Skip to main content
Log in

Influence of temperature on the microstructure and microwave absorption of C/Co composites

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this study, porous C/Co composites using corncobs as precursors to be used as a microwave absorbing material that is lightweight and has strong absorption and broad bandwidth. The microstructure and electromagnetic parameters of the C/Co composites were optimized by varying the calcination temperature to achieve enhanced attenuation capability and impedance matching. Low temperature is not enough to fully carbonize the corncobs and high temperature will destroy the integrity of the carbon sheet and appear holes, which are not conducive to the wave absorption performance. Benefiting from the hierarchically porous architecture and the optimized electromagnetic parameters, the C/Co composite calcined at 700 °C has a minimum reflection loss (RL) of − 64.53 dB at 12 GHz with a matching layer thickness of 2.14 mm; and the maximum absorption bandwidth of RL values below − 10 dB is 3.1 GHz (8.7–11.8 GHz) with a matching layer thickness of 2.55 mm. The C/Co composites with strong absorption, broad effective absorption bandwidth, and lightweight can be used as high-performance microwave absorbers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

Data availability

All data generated or analysed during this study are included in this published article.

References

  1. P.B. Liu, S. Gao, W.H. Huang, J. Ren, D.Y. Yu, W.J. He, Hybrid zeolite imidazolate framework derived N-implanted carbon polyhedrons with tunable heterogeneous interfaces for strong wideband microwave attenuation. Carbon 159, 83–93 (2020)

    Article  CAS  Google Scholar 

  2. B. Huang, J.L. Yue, Y.S. Wei, X.Z. Huang, X.Z. Tang, Z.J. Du, Enhanced microwave absorption properties of carbon nanofibers functionalized by FeCo coatings. Appl. Surf. Sci. 483, 98–105 (2019)

    Article  CAS  Google Scholar 

  3. Z. Lou, C. Yuan, Y. Zhang, Y. Li, J. Cai, L. Yang, W. Wang, H. Han, J. Zou, Synthesis of porous carbon matrix with inlaid Fe3C/Fe3O4 micro-particles as an effective electromagnetic wave absorber from natural wood shavings. J. Alloys Compd. 775, 800–809 (2019)

    Article  CAS  Google Scholar 

  4. T. Liu, N. Liu, S. Zhai, S. Gao, Z. Xiao, Q. An, D. Yang, Tailor-made core/shell/shell-like Fe3O4@ SiO2@PPy composites with prominent microwave absorption performance. J. Alloys Compd. 779, 831–843 (2019)

    Article  CAS  Google Scholar 

  5. S. Li, L. Lin, L. Yao, H. Zhang, Q. Luo, W. Xu, C. Zhang, Q. Xie, L. Wang, D. Peng, MOFs-derived Co-C@C hollow composites with high-performance electromagnetic wave absorption. J. Alloys Compd. 856, 158183 (2021)

    Article  CAS  Google Scholar 

  6. A. Ling, G. Tan, Q. Man, Y. Lou, S. Chen, X. Gu, R.-W. Li, J. Pan, X. Liu, Broadband microwave absorbing materials based on MWCNTs’ electromagnetic wave filtering effect. Compos. Part B 171, 214–221 (2019)

    Article  CAS  Google Scholar 

  7. Y. Wang, X. Gao, Y. Fu, X. Wu, Q. Wang, W. Zhang, C. Luo, Enhanced microwave absorption performances of polyaniline/graphene aerogel by covalent bonding. Compos. Part B 169, 221–228 (2019)

    Article  CAS  Google Scholar 

  8. C.-Y. Chen, N.-W. Pu, Y.-M. Liu, L.-H. Chen, C.-H. Wu, T.-Y. Cheng, M.-H. Lin, M.-D. Ger, Y.-J. Gong, Y.-Y. Peng, P.M. Grubb, R.T. Chen, Microwave absorption properties of holey graphene/silicone rubber composites. Compos. Part B 135, 119–128 (2018)

    Article  CAS  Google Scholar 

  9. H.S. Liang, L.M. Zhang, H.J. Wu, Exploration of twin-modified grain boundary engineering in metallic copper predominated electromagnetic wave absorber. Small 18, 2203620 (2022)

