Skip to main content
SpringerLink
Log in

Crystal structure, thermal analysis, and IR spectroscopic investigation of bis(2-amino-6-methyl) pyridinium sulfate

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Synthesis, crystal structure refinement, phase transitions studied by thermal analysis, and IR spectroscopic investigation of 2C6H9N2 < eqid2 > ⋅SO42− are reported. The title compound crystallizes in the monoclinic space group C2/c (no. 15) with a = 10.5068(4) Å, b = 10.2225(5) Å, c = 14.0422(7) Å, and β = 104.489(3)∘. A crystal packing diagram shows layers built by all the components of the structure and centered by planes z = 1/4 and 3/4. The pyridine substituents stack forming channels parallel to the c direction with dimensions of 4.163(1) Å and 5.148(4) Å. Thermal analysis shows that the anhydrous compound possesses an irreversible weak phase transition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Masse, R.; Zyss, J. Mol. Eng. 1991, 1, 141.

    Article  Google Scholar 

  2. Masse, R.; Bagieu-Beucher, M.; Pécaut, J.; Levy, J.P.; Zyss, J. Nonlinear Opt. 1993, 5, 413.

    Google Scholar 

  3. Zyss, J. In Conjugated Polymeric Materials, Opportunities in Electronics, Optoelectronics and Molecular Electronic; Brédas, J.L.; Chance, R.R., Eds.; 1990, 545.

  4. Fkyerat, A.; Guelzim, A.; Baert, F.; Paulus, W.; Heger, G.; Zyss, J.; Périgaud, A. Acta Crystallogr. B 1995, 51, 197.

    Article  Google Scholar 

  5. Pécaut, J.; Le Fur, Y.; Masse, R. Acta Crystallogr. B 1993, 49, 535.

    Article  Google Scholar 

  6. Chertanova, L.; Pascard, C. Acta Crystallogr. B 1996, 52, 677.

    Article  Google Scholar 

  7. Otwinowski, Z.; Minor, W. Methods in Enzymology, Vol. 276; Academic Press: New York, 1997.

    Google Scholar 

  8. Sheldrick, G.M. SHELXS97 and SHELXL97, Program for Crystal Structure Solution and Refinement; University of Göttingen: Germany, 1997.

    Google Scholar 

  9. Guerfel, T.; Bdiri, M.; Jouini, A. J. Chem. Crystallogr. 2000, 30(12), 799.

    Article  Google Scholar 

  10. Haile, S.M.; Kreuer, K.-D.; Maier, J. Acta Crystallogr. B 1995, 51, 680.

    Article  Google Scholar 

  11. Haile, S.M.; Calkins, P.M. J. Solid State Chem. 1998, 140, 251.

    Article  Google Scholar 

  12. Haile, S.M.; Calkins, P.M.; Boysen, D. J. Solid State Chem. 1998, 139, 373.

    Article  Google Scholar 

  13. Capasso, S.; Mattia, C.A.; Mazzarella, L.; Zagari, A. Acta Crystallogr. C 1983, 39, 281.

    Article  Google Scholar 

  14. Guerfel, T.; Jouini, A. J. Chem. Crystallogr. 2001, 31(6), 333.

    Article  Google Scholar 

  15. Chtioui, A.; Guerfel, T.; Benhamada, L.; Jouini, A. Solid State Sci. 2001, 3, 859.

    Article  Google Scholar 

  16. Baur, W.H. Acta Crystallogr. B 1974, 30, 1195.

    Article  Google Scholar 

  17. Farrugia, L.J. J. Appl. Crystallogr. 1997, 30, 565.

    Article  Google Scholar 

  18. Pecaut, J.; Le Fur, Y.; Masse:, R. Acta Crystallogr. B 1993, 49, 535.

    Article  Google Scholar 

  19. Baouab, L.; Guerfel, T.; Soussi, M.; Jouini, A. J. Chem. Crystallogr. 2000, 30(12), 805.

    Article  Google Scholar 

  20. Guerfel, T.; Bdiri, M.; Jouini, A. J. Chem. Crystallogr. 1999, 29(11), 1205.

    Article  Google Scholar 

  21. Baouab, L.; Jouini, A. J. Solid State Chem. 1998, 141, 343.

    Article  Google Scholar 

  22. Hertzberg, G. Infrared and Raman Spectra of Polyatomic Molecules; Van Nostrand: New York, 1966.

    Google Scholar 

  23. Nakamoto, K. IR and Ra Spectra of Inorganic and Coordinate Compounds; Wiley: New York, 1986.

    Google Scholar 

  24. Guerfel, T.; Jouini, A. J. Soc. Chim. Tunisie 2000, IV(7), 723.

    Google Scholar 

  25. Guerfel, T.; Jouini, A. J. Soc. Chim. Tunisie 2000, IV(8), 887.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie du Solide, Département de chimie, Faculté des Sciences de Monastir, Université du centre, 5019, Monastir, Tunisia

    Taha Guerfel & Amor Jouini

Authors
  1. Taha Guerfel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Amor Jouini
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Taha Guerfel.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Guerfel, T., Jouini, A. Crystal structure, thermal analysis, and IR spectroscopic investigation of bis(2-amino-6-methyl) pyridinium sulfate. J Chem Crystallogr 35, 513–521 (2005). https://doi.org/10.1007/s10870-005-2854-8

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-005-2854-8

Keywords

Search

Navigation