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Influence of green laser light on the structural and optical properties of Mg-, Mn-, and Mn + Mg-doped copper oxide nanoparticles prepared by spin coating

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Abstract

The study explores the impact of green laser light in a spin coating system on the structural, optical, and vibrational properties of CuO nanoparticles doped with Mn-, Mg-, and Mn + Mg-doped CuO. The investigation aims to understand how the introduction of dopant elements and subsequent exposure to green laser light influence a nanostructure’s properties. Structural analysis involves examining changes in the crystal structure, morphology, optical, and vibrational properties of doped CuO with or without laser exposure. X-ray diffractometry (XRD), scanning electron microscopy (SEM), UV–visible spectroscopy, and Fourier transforms infrared spectroscopy (FTIR) were used to characterize Mn-, Mg-, and Mn + Mg-doped CuO nanoparticles before and after illumination during deposition. The UV–visible absorption spectra of CuO have blue shifted and it decreased in size owing to the quantum-confinement effect and the effect of laser on surface morphology. The surface of CuO, Mn-, Mg-, and Mn + Mg-doped CuO was extremely smooth, dense, and small in size when the laser source was used during deposition; these results were confirmed by SEM. The presence of Mg-,Mn-, and Mn + Mg in the CuO was confirmed by the characteristic peaks within the 400–600 cm−1 regions of the FTIR spectra after illumination during deposition. These findings indicated that nanoparticles with improved optical and structural properties for certain technological applications can be fabricated by customizing doping concentrations and laser parameters. Moreover, a laser source can aid in the design and production of high-quality CuO through the deposition of a spin-coating system and plays an important role in fabricating metal-doped CuO.

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All data and material collected are presented in the manuscript. Clarification on any matter can be made through the corresponding author.

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Acknowledgements

The Nanoscience Lab in the Physics Department, College of Science, Salahaddin University generously offered the cutting-edge facilities necessary for the preparation and characterization of materials addressed in this research study. The assistance provided by them has greatly enhanced the quality of our work.

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The study did not receive any funding.

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Authors and Affiliations

  1. Department of Physics, College of Science, Salahaddin University, Erbil, 44001, Iraq

    Mahera M.Esmaeel, NasihH. Hmasalah & Shaida A. Kakil

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  1. Mahera M.Esmaeel
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  2. NasihH. Hmasalah
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  3. Shaida A. Kakil
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Contributions

MME designed the experiments and drafted the manuscript. NHH reviewed the literature and assisted with data collection SAk contributed to data analysis, provided critical input during manuscript revisions, and approved the final version.

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Correspondence to Shaida A. Kakil.

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M.Esmaeel, M., Hmasalah, N. & Kakil, S.A. Influence of green laser light on the structural and optical properties of Mg-, Mn-, and Mn + Mg-doped copper oxide nanoparticles prepared by spin coating. J Mater Sci: Mater Electron 35, 178 (2024). https://doi.org/10.1007/s10854-023-11919-0

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