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Investigation of the influence of VO2 formation on the structural morphology and magnetic properties in hydrothermally synthesized V6O13

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Abstract

Investigating the impact of hydrothermal duration on electronic magnetism, two distinct samples were synthesized: the V6O13 phase (S1) with 0.5 h of hydrothermal reaction, and the V6O13 and VO2 coexistent phase (S2) with 6 h of reaction. X-ray diffraction identified S1 as monoclinic C2/m, and S2 with a 4:1 ratio of V6O13 in P21/c space group VO2. Electron microscopy revealed rod-like V6O13 and spherical VO2. Both samples exhibited metal-insulator transitions, with the presence of VO2 in S2 elevating the metal-insulator phase transition onset temperature and widening the transition range. S1 exhibits antiferromagnetic ordering at low temperatures (TN ~ 55 K) and follows the Curie-Weiss law above the metal-insulator transition temperature, while the behavior of S2 was modeled by a combination of Pauli and Curie-like paramagnetism, aligning well with experimental data. Small hysteresis loops in both samples suggested weak ferromagnetism; the linear loop of S1 indicated strong vanadium electron correlation, and the incomplete S-loop of S2 was attributed to the influence of VO2 on the electronic magnetism of V6O13.

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Data availability

The datasets generated and/or analysed during the current study are available from the corresponding author on reasonable request.

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Funding

The authors gratefully acknowledge the financial support provided by National Natural Science Foundation of China (Nos. 22108077), the Project Supported by Natural Science Foundation of Jiangxi (20161BAB213067), Scientific Research Fund of Jiangxi Provincial Education Department (GJJ170807).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen, 333403, People’s Republic of China

    Li Liu, Qifu Bao, Tiangui Zhao, Detai Shi, Xiaolong Li & Jianer Zhou

  2. Department of Mathematics and Physics, Quzhou University, Quzhou, 324000, People’s Republic of China

    Li Liu & Wei Zhu

  3. National Engineering Research Center for Cereal Fermentation and Food Biomanufacturing, Jiangnan University, Wuxi, 214000, People’s Republic of China

    Siyu Li

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  1. Li Liu
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  2. Wei Zhu
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Contributions

LL carried out the paper conception, investigation and first draft writing. WZ and DS provide technical analysis, data collection and data processing. SL, QB and TZ were responsible for research, content or data visualization. XL provides characterization and verification of research results. JZ carried out project management, experimental guidance, initial draft review and editing. All authors have seen and approved the final version of the manuscript being submited. We warrant that the article is the authors’ original work, has not received prior publication.

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Correspondence to Jianer Zhou.

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Liu, L., Zhu, W., Li, S. et al. Investigation of the influence of VO2 formation on the structural morphology and magnetic properties in hydrothermally synthesized V6O13. J Mater Sci: Mater Electron 35, 503 (2024). https://doi.org/10.1007/s10854-024-12259-3

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