Skip to main content
Log in

Bending tailored conducting behavior in freestanding La0.67Sr0.33MnO3 (LSMO) film

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Bending is one of the most common scenes for wearable devices based on functional films. In this work, we use a modified method to peel off La0.67Sr0.33MnO3 (LSMO) film and transfer it onto soft polyethylene terephthalate (PET) to get freestanding LSMO film. The conducting test is performed under different bending curvature, which provides strain with different magnitudes, and the change in results is analyzed as the bending curvature increases. The mechanism is analyzed, and we do believe the work is sort of meaningful in flexible device preparation, as well as the theoretical analysis in oxide electronic field.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

Data availability

All data in this manuscript are available upon reasonable request.

References

  1. A.K. Geim, Graphene: status and prospects. Science 324, 1530–1534 (2009)

    Article  CAS  Google Scholar 

  2. H. Yin, X.D. Zhang, J.W. Lu, X.M. Geng, Y.F. Wan, M.Z. Wu, P. Yang, Substrate effects on the CVD growth of MoS2 and WS2. J. Mater. Sci. 55, 990–996 (2020)

    Article  CAS  Google Scholar 

  3. H. Yin, D.F. Hu, X.M. Geng, H. Liu, Y.F. Wan, P. Yang, 2D gold supercrystal-MoS2 hybrids: photoluminescence quenching. Mater. Lett. 255, 126531 (2019)

    Article  CAS  Google Scholar 

  4. K.S. Novoselov, V.I. Fal’ko, L. Colombo, P.R. Gellert, M.G. Schwab, K. Kim, A roadmap for graphene. Nature 490, 192–200 (2012)

    Article  CAS  Google Scholar 

  5. M. Li, H.J. Dong, X.Y. Wei, R.S. Yang, H. Yin, S.H. Wang, K.X. Jin, Ferroelectricity-like polarization and metallicity at GdAlO3/SrTiO3 heterointerfaces. J. Phys. Chem. C 126, 611–616 (2022)

    Article  CAS  Google Scholar 

  6. H. Xing, X.L. Dong, H.J. Wu, G.H. Hao, J.Y. Wang, C.L. Chen, K.X. Jin, Degenerate seaweed to tilted dendrite transition and their growth dynamics in directional solidification of non-axially oriented crystals: a phase-field study. Sci. Rep. 6, 26625 (2016)

    Article  CAS  Google Scholar 

  7. H. Yan, Z.T. Zhang, S.H. Wang, X.Y. Wei, C.L. Chen, K.X. Jin, Magnetism control by doping in LaAlO3/SrTiO3 heterointerfaces. ACS Appl. Mater. Interfaces 10, 14209–14213 (2018)

    Article  CAS  Google Scholar 

  8. K. Ueno, S. Nakamura, H. Shimotani, H.T. Yuan, N. Kimura, T. Nojima, H. Aoki, Y. Iwasa, M. Kawasaki, Discovery of superconductivity in KTaO3 by electrostatic carrier doping. Nat. Nanotechnol. 6, 408–412 (2011)

    Article  CAS  Google Scholar 

  9. R. Peng, X.P. Shen, X. Xie, H.C. Xu, S.Y. Tan, M. Xia, T. Zhang, H.Y. Cao, X.G. Gong, J.P. Hu, B.P. Xie, D.L. Feng, Measurement of an enhanced superconducting phase and a pronounced anisotropy of the energy gap of a strained FeSe single layer in FeSe/Nb:SrTiO3/KTaO3. Phys. Rev. Lett. 112, 107001 (2014)

    Article  CAS  Google Scholar 

  10. Y.Q. Wang, Z.T. Zhang, J.L. Cheng, Q.Y. Zhang, W. Tang, K.S. Yang, Creating a two-dimensional hole gas in a polar/polar LaAlO3/KTaO3 perovskite heterostructure. J. Mater. Chem. C 8, 14230–14237 (2020)

    Article  CAS  Google Scholar 

  11. H.J. Kim, S.I. Yoo, Enhanced low field magnetoresistance in La0.7Sr0.3MnO3-La2O3 composites. J. Alloys Compd. 521, 30–34 (2012)

    Article  CAS  Google Scholar 

  12. A. Sadoc, B. Mercey, C. Simon, D. Grebille, W. Prellier, M.-B. Lepetit, Large increase of the curie temperature by orbital ordering control. Phys. Rev. Lett. 104, 046804 (2010)

    Article  Google Scholar 

  13. M. Cesaria, A.P. Caricato, G. Maruccio, M. Martino, LSMO-growing opportunities by PLD and applications in spintronics. J. Phys. 292, 012003 (2011)

    Google Scholar 

  14. H.P. Xie, H. Huang, N.T. Cao, C.H. Zhou, D.M. Niu, Y.L. Gao, Effects of annealing on structure and composition of LSMO thin films. Physica B 477, 14–19 (2015)

