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Incorporating pre-stretching into electroless copper plating for conductivity improvement of elastic nylon fabric: application in ECG electrode

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Abstract

A preparation method of electroless copper electrodes based on elastic nylon fabric for ECG monitoring is proposed to meet the key needs of monitoring accuracy and wearing comfort in this paper. There were 72 rectangular nylon fabric samples involved in the experiment, and three key variables were introduced during the electrode preparation experiment, copper plating time, temperature, pre-stretching, where pre-stretching considered both warp and weft direction. The resistance of 72 samples at 30% stretch state was measured, SEM was used to characterize the copper plated fabric and copper plated fabric ECG electrodes were prepared and evaluated. According to the resistance statistics, the introduction of pre-stretching in the weft direction can bring better copper plating effects, and one sample (which was marked as D20/weft-1) showed the best electrical conductivity in the groups. Combined with SEM images, they all proved the success of copper plating on nylon fabric and that relatively low temperature and appropriate time are beneficial to copper plating. Simultaneously SEM inspection of MΩ-level high-resistance samples revealed that some of the copper plated particles were incompletely covered or peeled off. Finally, evaluating ECG waveforms and signal-to-noise ratios using fabric electrodes in natural and chest expansion state. Results showed that the fabric electrodes prepared from sample D20/weft-1 with excellent conductivity almost have the same performance as traditional Ag/AgCl electrodes. This study provides a cost-effective method and low-cost alternative for electrodes to record high-quality ECG both at home and in the clinic.

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References

  1. M. Chi, J. Zhao, Y. Dong, X. Wang, Flexible carbon nanotube-based polymer electrode for long-term electrocardiographic recording. Materials 12, 971 (2019). https://doi.org/10.3390/ma12060971

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  2. J. Liu, K. Liu, X. Pan et al., A flexible semidry electrode for long-term, high-quality electrocardiogram monitoring. Adv. Compos. Hybrid Mater. 6, 13 (2022). https://doi.org/10.1007/s42114-022-00596-y

    Article  CAS  Google Scholar 

  3. T. Cui, D. Li, X. Huang et al., Graphene-based flexible electrode for electrocardiogram signal monitoring. Appl. Sci. 12, 4526 (2022). https://doi.org/10.3390/app12094526

    Article  CAS  Google Scholar 

  4. N. Zhang, L. Yue, Y. Xie et al., A novel antibacterial membrane electrode based on bacterial cellulose/polyaniline/AgNO3 composite for bio-potential signal monitoring. IEEE J. Transl Eng. He. 6, 1–10 (2018). https://doi.org/10.1109/jtehm.2018.2863388

    Article  Google Scholar 

  5. S. Maji, M.J. Burke, Noise performance of textile-based dry ECG recording electrodes. Electron. Lett. 57, 45–48 (2020). https://doi.org/10.1049/ell2.12063

    Article  CAS  Google Scholar 

  6. M.A. Yokus, J.S. Jur, Fabric-based wearable dry electrodes for body surface biopotential recording. IEEE Trans. Biomed. Eng. 63, 423–430 (2016). https://doi.org/10.1109/tbme.2015.2462312

    Article  PubMed  Google Scholar 

  7. Y. Zhou, X. Ding, J. Zhang, Y. Duan, J. Hu, X. Yang, Fabrication of conductive fabric as textile electrode for ECG monitoring. Fibers Polym. 15, 2260–2264 (2014). https://doi.org/10.1007/s12221-014-2260-y

    Article  CAS  Google Scholar 

  8. J.H. Lin, X. Fu, T.-T. Li, X. Zhang, B. Zhao, B.C. Shiu, H. Wang, Q. Jiang, C.-W. Lou, Structure design of multi-functional flexible electrocardiogram electrodes based on PEDOT:PSS-coated fabrics. J. Ind. Text. 51, 8077–8091 (2021). https://doi.org/10.1177/15280837211022637

    Article  CAS  Google Scholar 

  9. X. An, G.K. Stylios, A hybrid textile electrode for electrocardiogram (ECG) measurement and motion tracking. Materials. (2018). https://doi.org/10.3390/ma11101887

    Article  PubMed  PubMed Central  Google Scholar 

  10. X. Xu, M. Luo, P. He, J. Yang, Washable and flexible screen printed graphene electrode on textiles for wearable healthcare monitoring. J. Phys. D (2020). https://doi.org/10.1088/1361-6463/ab5f4a

