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[Cd5(OH)(H2O)3][CH3CO2]9, a cadmium hydroxy-acetate compound with a layered network

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Abstract

[Cd5(OH)(H2O)3][CH3CO2]9 crystallizes in the triclinic system, with the space group P\(\bar{1}\), a = 10.897(3) Å, b = 11.035(5) Å, c = 16.061(12) Å, α = 96.83(7)∘, β = 95.31(8)∘, γ = 118.22(6)∘ and z = 2. Its structure has been determined using 9497 unique single crystal data. The final refinements let the agreement factors R1 and wR2(F2) converge to reach the respective values of 0.0548 and 0.0986. R1 = 0.0338 for the 7264 unique data with I > 2σ(I). [Cd5(OH)(H2O)3][CH3CO2]9 is a cadmium hydroxide acetate compound with a bi-dimensional structure in which hydrogen bonds insure cohesion between layers stacked along the [1\(\bar{1}\) 10] direction. The inorganic network is built up of layers constituted of CdO6 octahedra and CdO7 pentagonal bi-pyramids sharing edge or corner.

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Authors and Affiliations

  1. ITODYS, UMR CNRS 7086, Université PARIS VII Denis Diderot, Case 7090. 2, Place Jussieu, 75251, Paris Cedex 05, France

    L. Poul, M. Taibi, N. Jouini & F. Fiévet

  2. Laboratoire de Cristallochimie, Faculté des Sciences de Tunis, Campus Universitaire, Tunis, 2092, Tunisia

    M. Fakhfakh

  3. Laboratoire de Chimie Inorganique et Structurale, Faculté des Science de Bizerte, Zarzouna, Bizerte, 7021, Tunisia

    M. Fakhfakh

  4. LPMTM-UPR-CNRS 9001, Institut Galilée, Université ParisXIII. 99, avenue J. B. Clément, Villetaneuse, 93430, France

    N. Jouini

  5. Laboratoire de Chimie Inorganique et Matériaux Moléculaires, UMR CNRS 7071, Université Paris VI Pierre & Marie Curie, Case 42. 4, Place Jussieu, 75252, Paris, Cedex 05, France

    P. Herson

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  1. L. Poul
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  2. M. Fakhfakh
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  4. N. Jouini
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  6. F. Fiévet
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Poul, L., Fakhfakh, M., Taibi, M. et al. [Cd5(OH)(H2O)3][CH3CO2]9, a cadmium hydroxy-acetate compound with a layered network. J Chem Crystallogr 35, 285–291 (2005). https://doi.org/10.1007/s10870-005-1439-x

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  • DOI: https://doi.org/10.1007/s10870-005-1439-x

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