Abstract
The structure of the title compound bis-(1-tert-butyl-1,2-dibenzoylhydrazine)-N,N′- sulfide was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic, space group P2(1)/c with the following crystallographic parameters: a = 14.681(7) Å, b = 14.501(7) Å, c = 16.535(8) Å, α = 90°, β = 109.173(9)°, γ = 90°, V = 3325(3) Å 3, z = 4, Dx = 1.244 mg/m3, F(000) = 1320, T = 293(2) K, 1.47° ≤ θ ≤ 25.00°, the final R factor: R1 = 0.0584, wR2 = 0.1111. The bond distances and angles in the tert-butyl groups are different, that can interpret its 1H NMR spectra, which are very unusual for the absorption of –CMe3 being multiple.
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Jian, S., Min, W.Q., Qiu, H.R. et al. Crystal and molecular structure of bis-(1-tert-butyl-1,2-dibenzoylhydrazine)-N,N′-sulfide. J Chem Crystallogr 34, 873–876 (2004). https://doi.org/10.1007/s10870-004-7721-5
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DOI: https://doi.org/10.1007/s10870-004-7721-5