Abstract
An apatite layer was successfully formed on titanium substrates by electrochemical deposition in a metastable calcium phosphate solution, which had 1.5 times the ion concentrations of a normal simulated body fluid, but did not contain MgCl2·6H2O, at 41 °C for 40 or 60 min at 13 mA. The current did not produce large effects on the crystalline size of the apatite, but the thickness of the apatite layer could be controlled by deposition conditions such as electrolyte temperature, current and deposition time. It is expected that the present electrochemical deposition will be useful to rapidly coat apatite on metallic materials.
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S. D. COOK, K. A. THOMAS, J. F. KAY and M. JARCHO, Clin. Orthop. 230 (1988) 303
P. DUCHEYNE, S. RADIN, M. HEUGHEBAERT and J. C. HEUGHEBAERT, Biomaterials 11 (1990) 244
L. C. LUCAS, W. R. LACEFIELD, J. L. ONG and R. Y. WHITEHEAD, Colloids Surf. A: Physicochem. Eng. Asp. 77 (1993) 141
L. L. HENCH and Ö. H. ANDERSSON, in “An Introduction to Bioceramics”, Edited by: L. L. HENCH and J. WILSON (World Scientific, Singapore, 1993) p. 239
K. TAKATSUKA, T. YAMAMURO, T. KITSUGI, T. NAKAMURA, T. SHIBUYA and T. GOTO, J. Appl. Biomat. 4 (1993) 317
H. HERǾ, H. WIE, R. B. JǾRGENSEN and I. E. RUYTER, J. Biomed. Mater. Res. 28 (1994) 343
K. DE GROOT, R. GEESINK, C. P. A. T. KLEIN and P. SEREKIAN, J. Biomed. Mater. Res. 21 (1987) 1375
R. G. T. GEESINK, K. DE GROOT and C. P. A. T. KLEIN, Clin. Orthop. 225 (1987) 147
C. P. A. T. KLEIN, P. PATKA, H. B. M. VAN DER LUBBE, J. G. C. WOLKE and K. DE GROOT, J. Biomed. Mater. Res. 25 (1991) 53
P. DUCHEYNE, W. VAN RAEMDONCK, J. C. HEUGHEBAERT and M. HEUGHEBAERT, Biomaterials 7 (1986) 97
K. A. THOMAS, J. F. KAY, S. D. COOK and M. JARCHO, J. Biomed. Mater. Res. 21 (1987) 1395
S. R. RADIN and P. DUCHEYNE, J. Mater. Sci.: Mater. Med. 3 (1992) 33
C. P. A. T. KLEIN, J. G. C. WOLKE, J. M. A. DE BLIECK-HOGERVORST and K. DE GROOT, J. Biomed. Mater. Res. 28 (1994) 961
K. A. GROSS and C. C. BERNDT, J. Mater. Sci.: Mater. Med. 5 (1994) 219
K. A. MANN, A. A. EDIDIN, R. K. KINOSHITA and M. T. MANLEY, J. Appl. Biomat. 5 (1994) 285
H.-M. KIM, F. MIYAJI, T. KOKUBO and T. NAKAMURA, J. Biomed. Mater. Res. 32 (1996) 409
T. MIYAZAKI, H.-M. KIM, F. MIYAJI, T. KOKUBO and T. NAKAMURA, J. Biomed. Mater. Res. 50 (2000) 35
T. KOKUBO, H.-M. KIM and M. KAWASHITA, Biomaterials 24 (2003) 2161
T. KOKUBO, H. KUSHITANI, S. SAKKA, T. KITSUGI and T. YAMAMURO, J. Biomed. Mater. Res. 24 (1990) 721
S. B. CHO, K. NAKANISHI, T. KOKUBO, N. SOGA, C. OHTSUKI, T. NAKAMURA, T. KITSUGI and T. YAMAMURO, J. Am. Ceram. Soc. 78 (1995) 1769
T. KOKUBO and H. TAKADAMA, Biomaterials 27 (2006) 2907
J. REDEPENNING and J. P. MCISAAC, Chem. Mater. 2 (1990) 625
M. SHIRKHANZADEH, J. Mater. Sci. Lett. 10 (1991) 1415
H. MONMA, J. Ceram. Soc. Jpn. 101 (1993) 737
S. BAN and S. MARUNO, Jpn. J. Appl. Phys. 32 (1993) L1577
S. BAN and S. MARUNO, Jpn. J. Appl. Phys. Lett. 33 (1994) L1545
H. MONMA, J. Mater. Sci. 29 (1994) 949
S. BAN and S. MARUNO, Biomaterials 16 (1995) 977
S. BAN, S. MARUNO, N. ARIMOTO, A. HARADA and J. HASEGAWA, J. Biomed. Mater. Res. 36 (1997) 9
S. BAN and S. MARUNO, Biomaterials 19 (1998) 1245
S. BAN and S. MARUNO, J. Biomed. Mater. Res. 42 (1998) 387
S. BAN and J. HASEGAWA, Biomaterials 23 (2002) 2965
S. BAN, A. KAMIYA and T. SONODA, Dent. Mater. J. 21 (2002) 306
M. TANAHASHI, T. YAO, T. KOKUBO, M. MINODA, T. MIYAMOTO, T. NAKAMURA and T. YAMAMURO, J. Am. Ceram. Soc. 77 (1994) 2805
H. P. KLUG and L. E. ALEXANDER, in “X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials” 2nd edn. (John Wiley & Sons, Inc., New York, 1974)
A. L. BOSKEY and A. S. POSNER, Mater. Res. Bull. 9 (1974) 907
R. Z. LEGEROS, D. MIJARES, J. PARK, X. F. CHANG, I. KHAIROUN, R. KIJKOWSKA, R. DIAS and J. P. LEGEROS, Key Eng. Mater. 284–286 (2005) 7
J. C. ELLIOT, in “Structure and Chemistry of the Apatites and Other Calcium Orthophosphates” (Elsevier, Amsterdam, 1994) p 267
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This work was supported in part by a Grant-in-Aid for Scientific Research, the Ministry of Education, Culture, Sports, Science and Technology, Japan and Nanotechnology Support Project of the Ministry of Education, Culture, Sports, Science and Technology, Japan.
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Kawashita, M., Itoh, S., Miyamoto, K. et al. Apatite formation on titanium substrates by electrochemical deposition in metastable calcium phosphate solution. J Mater Sci: Mater Med 19, 137–142 (2008). https://doi.org/10.1007/s10856-007-3127-1
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DOI: https://doi.org/10.1007/s10856-007-3127-1