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Investigation of organotin (IV) thiosemicarbazones precursors for synthesizing nanoscaled tin sulfide materials

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Abstract

A sequence of organotin (IV) thiosemicarbazone addition of the type of RnSnCl4-n.mLH (1–14) were formed by the reactions of R2SnCl2 with ligands (LH), carvone thiosemicarbazone, C11H17N3S and carvone ethylthiosemicarbazone, C13H21N3S in anhydrous ethanol [where R = CH3, C4H9 or C6H5; n = 2–3 and m = 1–2]. Characterization of all the compounds is done by FT-IR (Fourier-Transform Infrared Spectroscopy), 1H, 13C, 119Sn NMR (Nuclear Magnetic Resonance) and FAB (Fast Atom Bombardment) mass studies. In the solution state, 119Sn NMR investigations indicate a monodentate method of ligand attachment with the core tin atom through the sulphur atom. TGA(Thermogravimetric Analysis) of (C4H9)2SnCl2.2C11H17N3S and (C6H5)2SnCl2.2C13H21N3S depicts big thermal events. Transformations of (C4H9)2SnCl2.2C11H17N3S and (C6H5)2SnCl2.2C13H21N3S to pure tin sulfide (SnS(i) and SnS(ii), correspondingly have been done using solvothermal technique. Images of SEM for (i) and (ii) represents plate-like morphologies of the crystallites and powder XRD(X-Ray Diffraction) of generated tin sulfides suggested formation of orthorhombic structure.

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The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

Veena Dhayal is thankful to SERB, New Delhi for funding this work (TAR/2020/000233). We are also thankful to SAIF and CAF labs, Manipal University Jaipur for carrying out all the analysis.

Funding

SERB, New Delhi for funding this work (TAR/2020/000233).

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Authors and Affiliations

  1. Department of Chemistry, Manipal University Jaipur, Jaipur, India

    Ishita Chopra & Veena Dhayal

  2. Department of Chemistry, University of Rajasthan, Jaipur, India

    Renu Sharma & Mukesh Kumar Atal

  3. School of Automobile, Mechanical and Mechatronics, Manipal University Jaipur, Jaipur, India

    Dalip Singh Shekhawat

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  1. Ishita Chopra
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Contributions

Ishita Chopra-Paper writing and editing. Renu Sharma -Particles synthesis. Mukesh Kumar Atal-Rough draft of paper. Dalip Singh Shekhawat – Review of rough draft. Veena Dhayal -Review and final draft.

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Correspondence to Veena Dhayal.

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Chopra, I., Sharma, R., Atal, M.K. et al. Investigation of organotin (IV) thiosemicarbazones precursors for synthesizing nanoscaled tin sulfide materials. J Mater Sci: Mater Electron 35, 439 (2024). https://doi.org/10.1007/s10854-024-12180-9

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