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Z-type Bi2O2CO3/NH2-MIL-125(Ti) heterojunction for efficient photocatalytic degradation of tetracycline

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Abstract

The spherical heterojunction Bi2O2CO3/NH2-MIL-125(Ti)(BOC/NMLT) composite photocatalytic materials were prepared by hydrothermal method. Under simulated visible light conditions, Bi2O2CO3/NH2-MIL-125(Ti)-5 (BOC/NMLT-5) had the best degradation performance of tetracycline (TC), and the degradation rate of TC reached 85.6% within 90 min, which was 10.4 times and 3.2 times that of pure NMLT and Bi2O2CO3, respectively. The characterization results show that Bi2O2CO3/NH2-MIL-125(Ti)-5 has a larger specific surface area, a wider light corresponding range, and a higher electron–hole transfer efficiency than the monomer Bi2O2CO3. The results of free radical quenching experiments show that h+ and ·O2− are the main active substances for the degradation of TC by Bi2O2CO3/NH2-MIL-125(Ti)-5, and the Z-type electron transfer mechanism of TC degradation in BOC/NMLT system is proposed.

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Funding

This work was supported by the Postgraduate Research & Practice Innovation Program of Jiangsu Province, China (SJCX22_1372).

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Authors and Affiliations

  1. School of Environmental Science and Engineering, Changzhou University, Changzhou, 213164, China

    Jiacheng Jin, Hao Hu, Mingchen Xu, Yanzhi Yang, Wenlou Jin, Zhipeng Zhang, Fan Dong, Min Shao & Yushan Wan

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  1. Jiacheng Jin
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  2. Hao Hu
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  9. Yushan Wan
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Hao Hu, Jiacheng Jin and Mingchen Xu. The first draft of the manuscript was written by Jiacheng Jin and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Yushan Wan.

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Jin, J., Hu, H., Xu, M. et al. Z-type Bi2O2CO3/NH2-MIL-125(Ti) heterojunction for efficient photocatalytic degradation of tetracycline. J Mater Sci: Mater Electron 35, 295 (2024). https://doi.org/10.1007/s10854-024-11963-4

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