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Structure and magnetic properties of a dinuclear complex [Cu2(TPA)2(o-phth)](ClO4)2

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Abstract

A new dinuclear complex, [Cu2(TPA)2(o-phth)](ClO4)2 (TPA = tris(2-pyridylmethyl) amine, o-phth = terephthalato dianion), was synthesized and characterized by X-ray crystallography. The unit of dinuclear Cu(II) was bridged by terephthalato dianion. The complex crystallizes in triclinic space group P1, with a = 8.287(3) Å, b = 10.623(4) Å, c = 13.818(5) Å; α = 92.077(7)∘, β = 94.768(7)∘, γ = 90.352(6)∘; V = 1211.4(8) Å3; Z = 2; R1 = 0.0604, wR2 = 0.1707. In the temperature range 4–300 K, magnetic measurement shows that the exchange interaction of the two metal ions is weak ferromagnetic with J = 1.20 cm−1, g = 1.97.

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References

  1. Irene, M.B.; Francois, L.; Jean, P. R.; Michele, C; Marechal, J.D.; Maseras, F. Inorg. Chim. Acta. 2000, 297, 338.

    Article  Google Scholar 

  2. Kazu, S.S.; Seiji O.; Shu, H.F.; Hideki, H.; Masatatsu, S.; Akira U.; Yoshihito, W. J. Am. Chem. Soc. 2000, 122, 254.

    Article  Google Scholar 

  3. Zang, Y.; Kim, J.H.; Dong, Y.H.; Wilkinson, E.C.; Appelman, E.H.; Que, L. J. Am. Chem. Soc. 1997, 119, 4197.

    Article  Google Scholar 

  4. Schatz, M.; Becker, M.; Walte, O.; Liehr, G.; Schindler, S. Inorg. Chim. Acta. 2001, 324, 173.

    Article  Google Scholar 

  5. Parker, R.J.; Spiccia, L.; Moubaraki, B.; Murray, K.S.; Skelton, B.W.; White, A.H. Inorg. Chim. Acta. 2000, 300, 922.

    Article  Google Scholar 

  6. He, Z.C.; Chaimungkalanont, P.J.; Craig, D.C.; Stephen, B.; Colbran, J. Chem. Soc. Dalton Trans. 2000, 1419.

  7. Tyeklár, Z.; Jacobson, R.R.; Wei, N.; Muzthy, N.N. J. Am. Chem. Soc. 1993, 115, 2677.

    Article  Google Scholar 

  8. Jacobson, R.R.; Tyeklar, Z.; Farooq, A.; Karlin, K.D.; Liu, S.C.; Zubieta, J. J. Am. Chem. Soc. 1988, 110, 3690.

    Article  Google Scholar 

  9. Rodriguez-Fortea, A.; Alemany, P.; Alvarez, S.; Ruiz, E.; Scuiller, A.; Decroix, C.; Marvaud, V.; Vaissermann, J.; Verdaguer, M.; Rosenman, I.; Julve, M. Inorg. Chem. 2001, 40, 5868.

    Article  PubMed  Google Scholar 

  10. Li, L.C.; Lao, D.Z.; Jiang, Z.-H.; Yan, S.P. Journal of Molecular Structure 2001, 597, 157.

    Article  Google Scholar 

  11. Li, L.C.; Lao, D.Z.; Jiang, Z.-H.; Yan, S.P. Polyhedron 2001, 20, 681.

    Article  Google Scholar 

  12. Gafford, B.G.; Holwerda, R.A. Inorg. Chem. 1989, 28, 60.

    Article  Google Scholar 

  13. Sheldrick, G.M. SHELX97, Program for Crystal Structure Refinement; University of Göttingen: Germany, 1997.

    Google Scholar 

  14. Cano, J.; Munno, G.D.; Sanz, J.L.; Ruiz, R.; Faus, J.; Lloret, F.; Julve, M.; Caneschi, A. J. Chem. Soc., Dalton Trans. 1997, 1915.

  15. Hong, C.S.; Do, Y. Inorg. Chem. 1997, 36, 157.

    Google Scholar 

  16. Chandhui, P.; Oder, K.; Wieghardt, K.; Gehring, S.; Haase, W.; Nuber, B.; Weiss, J. J. Am. Chem. oc. 1986, 108, 3657.

    Google Scholar 

  17. Lu, A.L.; Duan, C.Y.; Tian, Y.P.; You, X.Z. Polyhedron 1996, 15, 1769.

    Article  Google Scholar 

  18. Kim, J. C.; Cho, J.H.; Lough, A. J. Inorg. Chim. Acta. 2001, 317, 252.

    Article  Google Scholar 

  19. Duggan, M.; Ray, N.; Hathaway, B.; Tomlinson, G.; Brint, P.; Pelin, K. J. Chem. Soc., Dalton Trans. 1980, 1342.

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Authors and Affiliations

  1. Department of Chemistry, NanKai University, Tianjin, P.R. China

    Lei Yang, Yi Peng, Fang Bian, Shi-ping Yan, Dai-zheng Liao, Peng Cheng & Zong-hui Jiang

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  1. Lei Yang
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  2. Yi Peng
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  3. Fang Bian
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  4. Shi-ping Yan
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  5. Dai-zheng Liao
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  6. Peng Cheng
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  7. Zong-hui Jiang
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Correspondence to Shi-ping Yan.

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Yang, L., Peng, Y., Bian, F. et al. Structure and magnetic properties of a dinuclear complex [Cu2(TPA)2(o-phth)](ClO4)2. J Chem Crystallogr 35, 555–559 (2005). https://doi.org/10.1007/s10870-005-5383-6

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  • DOI: https://doi.org/10.1007/s10870-005-5383-6

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