å, b = 12.470(3) Å, c = 16.430(3) Å, and Φcalc = 1.564 Mg/m3 for Z = 8. The three-dimensional network is constructed through hydrogen bonds, electrostatic interactions and weak π–π stacking interaction among the guanidinium, carboxyl and hydroxy groups in the title compound.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yamamoto, Y.; Kojima, S. In Synthesis and Chemistry of Guanidine Derivatives; Patai, S.; Rappoport, Z., Eds.; John Wiley & Sons Ltd.: New York, 1991; Vol. 2, pp. 485–526.

    Google Scholar 

  2. Ohtani, I.; Kusumi, T.; Kakisawa, Y.; Hirsh, S. J. Am. Chem. Soc. 1992, 114, 8472–8479.

    Article  Google Scholar 

  3. Rama Rao, A.V.; Gurjar, M.K.; Islam, A. Tatrahedron Lett. 1993, 34, 4993–4996.

    Article  Google Scholar 

  4. Murphy, P.J.; Williams, H.L.; Hibbs. D.E.; Hursthouse, M.B.; Malik, K.M.A. Tetrahedron. 1996, 52, 8315–8332.

    Article  Google Scholar 

  5. Kinnel, R.B.; Gehrken, H.P.; Swali, R.; Skoropowski, G.; Scheure, P.J. J. Org. Chem. 1998, 63, 3281–3286.

    Article  Google Scholar 

  6. Brendan, P. Orner; Andrew, D. Hamilton. J. Incl. Phenom. Macro. Chem. 2001, 41, 141–147.

    Article  Google Scholar 

  7. Feichtinger, K.; Zapf, C.; Coodman, M. J. Org. Chem. 1998, 63, 3804–3805.

    Article  Google Scholar 

  8. Maryanoff, C.A.; Stanzione, R.C.; Plampin, J.N.; Mill, J.E. J. Org. Chem. 1986, 51, 1882–1884.

    Article  Google Scholar 

  9. Kim, K.; Lin, Y.T.; Mosher, H.S. Tetrahedron. 1988, 29, 3183–3186.

    Article  Google Scholar 

  10. Sheldrick, G.M. SHELXL 93, Program for Crystal Structure Refinement; University of Göttingen: Germany, 1993.

    Google Scholar 

  11. SHELXTL (version 5.03), Siemens Industrial Automation, Analytical Instruments: Madison, WI. 1995.

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, School of Science, Nanjing University of Technology, Nanjing, China

    Changmei Wei, Yueling Zhang, Hongjun Zhu & Jintang Wang

  2. Department of Chemistry, Huaiyin Teacher’s College, Huaian, Jiangsu, China

    Changmei Wei

Authors
  1. Changmei Wei
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yueling Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hongjun Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jintang Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jintang Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wei, C., Zhang, Y., Zhu, H. et al. Crystal structure of a novel inner salt 4-guanidino-2-hydroxybenzoic acid. J Chem Crystallogr 35, 561–564 (2005). https://doi.org/10.1007/s10870-005-5384-5

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-005-5384-5

Keywords

Search

Navigation