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Synthesis, characterization and crystal structure of oxovanadium(IV) complex with tridentate o-van-gly and bidentate phenanthroline

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Abstract

A novel oxovanadium(IV) complex with tridentate schiff base and bidentate phenanthroline ligands, VO(o-van)(phen) ⋅2H2O[o-van-gly: o-vanillin-glycine; phen: phenanthroline], was synthesized and characterized by elemental analysis, IR and UV-vis spectra. The crystal structure was determined by X-ray single crystal diffraction analysis. The crystal of title complex (C22H21N3O7V, Mw = 490.36) belongs to triclinic, space group P-1 with the following crystallographic parameters: a = 9.247(3) Å, b = 10.125(4) Å, c = 13.100(5) Å, α = 106.343(6)∘, β = 96.042(7)∘, γ = 101.726(7)∘, V = 1135.0(7) Å3, Z = 2, Dc = 1.435 Mg ⋅ m−3, μ(MoK α = 0.485 mm−1, F(000) = 506, and final R1 = 0.0779, wR2 = 0.1598 for observed reflections 1606 (I > 2σ(I)). V(IV) is six-coordinate with three oxygen atoms and three nitrogen atoms in a distorted octahedral geometry. The complex forms a 3-D network via π–π stacking and hydrogen bonds.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong, 252059, People’s Republic of China

    Tao Xu, Lian-Zhi Li, Guang-Qiang Guo & Mei-Ju Niu

  2. Liaocheng Profession Technical College, Liaocheng, Shandong, 252000, People’s Republic of China

    Shu-Fang Zhou

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  1. Tao Xu
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  2. Lian-Zhi Li
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  3. Shu-Fang Zhou
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  4. Guang-Qiang Guo
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  5. Mei-Ju Niu
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Correspondence to Lian-Zhi Li.

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Xu, T., Li, LZ., Zhou, SF. et al. Synthesis, characterization and crystal structure of oxovanadium(IV) complex with tridentate o-van-gly and bidentate phenanthroline. J Chem Crystallogr 35, 263–267 (2005). https://doi.org/10.1007/s10870-005-1286-9

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  • DOI: https://doi.org/10.1007/s10870-005-1286-9

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