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Enhanced anti-corrosion and microwave absorption properties of novel binary titanium niobium nitrides nanofiber

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Abstract

In this study, the novel binary titanium niobium nitride nanofibers with dual functionalities of microwave absorption and corrosion resistance were synthesized. The results of XRD, XPS and EDS indicated that the as-prepared nanofibers was NbTiN2 phase with residual oxygen, which is favorable to the enhancement of impedance matching and interface polarization. Furthermore, the results of SEM and TEM demonstrated that the NbTiN2 nanofibers possess porous fibrous structure, resulting in the improvement of dipole polarization, interface polarization and multiple reflections. As a result, when the matching layer thickness was only 1.9 mm, the optimal reflection loss value reached − 44.97 dB, which was superior to the single-metal nitride nanofibers. Furthermore, the adulteration of Nb into TiN induces the generation of NbTiN2 solid solution and the TiNbN2 nanofibers exhibit stronger inertness characteristics, smallest corrosion current, highest corrosion voltage, indicating that it possesses excellent corrosion resistance. Consequently, the dual-function of microwave absorbing and corrosion resistance could be regulated simultaneously via adulteration of Nb into TiN to form the novel binary titanium niobium nitride nanofiber.

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Funding

The work was supported by Hebei Natural Science Foundation (Grant No. E2021209120).

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Authors and Affiliations

  1. State Key Laboratory of Metastable Materials Science and Technology, College of Material Science and Engineering, Yanshan University, Qinhuangdao, 066004, Hebei, People’s Republic of China

    Yi Cui & Bo Liang

  2. College of Material Science and Engineering, North China University of Science and Technology, Tangshan, 063210, Hebei, People’s Republic of China

    Yi Cui, Li Chaojie, Lu Jiaqi, Wei Yingna, Lv Dongfeng, Jinglong Bu & Hengyong Wei

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  1. Yi Cui
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Contributions

YC: contributed to conceptualization, synthesis, performance testing and writing-original draft. CL: contributed to investigation, methodology and synthesis. JL: contributed to synthesis, performance testing and writing—review. YW: contributed to resources and formal analysis. DL: contributed to formal analysis and performance testing. JB: contributed to resources and formal analysis. HW: contributed to investigation, synthesis and performance testing. BL: contributed to idea and design of this research, writing—original draft & review & editing.

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Correspondence to Bo Liang.

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Cui, Y., Chaojie, L., Jiaqi, L. et al. Enhanced anti-corrosion and microwave absorption properties of novel binary titanium niobium nitrides nanofiber. J Mater Sci: Mater Electron 35, 337 (2024). https://doi.org/10.1007/s10854-024-12114-5

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