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Synthesis of Ag nanowires with an aspect ratio higher than 2000 for the fabrication of transparent conductive film

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Abstract

Silver nanowires (AgNWs) are promising materials in the fabrication of flexible and transparent conductive thin films (FTCFs), which are key components of flexible optoelectronic devices. However, the performance of AgNW FTCFs is severely limited by their low aspect ratio, and the fabrication of AgNWs with a high aspect ratio remains a significant challenge. In this study, AgNWs with a diameter of 40 nm and aspect ratio of 2000 were synthesized rapidly by controlling the total molar concentration of Cl− ions in the reaction solution by a typical polyol method to adjust the Cu2+/Fe3+ molar ratio. Subsequently, AgNW FTCFs were fabricated by the coating method using hydroxyethyl cellulose (HEC). The films exhibited a low sheet resistance of 68 Ω/sq and transmittance of 86.70%, which are comparable to those of typical indium tin oxide electrodes. Meanwhile, a mechanical robustness test showed that the sheet resistance of the AgNW-HEC films increased by only 3.15% even after 3000 bending cycles.

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References

  1. L. Lin, Y. Choi, T. Chen, H. Kim, K.S. Lee, J.M. Kang, L. Lyu, J.F. Gao, Y. Piao, Superhydrophobic and wearable TPU based nanofiber strain sensor with outstanding sensitivity for high-quality body motion monitoring. Chem. Eng. J. 419, 129513 (2021)

    Article  CAS  Google Scholar 

  2. A.R. Madaria, A. Kumar, C. Zhou, Large scale, highly conductive and patterned transparent films of silver nanowires on arbitrary substrates and their application in touch screens. Nanotechnology 22, 245201 (2011)

    Article  Google Scholar 

  3. A. Moradi, M. Abrari, M. Ahmadi, Efficiency enhancement in dye-sensitized solar cells through the decoration of electro-spun TiO(2)nanofibers with ag nanoparticles. J. Mater. Sci. Mater. Electron. 31, 16759–16768 (2020)

    Article  CAS  Google Scholar 

  4. Z.-R. Zhu, W. Geng, Q. Zhu, A.S. Ethiraj, T. Wang, L.-C. Jing, Y.-J. Ning, Y. Tian, W.-H. Geng, L. Wu, H.-Z. Geng, Highly transparent, low sheet resistance and stable tannic acid modified-SWCNT/AgNW double-layer conductive network for organic light emitting diodes. Nanotechnology 32, 015708 (2021)

    Article  CAS  Google Scholar 

  5. H. Lee, D. Lee, Y. Ahn, E.-W. Lee, L.S. Park, Y. Lee, Highly efficient and low voltage silver nanowire-based OLEDs employing a n-type hole injection layer. Nanoscale 6, 8565–8570 (2014)

    Article  CAS  Google Scholar 

  6. W. Dong, C. Zhu, W. Hu, L. Xiao, Y. Huang, Stretchable human-machine interface based on skin-conformal sEMG electrodes with self-similar geometry. J. Semicond. 39, 014001–014001 (2018)

    Article  Google Scholar 

  7. M. Saychak, N. Borodinov, R. Burtovyy, M. Anayee, K. Hu, R. Ma, A. Grant, H. Li, D.B. Cutshall, Y. Wen, G. Koley, W.R. Harrell, G. Chumanov, V. Tsukruk, I. Luzinov, Highly conductive and transparent reduced graphene oxide nanoscale films via thermal conversion of polymer-encapsulated graphene oxide sheets. ACS Appl. Mater. Interfaces 10, 3975–3985 (2018)

    Article  Google Scholar 

  8. D.H. Shin, S.W. Seo, J.M. Kim, H.S. Lee, S.-H. Choi, Graphene transparent conductive electrodes doped with graphene quantum dots-mixed silver nanowires for highly-flexible organic solar cells. J. Alloys Compd. 744, 1–6 (2018)

    Article  CAS  Google Scholar 

  9. Y. Chen, X.-Y. Fu, Y.-Y. Yue, N. Zhang, J. Feng, H.-B. Sun, Flexible and transparent supercapacitor based on ultrathin Au/graphene composite electrodes. Appl. Surf. Sci. 467, 104–111 (2019)

    Article  Google Scholar 

  10. J. Ning, L. Hao, M. Jin, X. Qiu, Y. Shen, J. Liang, X. Zhang, B. Wang, X. Li, L. Zhi, A facile reduction method for roll-to-roll production of high performance graphene-based transparent conductive films. Adv. Mater. 29, 1605028 (2017)

