Abstract
In the present work, we employed BaTiO3 powder as tribocatalyst for removing dye, a representative pollutant from the water via tribocatalysis process. In tribocatalysis experiments, it was demonstrated that BaTiO3 powder acting as a tribocatalyst, can effectively eliminates organic dyes due to the triboelectric effect occurring between glass and PTFE/Teflon interface. Additionally, the tribocatalytic performance of BaTiO3 powder was also investigated by varying the size and speed of the used PTFE. The maximum degradation for Methylene Blue (MB) and Rhodamine B (RB) dyes was ∼ 57 and ∼ 82% in 12 h, respectively. This work not only establishes an environmentally friendly method for the oxidative purification of organic contamination but also presents a hopeful approach which could be used in sustainable energy production and environmental remediation.
Similar content being viewed by others
Data availability
The data that supports the findings of this study are available within the article.
References
F.R. Fan, W. Tang, Z.L. Wang, Flexible nanogenerators for energy harvesting and self-powered electronics. Adv. Mater. 28(22), 4283–4305 (2016)
F.-R. Fan, Z.-Q. Tian, Z.L. Wang, Flexible triboelectric generator. Nano Energy. 1(2), 328–334 (2012)
Z.L. Wang, J. Song, Piezoelectric nanogenerators based on zinc oxide nanowire arrays. Science 312(5771), 242–246 (2006)
S. Xu et al., A coupled photo-piezo-catalytic effect in a BST-PDMS porous foam for enhanced dye wastewater degradation. Nano Energy. 77, 105305 (2020)
M. Sharma, R. Vaish, Vibration energy harvesting for degradation of dye and bacterial cells using cement-based Ba0. 85Ca0. 15Zr0. 1Ti0. 90O3 composites. Mater. Today Commun. 25, 101592 (2020)
S. Lan, Y. Chen, L. Zeng, H. Ji, W. Liu, M. Zhu, Piezo-activation of peroxymonosulfate for benzothiazole removal in water. J. Hazard. Mater. 393, 122448 (2020)
A. Zhang et al., Vibration catalysis of eco-friendly Na0. 5K0. 5NbO3-based piezoelectric: an efficient phase boundary catalyst. Appl. Catal. B Environ. 279, 119353 (2020)
W. Feng et al., Piezopotential-driven simulated electrocatalytic nanosystem of ultrasmall MoC quantum dots encapsulated in ultrathin N-doped graphene vesicles for superhigh H2 production from pure water. Nano Energy 75, 104990 (2020)
X. Xu et al., Harvesting vibration energy to piezo-catalytically generate hydrogen through Bi2WO6 layered-perovskite. Nano Energy. 78, 105351 (2020)
L. Chen et al., Strong piezocatalysis in barium titanate/carbon hybrid nanocomposites for dye wastewater decomposition. J. Colloid Interface Sci. 586, 758–765 (2021)
M. Sharma, G. Singh, R. Vaish, Dye degradation and bacterial disinfection using multicatalytic BaZr0. 02Ti0. 98O3 ceramics. J. Am. Ceram. Soc. 103(9), 4774–4784 (2020)
E. Lin, Z. Kang, J. Wu, R. Huang, N. Qin, D. Bao, BaTiO3 nanocubes/cuboids with selectively deposited Ag nanoparticles: efficient piezocatalytic degradation and mechanism. Appl. Catal. B Environ. 285, 119823 (2021)
D. Xia et al., Piezo-catalytic persulfate activation system for water advanced disinfection: process efficiency and inactivation mechanisms. Chem. Eng. J. 400, 125894 (2020)
Y. Wang, J.M. Wu, Effect of controlled oxygen vacancy on H2-production through the piezocatalysis and piezophototronics of ferroelectric R3C ZnSnO3 nanowires. Adv. Funct. Mater. 30(5), 1907619 (2020)
Y. Lin, S. Lai, J.M. Wu, Simultaneous piezoelectrocatalytic hydrogen-evolution and degradation of water pollutants by quartz microrods@ few‐layered MoS2 hierarchical heterostructures. Adv. Mater. 32(34), 2002875 (2020)
S.-E. Zhu, F. Li, G.-W. Wang, Mechanochemistry of fullerenes and related materials. Chem. Soc. Rev. 42(18), 7535–7570 (2013)
R. Zhang et al., The triboelectricity of the human body. Nano Energy. 86, 106041 (2021)