    Article  CAS  Google Scholar 

  15. C.H. Yan, Z.G. Xu, T. Zhu, Z.M. Wang, F.X. Cheng, Y.H. Huang, C.S. Liao, A large low field colossal magnetoresistance in the La0.7Sr0.3MnO3 and CoFe2O4 combined system. J. Appl. Phys. 87, 5588 (2000)

    Article  CAS  Google Scholar 

  16. J.J. Huang, H. Wang, X. Sun, X.H. Zhang, H.Y. Wang, Multifunctional La0.67Sr0.33MnO3 (LSMO) thin films integrated on mica substrates toward flexible spintronics and electronics. ACS Appl. Mater. Interfaces 10, 42698–42705 (2018)

    Article  CAS  Google Scholar 

  17. Z.F. Duan, Y. Cui, X.J. Shi, J.N. Wei, P.R. Ren, G.Y. Zhao, Facile fabrication of micro-patterned LSMO films with unchanged magnetic properties by photosensitive sol-gelmethod on LaAlO3 substrates. Ceram. Int. 42, 14100–14106 (2016)

    Article  CAS  Google Scholar 

  18. I. Tenreiro, V. Rouco, G. Sanchez-Santolino, F. Gallego, C. Leon, A. Rivera-Calzada, I.K. Schuller, J. Santamaria, Photovoltaic sensing of a memristor based in LSMO/BTO/ITO ferroionic tunnel junctions. Appl. Phys. Lett. 120, 034101 (2022)

    Article  CAS  Google Scholar 

  19. D. Lu, D.J. Baek, S.S. Hong, L.F. Kourkoutis, Y. Hikita, H.Y. Hwang, Synthesis of freestanding single-crystal perovskite films and heterostructures by etching of sacrificial water-soluble layers. Nat. Mater. 15, 1255–1260 (2016)

    Article  CAS  Google Scholar 

  20. Z.X. Lu, J.W. Liu, J.T. Feng, X. Zheng, L.H. Yang, C. Ge, K.J. Jin, Z.M. Wang, R.W. Li, Synthesis of single-crystal La0.67Sr0.33MnO3 freestanding films with different crystal-orientation. APL Mater. 8, 051105 (2020)

    Article  CAS  Google Scholar 

  21. S.S. Hong, M.Q. Gu, M. Verma, V. Harbola, B.Y. Wang, D. Lu, A. Vailionis, Y. Hikita, R. Pentcheva, J.M. Rondinelli, H.Y. Hwang, Extreme tensile strain states in La0.7Ca0.3MnO3 membranes. Science 368, 71–76 (2020)

    Article  CAS  Google Scholar 

  22. J.J. Huang, H. Wang, X. Sun, X.H. Zhang, H.Y. Wang, Multifunctional La0.67Sr0.33MnO3 (LSMO) thin films integrated on mica substrates towards flexible spintronics and electronics. ACS Appl. Mater. Interfaces 10, 42698–42705 (2018)

    Article  CAS  Google Scholar 

  23. R. Guo, L. You, W.N. Lin, A. Abdelsamie, X.Y. Shu, G.W. Zhou, S.H. Chen, L. Liu, X.B. Yan, J.L. Wang, J.S. Chen, Continuously controllable photoconductance in freestanding BiFeO3 by the macroscopic flexoelectric effect. Nat. Commun. 11, 2571 (2020)

    Article  CAS  Google Scholar 

  24. B. Peng, R.C. Peng, Y.Q. Zhang, G.H. Dong, Z.Y. Zhou, Y.Q. Zhou, T. Li, Z.J. Liu, Z.L. Luo, S.H. Wang, Y. Xia, R.B. Qiu, X.X. Cheng, F. Xue, Z.Q. Hu, W. Ren, Z.G. Ye, L.Q. Chen, Z.W. Shan, T. Min, M. Liu, Phase transition enhanced superior elasticity in freestanding single-crystalline multiferroic BiFeO3 membranes. Sci. Adv. 6, aba5847 (2020)

    Article  Google Scholar 

  25. A. Sambri, A. Scuderi, A. Guarino, E.D. Gennaro, R. Erlandsen, R.T. Dahm, A.V. Bjorlig, D.V. Christensn, R.D. Capua, B.D. Ventura, U.S.D. Uccio, S. Mirabella, G. Nicotra, C. Spinella, T.S. Jespersen, F.M. Granozio, Self-formed, conducting LaAlO3/SrTiO3 micro-membranes. Adv. Funct. Mater. 30, 1909964 (2020)