    Article  Google Scholar 

  11. A.A. Tonkikh, V.I. Tsebro, E.A. Obraztsova, D.V. Rybkovskiy, A.S. Orekhov, I.I. Kondrashov, E.I. Kauppinen, A.L. Chuvilin, E.D. Obraztsova, Films of filled single-wall carbon nanotubes as a new material for high-performance air-sustainable transparent conductive electrodes operating in a wide spectral range. Nanoscale 11, 6755–6765 (2019)

    Article  CAS  Google Scholar 

  12. O. Urper, I. Cakmak, N. Karatepe, Fabrication of carbon nanotube transparent conductive films by vacuum filtration method. Mater. Lett. 223, 210–214 (2018)

    Article  CAS  Google Scholar 

  13. P. Zhao, Q. Tang, X. Zhao, Y. Tong, Y. Liu, Highly stable and flexible transparent conductive polymer electrode patterns for large-scale organic transistors. J. Colloid Interface Sci. 520, 58–63 (2018)

    Article  CAS  Google Scholar 

  14. J. Yang, C.X. Bao, K. Zhu, T. Yu, Q.Y. Xu, High-performance transparent conducting metal network electrodes for perovksite photodetectors. ACS Appl. Mater. Interfaces 10, 1996–2003 (2018)

    Article  CAS  Google Scholar 

  15. X.S. Li, Y.M. Wang, C.R. Yin, Z.X. Yin, Copper nanowires in recent electronic applications: progress and perspectives. J. Mater. Chem. C 8, 849–872 (2020)

    Article  CAS  Google Scholar 

  16. Y. Li, Y. Li, Z. Fan, H. Yang, X. Yuan, C. Wang, Ascorbic acid-assisted one-step chemical reaction to design an ultralong silver nanowire structure for a highly transparent flexible conducting Film. ACS Omega 5, 18458–18464 (2020)

    Article  CAS  Google Scholar 

  17. J. Lee, P. Lee, H.B. Lee, S. Hong, I. Lee, J. Yeo, S.S. Lee, T.S. Kim, D. Lee, S.H. Ko, Room-temperature nanosoldering of a very long metal nanowire network by conducting-polymer-assisted joining for a flexible touch-panel application. Adv. Funct. Mater. 23, 4171–4176 (2013)

    Article  CAS  Google Scholar 

  18. R.M. Mutiso, M.C. Sherrott, A.R. Rathmell, B.J. Wiley, K.I. Winey, Integrating simulations and experiments to predict sheet resistance and optical transmittance in nanowire films for transparent conductors. ACS Nano 7, 7654–7663 (2013)

    Article  CAS  Google Scholar 

  19. R.R. da Silva, M. Yang, S.-I. Choi, M. Chi, M. Luo, C. Zhang, Z.-Y. Li, P.H.C. Camargo, S.J. Lima Ribeiro, Y. Xia, Facile synthesis of Sub-20 nm silver nanowires through a bromide-mediated polyol method. ACS Nano 10, 7892–7900 (2016)

    Article  Google Scholar 

  20. Z. Chen, J.W. Chang, C. Balasanthiran, S.T. Milner, R.M. Rioux, Anisotropic growth of silver nanoparticles is kinetically controlled by polyvinylpyrrolidone binding. J. Am. Chem Soc 141, 4328–4337 (2019)

    Article  CAS  Google Scholar 

  21. Y.G. Sun, Y.D. Yin, B.T. Mayers, T. Herricks, Y.N. Xia, Uniform silver nanowires synthesis by reducing AgNO3 with ethylene glycol in the presence of seeds and poly(vinyl pyrrolidone). Chem. Mater. 14, 4736–4745 (2002)

    Article  CAS  Google Scholar 

  22. M. Jia-qing, H. Jun-wei, Template-directed synthesis of Ag nanowire arrays by a simple paired cell method for SERS. Optoelectron. Lett. 11, 401–404 (2015)

    Article  Google Scholar 

  23. X.J. Xu, G.T. Fei, X.W. Wang, Z. Jin, W.H. Yu, L.D. Zhang, Synthetic control of large-area, ordered silver nanowires with different diameters. Mater. Lett. 61, 19–22 (2007)

    Article  CAS  Google Scholar 

  24. L. Lin, L. Liu, P. Peng, G. Zou, W.W. Duley, Y.N. Zhou, In situ nanojoining of Y- and T-shaped silver nanowires structures using femtosecond laser radiation. Nanotechnology 27, 125201 (2016)

    Article  Google Scholar 

  25. Y. Chen, Y. Zhang, J. Chen, X. Sun, Understanding the influence of crystallographic structure on controlling the shape of noble metal nanostructures. Cryst. Growth Des. 11, 5457–5460 (2011)