    Article  Google Scholar 

  11. K. Le, H. Narayana, A. Servati, A. Bahi, S. Soltanian, P. Servati, F. Ko, Electronic textiles for electrocardiogram monitoring: a review on the structure–property and performance evaluation from fiber to fabric. Text. Res. J. 93, 878–910 (2022). https://doi.org/10.1177/00405175221108208

    Article  CAS  Google Scholar 

  12. T. Takeshita, M. Yoshida, Y. Takei, A. Ouchi, A. Hinoki, H. Uchida, T. Kobayashi, Development of wearable multi-lead ECG measurement device using cubic flocked electrode. Sci. Rep. 12, 19308 (2022). https://doi.org/10.1038/s41598-022-24043-6

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  13. L. Wang, Y. Pan, D. He, L. Qian, X. Cao, B. He, J. Li, Conductive polyester fabrics with high washability as electrocardiogram textile electrodes. ACS Appl. Polym. Mater. (2022). https://doi.org/10.1021/acsapm.1c01619

    Article  Google Scholar 

  14. H. Wang, T. Cheng, C. Huang, C. Su, C. Dai, Y. Tsai, High sensitivity and flexible fabric strain sensor based on electrochemical graphene. Jpn. J. Appl. Phys. (2021). https://doi.org/10.35848/1347-4065/abe2e6

    Article  Google Scholar 

  15. Z. Hassan, O. Atalay, F. Kalaoglu, F.A. Ozat, O. Ozdemir, M.O. Kesimci, Development and characterization of conductive textile (polyester fabric) for wearable electronics by using electroless metallization. J. Text. Inst. (2023). https://doi.org/10.1080/00405000.2023.2225706

    Article  Google Scholar 

  16. J. Landsiedel, J. Tschannett, M. Lenninger, S. Stroj, M. Domke, T. Bechtold, T. Pham, N. Aguiló-Aguayo, A siloxane interlayer approach to enhance surface metallization on polyamide fabrics via electroless copper deposition. Surf. Interfaces 42, 103434 (2023). https://doi.org/10.1016/j.surfin.2023.103434

    Article  CAS  Google Scholar 

  17. G. Zhang, W. Yang, J. Ding, M. Liu, C. Di, S. Ci, K. Qiao, Influence of carbon fibers on interfacial bonding properties of copper-coated carbon fibers. Carbon Lett. (2024). https://doi.org/10.1007/s42823-023-00671-4

    Article  Google Scholar 

  18. W. Zhao, X. Liu, X. Song, C. Zhang, H. Chen, X. Li, K. Hui, W. Zhao, L. Qiao, H. Zhu, Y. Cheng, Z. Wang, Surface modification of epoxy resin by MnO2–H2SO4–H2O–Na4P2O7 for enhanced adhesion to electroless copper. Int. J. Adhes. Adhes. 130, 103611 (2024). https://doi.org/10.1016/j.ijadhadh.2023.103611

    Article  CAS  Google Scholar 

  19. Y. Lu, Improvement of copper plating adhesion on silane modified PET film by ultrasonic-assisted electroless deposition. Appl. Surf. Sci. 256, 3554–3558 (2010). https://doi.org/10.1016/j.apsusc.2009.12.153

    Article  CAS  Google Scholar 

  20. G.H. Zheng, J. Ren, X. Zhang, R.H. Guo, F.L. Ji, Research of the electroless copper plating on wool fabrics. Microsyst. Technol. 22, 929–934 (2016). https://doi.org/10.1007/s00542-016-2876-5

    Article  CAS  Google Scholar 

  21. B. Li, K. Dastafkan, Y. Shen, L. Wang, Y. Ma, Z. Wang, C. Zhao, Enhancing adhesion of electroless copper film on smooth polyimide surfaces by photocatalytic oxidation. J. Electrochem. Soc. (2023). https://doi.org/10.1149/1945-7111/acf6e5

    Article  Google Scholar 

  22. S. Mu, H. Xie, W. Wang, D. Yu, Electroless silver plating on PET fabric initiated by in situ reduction of polyaniline. Appl. Surf. Sci. 353, 608–614 (2015). https://doi.org/10.1016/j.apsusc.2015.06.126