Z.L. Wang, Triboelectric nanogenerators as new energy technology for self-powered systems and as active mechanical and chemical sensors. ACS Nano. 7(11), 9533–9557 (2013)
D.K. Davies, Charge generation on dielectric surfaces. J. Phys. D Appl. Phys. 2(11), 1533 (1969)
P.E. Shaw, “Experiments on tribo-electricity. I.—The tribo-electric series.” Proc. R. Soc. London. Ser. A, Contain. Pap. a Math. Phys. Character 94(656), 16–33 (1917)
T. Ohta, Mechano-catalytic water-splitting. Appl. Energy. 67, 1–2 (2000)
T. Ohta, Efficiency of mechano-catalytic water-splitting system. Int. J. Hydrog. Energy 25(12), 1151–1156 (2000)
P. Li et al., Strong tribocatalytic dye decomposition through utilizing triboelectric energy of barium strontium titanate nanoparticles. Nano Energy. 63, 103832 (2019)
H. Lei et al., Tribo-catalytic degradation of organic pollutants through bismuth oxyiodate triboelectrically harvesting mechanical energy. Nano Energy. 78, 105290 (2020)
C. Porwal et al., Piezocatalytic dye degradation using Bi2O3–ZnO–B2O3 glass-nanocomposites. J. Mater. Res. Technol. 21, 2028–2037 (2022)
S. Verma, R. Vaish, Organic pollutants removal by quartz crystals. Int. J. Ceram. Eng. Sci. (2022). https://doi.org/10.1002/ces2.10161
A. Gaur, V.S. Chauhan, R. Vaish, Porous BaTiO3 ceramic with enhanced piezocatalytic activity for water cleaning application. Surf. Interfaces 36, 102497 (2022)
A. Gaur, M. Sharma, V.S. Chauhan, R. Vaish, “Solar/visible light photocatalytic dye degradation using BaTi1x–FexO3 ceramics,.” J. Am. Ceram. Soc (2022). https://doi.org/10.1111/jace.18514
M. Rastogi, H.S. Kushwaha, R. Vaish, Highly efficient visible light mediated azo dye degradation through barium titanate decorated reduced graphene oxide sheets. Electron. Mater. Lett. 12(2), 281–289 (2016)
A. Gajović, J.V. Pleština, K. Žagar, M. Plodinec, S. Šturm, M. Čeh, Temperature-dependent Raman spectroscopy of BaTiO3 nanorods synthesized by using a template‐assisted sol–gel procedure. J. Raman Spectrosc. 44(3), 412–420 (2013)
C.H. Perry, D.B. Hall, Temperature dependence of the Raman spectrum of BaTiO3. Phys. Rev. Lett. 15(17), 700 (1965)
U.D. Venkateswaran, V.M. Naik, R. Naik, High-pressure Raman studies of polycrystalline BaTiO3. Phys. Rev. B 58(21), 14256 (1998)
Y. Shiratori, C. Pithan, J. Dornseiffer, R. Waser, “Raman scattering studies on nanocrystalline BaTiO3 Part I—isolated particles and aggregates.” J. Raman Spectrosc. An Int. J. Orig. Work all Asp. Raman Spectrosc. Incl. High. Order Process. also Brillouin Rayleigh Scatt., 38(10), 1288–1299 (2007)
A. Kumar, C. Schuerings, S. Kumar, A. Kumar, V. Krishnan, Perovskite-structured CaTiO3 coupled with g-C3N4 as a heterojunction photocatalyst for organic pollutant degradation. Beilstein J. Nanotechnol. 9(1), 671–685 (2018)
M.A. Butler, D.S. Ginley, Prediction of flatband potentials at semiconductor-electrolyte interfaces from atomic electronegativities. J. Electrochem. Soc. 125(2), 228 (1978)
S.A. Nasser, X-ray photoelectron spectroscopy study on the composition and structure of BaTiO3 thin films deposited on silicon. Appl. Surf. Sci. 157, 1–2 (2000)
A. Gaur et al., Effect of Poling on Multicatalytic Performance of 0.5 ba (Zr0. 2Ti0. 8) O3-0.5 (Ba0. 7Sr0. 3) TiO3 ferroelectric ceramic for dye degradation. Mater. (Basel) 15(22), 8217 (2022)
N. Gunasekaran, S. Rajadurai, J.J. Carberry, N. Bakshi, C.B. Alcock, Surface characterization and catalytic properties of La1–xAxMO3 perovskite type oxides. Part I. studies on La0. 95Ba0. 05MO3 (M = mn, Fe or Co) oxides. ” Solid State Ionics 73, 3–4 (1994)
K. Wei et al., Photocatalytic properties of a new Z-scheme system BaTiO 3/In 2 S 3 with a core–shell structure. RSC Adv. 9(20), 11377–11384 (2019)
V. Craciun, R.K. Singh, Characteristics of the surface layer of barium strontium titanate thin films deposited by laser ablation. Appl. Phys. Lett. 76(14), 1932–1934 (2000)