    Article  CAS  Google Scholar 

  10. H. Guan, H. Wang, Y. Zhang, C. Dong, G. Chen, Y. Wang, J. Xie, Microwave absorption performance of Ni(OH)2 decorating biomass carbon composites from Jackfruit peel. Appl. Surf. Sci. 447, 261–268 (2018)

    Article  CAS  Google Scholar 

  11. Z. Lou, Y. Li, H. Han, H. Ma, L. Wang, J. Cai, L. Yang, C. Yuan, J. Zou, Synthesis of porous 3D Fe/C composites from waste wood with tunable and excellent electromagnetic wave absorption performance. ACS Sustain. Chem. Eng. 6, 15598–15607 (2018)

    Article  CAS  Google Scholar 

  12. J.B. Xi, E.Z. Zhou, Y.J. Liu, W.W. Gao, J. Ying, Z.C. Chen, C. Gao, Wood-based straightway channel structure for high performance microwave absorption. Carbon 124, 492–498 (2017)

    Article  CAS  Google Scholar 

  13. Z.C. Wu, K. Tian, T. Huang, W. Hu, F.F. Xie, J.J. Wang, M.X. Su, L. Li, Hierarchically porous carbons derived from biomasses with excellent microwave absorption performance. ACS Appl. Mater. Interfaces 10, 11108–11115 (2018)

    Article  CAS  Google Scholar 

  14. Y. Fan, Y. Li, Y. Yao, Y. Sun, B. Tong, J. Zhan, Hierarchically porous carbon sheets/Co nanofibers derived from corncobs for enhanced microwave absorbing properties. Appl. Surf. Sci. 534, 147510 (2020)

    Article  CAS  Google Scholar 

  15. H.L. Xu, X.W. Yin, M. Zhu, M.H. Li, H. Zhang, H.J. Wei, L.T. Zhang, L.F. Cheng, Constructing hollow graphene nano-spheres confined in porous amorphous carbon particles for achieving full X band microwave absorption. Carbon 142, 346–353 (2019)

    Article  CAS  Google Scholar 

  16. R. Xu, D. Xu, Z. Zeng, D. Liu, CoFe2O4/porous carbon nanosheet composites for broadband microwave absorption. Chem. Eng. J. 427, 130796 (2022)

    Article  CAS  Google Scholar 

  17. Y. Shi, X. Gao, J. Qiu, Synthesis and strengthened microwave absorption properties of three-dimensional porous Fe3O4/graphene composite foam. Ceram. Int. 45, 3126–3132 (2019)

    Article  CAS  Google Scholar 

  18. Y. Lin, J.J. Dai, H.B. Yang, L. Wang, F. Wang, Graphene multilayered sheets assembled by porous Bi2Fe4O9 microspheres and the excellent electromagnetic wave absorption properties. Chem. Eng. J. 334, 1740–1748 (2018)

    Article  CAS  Google Scholar 

  19. R. Qiang, Y.C. Du, H.T. Zhao, Y. Wang, C.H. Tian, Z.G. Li, X.J. Han, P. Xu, Metal organic framework-derived Fe/C nanocubes toward efficient microwave absorption. J. Mater. Chem. 3(25), 13426–13434 (2015)

    Article  CAS  Google Scholar 

  20. Y.Y. Lu, Y.T. Wang, H.L. Li, Y. Lin, Z.Y. Jiang, Z.X. Xie, Q. Kuang, L.S. Zheng, MOF-derived porous Co/C nanocomposites with excellent electromagnetic wave absorption properties. ACS Appl. Mater. Interfaces 7(24), 13604–13611 (2015)

    Article  CAS  Google Scholar 

  21. H.S. Liang, G. Chen, D. Liu, Z.J. Li, S.C. Hui, J.J. Yun, L.M. Zhang, H.J. Wu, Exploring the Ni 3d orbital unpaired electrons induced polarization loss based on Ni single-atoms model absorber. Adv. Funct. Mater. 33, 2212604 (2023)