    Article  CAS  Google Scholar 

  23. E.G. Han, E.A. Kim, K.W. Oh, Electromagnetic interference shielding effectiveness of electroless Cu-plated PET fabrics. Synth. Met. 123, 469–476 (2001). https://doi.org/10.1016/s0379-6779(01)00332-0

    Article  CAS  Google Scholar 

  24. J. Liu, J. Chen, Y. Zhang, S. Fu, G. Chai, C. Cao, X. Zhu, Y. Guo, W. Cheng, D. Jiang, Z. Zhao, Q. Zhan, Stretching-tunable high-frequency magnetic properties of wrinkled CoFeB films grown on PDMS. ACS Appl. Mater. Interfaces 13, 29975–29983 (2021). https://doi.org/10.1021/acsami.1c07384

    Article  CAS  PubMed  Google Scholar 

  25. M. Sarafpour, M. Youssefi, S.M. Mortazavi, Copper functionalization of polypropylene fabric surface in order to use in fog collectors. Fibers Polym. 17, 2041–2046 (2017). https://doi.org/10.1007/s12221-016-6560-2

    Article  CAS  Google Scholar 

  26. H. Chen, Y. Tai, C. Xu, Fabrication of copper-coated glass fabric composites through electroless plating process. J. Mater. Sci. 28, 798–802 (2016). https://doi.org/10.1007/s10854-016-5592-0

    Article  CAS  Google Scholar 

  27. E. Kim, N. Sabari Arul, L. Yang, J.I. Han, Electroless plating of copper nanoparticles on PET fiber for non-enzymatic electrochemical detection of H2O2. RSC Adv. 5, 76729–76732 (2015). https://doi.org/10.1039/c5ra10157c

    Article  CAS  Google Scholar 

  28. J. Kim, K. Cho, D. Cho, K. Hong, K. Lee, Ultra-sensitive and stretchable ionic skins for high-precision motion monitoring. Adv. Funct. Mater. 31, 2010199 (2021). https://doi.org/10.1002/adfm.202010199

    Article  CAS  Google Scholar 

  29. C. Biermaier, T. Bechtold, T. Pham, Time-resolved monitoring of electroless copper deposition on woven cellulose fabrics. Thin Solid Films 775, 139852 (2023). https://doi.org/10.1016/j.tsf.2023.139852

    Article  CAS  Google Scholar 

  30. L. Meng, Q. Fu, S. Hao, F. Xu, J. Yang, Self-adhesive, biodegradable silk-based dry electrodes for epidermal electrophysiological monitoring. Chem. Eng. J. 427, 131999 (2022). https://doi.org/10.1016/j.cej.2021.131999

    Article  CAS  Google Scholar 

  31. J. Ferri, R. Llinares, I. Segarra, A. Cebrián, E. Garcia-Breijo, J. Millet, A new method for manufacturing dry electrodes on textiles. Validation for wearable ECG monitoring. Electrochem. Commun. 136, 107244 (2022). https://doi.org/10.1016/j.elecom.2022.107244

    Article  CAS  Google Scholar 

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Acknowledgements

The work described in this paper was mainly supported by Guangxi Science and Technology and Base Project Guike AD20238039 and partially supported by Guangxi Innovation Driven Development Project Guike AA21077015. Authors also thank Prof. Liucheng Gui, Prof. Juantao Jiang, Prof.lingsheng Liu and Prof. Zhen Yang from Guangxi Normal University for SEM inspection, experiments and analysis support and valuable discussions.

Funding

The work described in this paper was mainly supported by Guangxi Science and Technology and Base Project Guike AD20238039 and partially supported by Guangxi Innovation Driven Development Project Guike AA21077015.

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All authors contributed to the conception and design of this study. The first draft of the manuscript was written by Youshi Pan, revised and edited by Dr. Guangjun Lu, and all authors commented on previous versions of the manuscript. All authors reviewed and approved the final manuscript.

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Correspondence to GuangJun Lu.

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Pan, Y., Lu, G., Su, J. et al. Incorporating pre-stretching into electroless copper plating for conductivity improvement of elastic nylon fabric: application in ECG electrode. J Mater Sci: Mater Electron 35, 942 (2024). https://doi.org/10.1007/s10854-024-12538-z

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