    Article  CAS  Google Scholar 

  26. G.H. Dong, S.Z. Li, T. Li, H.J. Wu, T.X. Nan, X.H. Wang, H.X. Liu, Y.X. Cheng, Y.Q. Zhou, W.B. Qu, Y.F. Zhao, B. Peng, Z.G. Wang, Z.Q. Hu, Z.L. Luo, W. Ren, S.J. Pennycook, J. Li, J. Sun, Z.G. Ye, Z.D. Jiang, Z.Y. Zhou, X.D. Ding, T. Min, M. Liu, Periodic wrinkle-patterned-crystalline ferroelectric oxide membranes with enhanced piezoelectricity. Adv. Mater. 32, 2004477 (2020)

    Article  CAS  Google Scholar 

  27. M. Li, H. Yan, Z.T. Zhang, L.X. Ren, J. Zhao, S.H. Wang, C.L. Chen, K.X. Jin, Quasi-two-dimensional electron gas at γ-Al2O3/SrTiO3 heterointerfaces fabricated by spin coating method. J. Appl. Phys. 124, 145301 (2018)

    Article  Google Scholar 

  28. M. Li, Z.T. Zhang, H. Yan, L.X. Ren, J. Zhao, S.H. Wang, K.X. Jin, Creation and control of quasi-two dimensional electron gas at yttrium aluminum oxides/strontium titanate heterointerfaces by spin coating. Phys. Lett. A 384, 126283 (2020)

    Article  CAS  Google Scholar 

  29. Z.Y. Chen, B.Y. Wang, B.H. Goodge, D. Lu, S.S. Hong, D.F. Li, L.F. Kourkoutis, Y. Hikita, H.H. Hwang, Freestanding crystalline YBa2Cu3O7-x heterostructure membranes. Phys. Rev. Mater 3, 060801 (2019)

    Article  CAS  Google Scholar 

  30. H. Wang, L.K. Chen, T.Z. Duan, C.R. Ma, C.M. Cao, C.J. Jiang, X.L. Lu, H.Y. Sun, M. Liu, Integration of both invariable and tunable microwave magnetisms in a single flexible La0.67Sr0.33MnO3 thin film. ACS Appl. Interfaces 11, 22677–22683 (2019)

    Article  CAS  Google Scholar 

  31. R.J. Xu, J.W. Huang, E.S. Barnard, S.S. Hong, P. Singh, E.K. Wong, T. Jansen, V. Harbola, J. Xiao, B.Y. Wang, S. Crossley, D. Lu, S. Liu, H.Y. Hwang, Strain-induced room-temperature ferroelectricity in SrTiO3 membranes. Nat. Commun. 11, 3141 (2020)

    Article  CAS  Google Scholar 

  32. J. Kreisel, G. Lucazeau, C. Dubourdieu, M. Rosina, F. Weiss, Raman scattering study of La0.7Sr0.3MnO3/SrTiO3 multilayers. J. Phys. 14, 5201–5210 (2002)

    CAS  Google Scholar 

  33. R. Ren, Y.J. Ren, X. Li, L. Bai, Carrier transport spin-orbit dynamics in surface enhanced Raman shift of perovskite films. J. Alloys Compd. 662, 290–295 (2016)

    Article  CAS  Google Scholar 

  34. A.H. Zhang, Q. Li, D. Wang, Y. Zhang, Y.S. Li, M. Zeng, X.B. Lu, J.M. Liu, Epitaxial strain tunable conductivity and charge transport of Ba0.6La0.4TiO3 thin films deposited by pulsed laser deposition. J. Appl. Phys. 129, 025106 (2021)

    Article  CAS  Google Scholar 

  35. Y. Sun, X.J. Xu, Y.H. Zhang, Variable-range hopping of small polarons in mixed-valence manganites. J. Phys. 12, 10475 (2000)

    CAS  Google Scholar 

  36. T. Kolodiazhnyi, S.C. Wimbush, Spin-singlet small bipolarons in Nb-Doped BaTiO3. Phys. Rev. Lett. 96, 246404 (2006)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work is supported by the National Natural Science Foundation of China (No. 51572222, 52373253, 12374192) and Key Research Project of the Natural Science Foundation of Shaanxi Province, China (Grant Nos. 2021JZ-08 and 2020JM-088), and Natural Science Foundation of Shaanxi Province, China (Grant No. 2023-JC-YB-074).

Author information

Authors and Affiliations

Authors

Contributions

All authors contributed to the study conception and design. Experimental data collection, analysis, and writing are performed by HY. Funding, resources, and manuscript’s structural design are provided by KJ and SW. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Kexin Jin.

Ethics declarations

Conflict of interest

The authors declare no conflicts of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yin, H., Lv, J., Wang, S. et al. Bending tailored conducting behavior in freestanding La0.67Sr0.33MnO3 (LSMO) film. J Mater Sci: Mater Electron 35, 90 (2024). https://doi.org/10.1007/s10854-023-11866-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10854-023-11866-w

Navigation