    Article  CAS  Google Scholar 

  22. L. Wang, M.Q. Huang, X.F. Yu, W.B. You, J. Zhang, X.H. Liu, M. Wang, R.C. Chen, MOF-derived Ni1-xCox@Carbon with tunable nano-microstructure as lightweight and highly efficient electromagnetic wave absorber. Nano-Micro Lett. 12, 1–17 (2020)

    Article  Google Scholar 

  23. H.L. Lv, X.H. Liang, G.B. Ji, H.Q. Zhang, Y.W. Du, Porous Three-dimensional flower-like Co/CoO and its excellent electromagnetic absorption properties. ACS Appl. Mater. Interfaces 7(18), 9776–9783 (2015)

    Article  CAS  Google Scholar 

  24. Y. Shu, T. Zhao, X. Li, L. Yang, S. Cao, A. Ahmad, T. Jiang, H. Luo, Z. Jing, N. Ain, Flower-like Co@CoO nanohybrids assembled by crisp-rice-like quadrate flakes as high-performance electromagnetic wave absorber. Appl. Surf. Sci. 597, 153754 (2022)

    Article  CAS  Google Scholar 

  25. Y. Wu, K. Peng, Z. Man, R. Zang, P. Li, S. Liu, S. Wang, P. Liu, P. Li, Y. Cui, A hierarchically three-dimensional CoNi/N-doped porous carbon nanosheets with high performance of electromagnetic wave absorption. Carbon 188, 503–512 (2022)

    Article  CAS  Google Scholar 

  26. T. Ying, J. Zhang, X. Liu, J. Yu, J. Yu, X. Zhang, Corncob-derived hierarchical porous carbon/Ni composites for microwave absorbing application. J. Alloys Compd. 849, 156662 (2020)

    Article  CAS  Google Scholar 

  27. D. Voiry, J. Yang, J. Kupferberg, R. Fullon, C. Lee, H.Y. Jeong, H.S. Shin, M. Chhowalla, High-quality graphene via microwave reduction of solution-exfoliated graphene oxide. Science 353(6306), 1413–1416 (2016)

    Article  CAS  Google Scholar 

  28. J. Liu, R. Che, H. Chen, F. Zhang, F. Xia, Q. Wu, M. Wang, Microwave absorption enhancement of multifunctional composite microspheres with spinel Fe3O4 cores and anatase TiO2 shells. Small 8, 1214–1221 (2012)

    Article  CAS  Google Scholar 

  29. D. Lan, H.J. Zhou, H.J. Wu, A polymer sponge with dual absorption of mechanical and electromagnetic energy. J. Colloid Interf. Sci. 633, 92–101 (2023)

    Article  CAS  Google Scholar 

  30. D. Wu, Y.Q. Wang, S.L. Deng, D. Lan, Z.N. Xiang, Q.C. He, Heterstructured CoFe@N-doped porous polyhedron for efficient microwave absorption. Nano Res. 16(2), 1859–1868 (2023)

    Article  CAS  Google Scholar 

Download references

Funding

This work was financially supported by Natural Science Basic Research Plan in Shaanxi Province of China (Grant No. 2020JQ-912), Innovative Talent Promotion Program Youth Science and Technology Rising Star Project (Grant No. 2023KJXX-075) and General Project (Youth) of Shaanxi Provincial Natural Science Basic Research Program (Grant No. 2023-JC-QN-0523).

Author information

Authors and Affiliations

Authors

Contributions

LY, YJ and ZY designed and performed the experiments. YJ initiated and supervised the research. LY prepared the first draft of the manuscript. YC, WB and CH analyzed and discussed the data. All authors edited and revised the manuscript. All authors have given approval to the final version of the manuscript.

Corresponding author

Correspondence to Yu Jiuhong.

Ethics declarations

Competing interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yuanyuan, L., Jiuhong, Y., Yingying, Z. et al. Influence of temperature on the microstructure and microwave absorption of C/Co composites. J Mater Sci: Mater Electron 34, 1892 (2023). https://doi.org/10.1007/s10854-023-11245-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10854-023-11245-5

Navigation