    Article  CAS  Google Scholar 

  26. W.C. Zhang, X.L. Wu, H.T. Chen, Y.J. Gao, J. Zhu, G.S. Huang, P.K. Chu, Self-organized formation of silver nanowires, nanocubes and bipyramids via a solvothermal method. Acta Mater. 56, 2508–2513 (2008)

    Article  CAS  Google Scholar 

  27. Y.G. Sun, B. Mayers, T. Herricks, Y.N. Xia, Polyol synthesis of uniform silver nanowires: a plausible growth mechanism and the supporting evidence. Nano Lett. 3, 955–960 (2003)

    Article  CAS  Google Scholar 

  28. X.-M. Wang, L. Chen, E. Sowade, R.D. Rodriguez, E. Sheremet, C.-M. Yu, R.R. Baumann, J.-J. Chen, Ultra-uniform and very thin Ag nanowires synthesized via the synergy of Cl–, Br– and Fe3+ for transparent conductive films. Nanomaterials 10, 237 (2020)

    Article  CAS  Google Scholar 

  29. J.-J. Chen, S.-L. Liu, H.-B. Wu, E. Sowade, R.R. Baumann, Y. Wang, F.-Q. Gu, C.-R.-L. Liu, Z.-S. Feng, Structural regulation of silver nanowires and their application in flexible electronic thin films. Mater. Des. 154, 266–274 (2018)

    Article  CAS  Google Scholar 

  30. K. Zhan, R. Su, S. Bai, Z. Yu, N. Cheng, C. Wang, S. Xu, W. Liu, S. Guo, X.-Z. Zhao, One-pot stirring-free synthesis of silver nanowires with tunable lengths and diameters via a Fe3+ & Cl– co-mediated polyol method and their application as transparent conductive films. Nanoscale 8, 18121–18133 (2016)

    Article  CAS  Google Scholar 

  31. N. Xiao, Y. Chen, W. Weng, X. Chi, H. Chen, D. Tang, S. Zhong, Mechanism understanding for size regulation of silver nanowires mediated by halogen ions. Nanomaterials 12, 2681 (2022)

    Article  CAS  Google Scholar 

  32. Y. Mao, H. Yang, C. Hu, J. Guo, X. Meng, Y. Yang, Large-scale synthesis of AgNWs with ultra-high aspect ratio above 4000 and their application in conductive thin film. J. Mater. Sci. Mater. Electron. 28, 5308–5314 (2017)

    Article  CAS  Google Scholar 

  33. C. Liu, X. Zhang, J. Shan, Z. Li, X. Guo, X. Zhao, H. Yang, Large-scale preparation of silver nanowire-based flexible transparent film heaters by slot-die coating. Materials 15, 2634 (2022)

    Article  CAS  Google Scholar 

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Acknowledgements

This work is supported by the Science and Technology Project of Jiaxing (2022AY10005); Science and Technology Project of Jiaxing (2019AY11018); General scientific research project of Zhejiang Education Department (Y202250333).

Funding

This research is funded by the Science and Technology Project of Jiaxing (2022AY10005); Science and Technology Project of Jiaxing (2019AY11018); General scientific research project of Zhejiang Education Department (Y202250333).

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Authors and Affiliations

  1. College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou, 310014, Zhejiang, China

    Hezheng Ao, Peng Cao & Tao Yang

  2. College of Mechanical and Electronic Engineering, Jiaxing Nanhu University, Jiaxing, 314001, China

    Junyan Feng

  3. College of Information Science and Engineering, Jiaxing University, Jiaxing, 314000, China

    Tao Shang & Bo Xing

Authors
  1. Hezheng Ao
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  2. Junyan Feng
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  3. Peng Cao
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  4. Tao Yang
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  5. Tao Shang
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  6. Bo Xing
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Contributions

HZA: investigation, data curation, writing-original draft preparation, writing-review and editing, formal analysis. JYF: conceptualization, investigation, methodology, validation, data curation, writing-review and editing, resources, supervision, project administration. PC: investigation, data curation, formal analysis. TY: investigation, data curation, formal analysis. TS: formal analysis. BX: review and editing, formal analysis, funding acquisition.

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Correspondence to Junyan Feng or Bo Xing.

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Ao, H., Feng, J., Cao, P. et al. Synthesis of Ag nanowires with an aspect ratio higher than 2000 for the fabrication of transparent conductive film. J Mater Sci: Mater Electron 34, 2183 (2023). https://doi.org/10.1007/s10854-023-11579-0

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