Abstract
Structure, mechanical properties and grindability of a series of binary Ti–Zr alloys with zirconium contents ranging from 10 to 40 wt% have been investigated. Commercially pure titanium (c.p. Ti) was used as a control. Experimental results indicated that the diffraction peaks of all the Ti–Zr alloys matched those for α Ti. No β-phase peaks were found. The hardness of the Ti–Zr alloys increased as the Zr contents increased, and ranged from 266 HV (Ti–10Zr) to 350 HV (Ti–40Zr). As the concentration of zirconium in the alloys increased, the strength, elastic recovery angles and hardness increased. Moreover, the elastically recoverable angle of Ti–40Zr was higher than of c.p. Ti by as much as 550%. The grindability of each metal was found to be largely dependent on the grinding conditions. The Ti–40Zr alloy had a higher grinding rate and grinding ratio than c.p. Ti at low speed. The grinding rate of the Ti–40Zr alloy at 500 m/min was about 1.8 times larger than that of c.p. Ti, and the grinding ratio was about 1.6 times larger than that of c.p. Ti. Our research suggested that the Ti–40Zr alloy has better mechanical properties, excellent elastic recovery capability and improved grindability at low grinding speed. The Ti–40Zr alloy has a great potential for use as a dental machining alloy.









References
R.R. Wang, A. Fenton, Quintessence Int. 27, 401 (1996)
J.A. Hautaniemi, H. Hero, J.T. Juhanoja, J. Mater. Sci. 3, 186 (1992)
O. Okuno, H. Hamanaka, Dent. Jpn. 26, 101 (1989)
E.P. Lautenschlager, P. Monaghan, Int. Dent. J. 43(3), 245 (1993)
M. Hattori, K. Hasegawa, M. Yoshinari, E. Kawada, Y. Oda, T. Okabe, Dent. Mater. J. 20(1), 16 (2001)
Y. Takada, H. Nakajima, O. Okuno, T. Okabe, Dent. Mater. J. 20(1), 34 (2001)
M. Takahashi, M. Kikuchi, Y. Takada, O. Okuno, Dent. Mater. J. 21(3), 270 (2002)
F. Duret, J.L. Blouin, B. Duret, J. Am. Dent. Assoc. 117(6), 715 (1988)
H. Nakajima, T. Okabe, Dent. Mater. J. 15, 77 (1996)
M. Kikuchi, Y. Takada, S. Kiyosue, M. Yoda, M. Woldu, Z. Cai, O. Okuno, T. Okabe, Dent. Mater. 19, 375 (2003)
M. Kikuchi, M. Takahashi, T. Okabe, O. Okuno, Dent. Mater. J. 22(2), 191 (2003)
M. Kikuchi, M. Takahashi, O. Okuno, Dent. Mater. J. 22(3), 328 (2003)
M. Kikuchi, M. Takahashi, H. Sato, O. Okuno, M.E. Nunn, T. Okabe, J. Biomed. Mater. Res. B., Appl. Biomater. 77(1), 34 (2005)
M. Takahashi, M. Kikuchi, O. Okuno, Dent. Mater. J. 23(2), 203 (2004)
P.R. Walker, J. Leblanc, M. Sikorska, Biochemistry 28, 3911 (1989)
S. Yumoto, H. Ohashi, H. Nagai, S. Kakimi, Y. Ogawa, Y. Iwata, K. Ishii, Int. J. PIXE 2, 493 (1992)
Y. Okazaka, S. Asao, S. Rao, T. Tateshi, J. Jpn. Inst. Met. 60(9), 902 (1996)
D.L. Douglass, At. Energy Rev. 3, 71 (1963)
J.L. Murray, Binary alloy phase diagrams, in Alloy Phase Diagrams, ed. by H. Baker (ASM International, Materials Park, OH, 1987), p. 340
S. Zinelis, A. Tsetsekou, T. Papadopoulos, J. Prosth. Dent. 90, 332 (2003)
E. Kobayashi, S. Matsumoto, H. Doi, T. Yoneyama, H. Hamanaka, J. Biomed. Mater. Res. 29, 943 (1995)
A. Guha, in Metals Handbook, 9th edn (ASM International, Materials Park, OH, 1985), p. 133
W.F. Ho, C.P. Ju, J.H. Chern Lin, Biomaterials 20, 2115 (1999)
M. Taira, M. Okazaki, J. Takahashi, M. Yamaki, J. Oral Rehabil. 24(7), 527 (1997)
I. Watanabe, C. Ohkubo, J.P. Ford, M. Atsuta, T. Okabe, Dent. Mater. 16(6), 420 (2000)
C. Ohkubo, I. Watanabe, J.P. Ford, H. Nakajima, T. Hosoi, T. Okabe, Biomaterials 21, 421 (2000)
J.C. Willians, Critical review: kinetics and phase transformation, in Titanium Science and Technology; Proceeding (Metallurgical Society of AIME, Plenum Press, New York, 1973), p. 1433
K. Nakasuji, M. Okada, Mater. Sci. Eng. A213, 162 (1996)
W.J. Gammon, O. Kraft, A.C. Reilly, B.C. Holloway, Carbon 41, 1917 (2003)
C.W. Lin, C.P. Ju, J.H. Chern Lin, Biomaterials 26, 2899 (2005)
W.W. Cheng, C.P. Ju, J.H. Chern Lin, J. Oral Rehabil. 34, 528 (2007)
A.G. Guy, Introduction to Materials Science (McGraw-Hill, New York, 1972), p. 225
H. Takeyama, T. Yoshikawa, T. Takada, J. Jpn. Soc. Preci Eng. 41(4), 392 (1975)
R. Grajower, I. Kurz, M.S. Bapna, Dent. Mater. 2, 187 (1986)
M.H. Reisbick, B.F. Bunshah, J. Dent. Res. 52, 1138 (1973)
W.J. O’brien, Dental Materials Properties and Selection, 3rd edn (Quintessence Publishing Co, Chicago, 1989), p. 515
E.O. Ezugwu, Z.M. Wang, J. Mater. Process. Tech. 68(3), 262 (1997)
Acknowledgment
This work was supported by grants, NSC95-2622-E-212-003-CC3 and NSC96-2622-E-212-008-CC3, provided by National Science Council of Taiwan.
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Ho, WF., Chen, WK., Wu, SC. et al. Structure, mechanical properties, and grindability of dental Ti–Zr alloys. J Mater Sci: Mater Med 19, 3179–3186 (2008). https://doi.org/10.1007/s10856-008-3454-x
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DOI: https://doi.org/10.1007/s10856-008-3454-x