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A suitable approach to achieve functional (Bi, Na)TiO3-based lead-free piezoceramics via compositional design for energy storage applications

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Abstract

In this work, sodium bismuth titanate based lead-free piezoceramics with modifiable dielectric and energy storage properties by compositional modification through Nb doping (0.94Bi0.5Na0.5TiO3–0.06BaTiO3–xNb2O5) were obtained. Nb doping on 0.94Bi0.5Na0.5TiO3–0.06BaTiO3-based ceramics produces a bifunctional behavior, which is governed by controlling the structural and microstructural characteristics of the system. Whereby the incorporation of Nb+5 leads to a change from rhombohedral–tetragonal (R–T) multiphasic coexistence to a tetragonal (T) phase at room temperature (RT) and causes a decrease in average grain size. The particularly high piezoelectric coefficient (d33), in the R–T multiphase coexistence region, facilitates the polarization and leads to a higher piezoelectric response than in the T-region. Meanwhile, increasing the Nb content improves the energy storage properties and results in a storage of energy value (Wrec) up to about 0.50 J/cm3 at room temperature.

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Funding

The Spanish Ministry of Economy and Competitiveness (MINECO) provided support for this work under project PID2020-114192RB-C41. FR-M received financial assistance from the Comunidad de Madrid for the “Doctorados Industriales” project (IND2020/IND-17375), co-financed by the European Social Fund. MD, MC, LR would like to express their gratitude for the support they received from CONICET and the National University of Mar del Plata (Argentina).

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Authors and Affiliations

  1. Institute of Research in Materials Science and Technology (INTEMA), B7606BWV, Mar del Plata, Argentina

    Mauro Difeo, Miriam Castro & Leandro Ramajo

  2. Institute of Ceramics and Glass (CSIC), 28049, Madrid, Spain

    Fernando Rubio-Marcos & Adolfo Del Campo

Authors
  1. Mauro Difeo
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  2. Fernando Rubio-Marcos
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  3. Adolfo Del Campo
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  4. Miriam Castro
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  5. Leandro Ramajo
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by MD, LR, MC and FR-M. The first draft of the manuscript was written by MD and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Mauro Difeo.

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Difeo, M., Rubio-Marcos, F., Del Campo, A. et al. A suitable approach to achieve functional (Bi, Na)TiO3-based lead-free piezoceramics via compositional design for energy storage applications. J Mater Sci: Mater Electron 34, 1962 (2023). https://doi.org/10.1007/s10854-023-11258-0

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