B.H. Devmunde, S.B. Somwanshi, P.B. Kharat, M.B. Solunke, “Rare earth ion (La3+) doped BaTiO3 perovskite nanoceramics for spintronic applications.” J. Phys. Conference Ser. 1644(1), 12055 (2020)
X. Xiong, R. Tian, X. Lin, D. Chu, S. Li, “Formation and photocatalytic activity of BaTiO3 nanocubes via hydrothermal process.” J. Nanomater. (2015). https://doi.org/10.1155/2015/692182
W.R. Harper, Contact and frictional electrification (Laplacian Press, Morgan Hill, 1998)
M.N. Horenstein, J.-S. Chang, A.J. Kelly, J.M. Crowley, Measurement of electrostatic fields, voltages, and charges (Marcel Dekker, New York, 1995)
C. Hu, H. Huang, F. Chen, Y. Zhang, H. Yu, T. Ma, Coupling piezocatalysis and photocatalysis in Bi4NbO8X (X = cl, br) polar single crystals. Adv. Funct. Mater. 30(7), 1908168 (2020)
B. Baytekin, H.T. Baytekin, B.A. Grzybowski, What really drives chemical reactions on contact charged surfaces? J. Am. Chem. Soc. 134(17), 7223–7226 (2012)
Q. Tang et al., Enhanced tribocatalytic degradation of dye pollutants through governing the charge accumulations on the surface of ferroelectric barium zirconium titanate particles. Nano Energy. 100, 107519 (2022)
C. Sun et al., Tribocatalytic degradation of dyes by tungsten bronze ferroelectric ba2.5 Sr2.5 nb8 T2 O30 submicron particles. RSC Adv. 11(22), 13386–13395 (2021)
B. Yang et al., Enhanced tribocatalytic degradation using piezoelectric CdS nanowires for efficient water remediation. J. Mater. Chem. C 8(42), 14845–14854 (2020)
H. Lei, X. Cui, X. Jia, J. Qi, Z. Wang, W. Chen, Enhanced tribocatalytic degradation of Organic pollutants by ZnO nanoparticles of high crystallinity. Nanomaterials 13(1), 46 (2022)
Y. Xu, R. Yin, Y. Zhang, B. Zhou, P. Sun, X. Dong, “Unveiling the mechanism of frictional catalysis in water by Bi12tio20: charge transfer and contaminant decomposition path,” Available SSRN 4154956
C. Sun et al., Strong tribocatalytic dye degradation by tungsten bronze Ba4Nd2Fe2Nb8O30. Ceram. Int. 47(4), 5038–5043 (2021)
M. Wu, H. Lei, J. Chen, X. Dong, Friction energy harvesting on bismuth tungstate catalyst for tribocatalytic degradation of organic pollutants. J. Colloid Interface Sci. 587, 883–890 (2021)
A. Gaur, A.K. Moharana, C. Porwal, V.S. Chauhan, R. Vaish, Degradation of organic dyes by utilizing CaCu3Ti4O12 (CCTO) nanoparticles via tribocatalysis process. J. Ind. Eng. Chem. (2023). https://doi.org/10.1016/j.jiec.2023.08.048
S. Acharya, S. Mansingh, K.M. Parida, The enhanced photocatalytic activity of gC 3 N 4-LaFeO 3 for the water reduction reaction through a mediator free Z-scheme mechanism. Inorg. Chem. Front. 4(6), 1022–1032 (2017)
K.P. Singh, G. Singh, R. Vaish, Utilizing the localized surface piezoelectricity of centrosymmetric Sr1-xFexTiO3 (x ≤ 0.2) ceramics for piezocatalytic dye degradation. J. Eur. Ceram. Soc. 41(1), 326–334 (2021)
Funding
The authors have not disclosed any funding.
Author information
Authors and Affiliations
Contributions
All authors read and approved the final manuscript. AG: Methodology, experimentation, and writing original draft; CP: assisted in performing experiments, writing first draft; VSC: supervision, validation, writing first Draft, RV: Supervision, contributed to design experiments and planning.
Corresponding authors
Ethics declarations
Conflict of interest
The authors have no competing interests to declare that are relevant to this article.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Gaur, A., Porwal, C., Chauhan, V.S. et al. Tribocatalytic investigation of BaTiO3 for dye removal from water. J Mater Sci: Mater Electron 34, 2154 (2023). https://doi.org/10.1007/s10854-023-11511-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10854-023-11511-6