Skip to main content

Advertisement

SpringerLink
Log in

Bi0.2Sr0.7TiO3–doped Bi0.5Na0.5TiO3–based lead-free ceramics with good energy storage properties

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Dielectric capacitors have received much attention and are used in pulsed power supplies, electronic circuits etc. due to their fast charge/discharge rate and high-power density. However, the large-scale application of dielectric capacitors is limited by the energy storage density. Bi0.5Na0.5TiO3 (BNT)-based ceramic capacitors are suitable materials for the preparation of dielectric capacitors due to their large spontaneous polarization. Therefore, the use of chemical modification to improve the energy storage density of BNT-based ceramics is a current research hotspot. In this work, the (0.9-x)Bi0.5Na0.5TiO3-0.1Ba0.7Ca0.3TiO3-xBi0.2Sr0.7TiO3 ceramics (BNT-BCT-xBST) were prepared. BST was used to modulate the relaxor characteristics of BNT-BCT. When the content of BST is 6%, the ceramic has a recoverable energy storage density of 2.73 J/cm3 and an energy storage efficiency of 85% at 280 kV/cm and a power density of 33.3 MW/cm3 at 150 kV/cm. This work proves that BNT-BCT-0.06BST is a good candidate for dielectric capacitor.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

Data availability

Data is available on request from the authors.

References

  1. K. Li, X. Liu, T. Zheng, D. Jiang, Z. Zhou, C. Liu, X. Zhang, Y. Zhang, D. Losic, Tuning MnO2 to FeOOH replicas with bio-template 3D morphology as electrodes for high performance asymmetric supercapacitors. Chem. Eng. J. 370, 136–147 (2019)

    Article  CAS  Google Scholar 

  2. K. Li, S. Feng, C. Jing, Y. Chen, X. Liu, Y. Zhang, L. Zhou, Assembling a double shell on a diatomite skeleton ternary complex with conductive polypyrrole for the enhancement of supercapacitors. Chem. Commun. 55, 13773–13776 (2019)

    Article  CAS  Google Scholar 

  3. L. Yang, X. Kong, F. Li, H. Hao, Z. Cheng, H. Liu, J.-F. Li, S. Zhang, Perovskite lead-free dielectrics for energy storage applications. Prog Mater. Sci. 102, 72–108 (2019)

    Article  CAS  Google Scholar 

  4. Z. Sun, Z. Wang, Y. Tian, G. Wang, W. Wang, M. Yang, X. Wang, F. Zhang, Y. Pu, Progress, outlook, and challenges in lead-free energy-storage ferroelectrics. Adv. Electron. Mater. 6, 1900698 (2020)

    Article  CAS  Google Scholar 

  5. Z. Yang, H. Du, L. Jin, D. Poelman, High-performance lead-free bulk ceramics for electrical energy storage applications: design strategies and challenges. J. Mater. Chem. A 9, 18026–18085 (2021)

    Article  CAS  Google Scholar 

  6. K. Zou, Y. Dan, H. Xu, Q. Zhang, Y. Lu, H. Huang, Y. He, Recent advances in lead-free dielectric materials for energy storage. Mater. Res. Bull. 113, 190–201 (2019)

    Article  CAS  Google Scholar 

  7. H. Zhang, T. Wei, Q. Zhang, W. Ma, P. Fan, D. Salamon, S.-T. Zhang, B. Nan, H. Tan, Z.-G. Ye, A review on the development of lead-free ferroelectric energy-storage ceramics and multilayer capacitors. J. Mater. Chem. C 8, 16648–16667 (2020)

    Article  CAS  Google Scholar 

  8. P. Shi, X. Zhu, X. Lou, B. Yang, Q. Liu, C. Kong, S. Yang, L. He, R. Kang, J. Zhao, Tailoring ferroelectric polarization and relaxation of BNT-based lead-free relaxors for superior energy storage properties. Chem. Eng. J. 428, 132612 (2022)

    Article  CAS  Google Scholar 

  9. H. Qi, A. Xie, R. Zuo, Local structure engineered lead-free ferroic dielectrics for superior energy-storage capacitors: a review. Energy Storage Materials. 45, 541–567 (2022)

    Article  Google Scholar 

  10. P. Shi, Z. Hong, X. Zhu, Q. Liu, B. Yang, T. Li, R. Kang, J. Zhao, C. Kong, Y. Hu, X. Ke, S. Yang, X. Lou, Enhancement of energy storage properties of Bi0.5Na0.5TiO3-based relaxor ferroelectric under moderate electric field. Appl. Phys. Lett. 120, 132903 (2022)

    Article  CAS  Google Scholar 

  11. P. Shi, T. Li, X. Zhu, W. Liu, Q. Liu, B. Yang, X. Wang, R. Kang, S. Yang, X. Lou, High strain in Bi0.5Na0.5TiO3-based relaxors by adding two modifiers featuring with morphotropic phase boundary. Scripta Mater. 218, 114674 (2022)

    Article  CAS  Google Scholar 

  12. Y. Huang, F. Li, H. Hao, F. Xia, H. Liu, S. Zhang, (Bi0.51 Na0.47)TiO3 based lead free ceramics with high energy density and efficiency. J. Materiomics. 5, 385–393 (2019)

    Article  Google Scholar 

  13. W. Ping, W. Liu, S. Li, Enhanced energy storage property in glass-added ba(Zr0.2Ti0.8)O3-0.15(Ba0.7Ca0.3)TiO3 ceramics and the charge relaxation. Ceram. Int. 45, 11388–11394 (2019)

    Article  CAS  Google Scholar 

  14. Y. Pu, M. Yao, H. Liu, T. Frömling, Phase transition behavior, dielectric and ferroelectric properties of (1–x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 ceramics. J. Eur. Ceram. Soc. 36, 2461–2468 (2016)

    Article  CAS  Google Scholar 

  15. P. Shi, X. Zhu, X. Lou, B. Yang, X. Guo, L. He, Q. Liu, S. Yang, X. Zhang, Bi0.5Na0.5TiO3-based lead-free ceramics with superior energy storage properties at high temperatures. Compos. Part B: Eng. 215, 108815 (2021)

    Article  CAS  Google Scholar 

  16. J. Lv, Q. Li, Y. Li, M. Tang, D. Jin, Y. Yan, B. Fan, L. Jin, G. Liu, Significantly improved energy storage performance of NBT-BT based ceramics through domain control and preparation optimization. Chem. Eng. J. 420, 129900 (2021)

    Article  CAS  Google Scholar 

  17. X. Zhao, C. Li, J. Liu, Y. Ding, W. Bai, P. Zheng, P. Li, J. Zhang, J. Zhai, (Bi0.5Na0.5)TiO3-based relaxor ferroelectrics with simultaneous high energy storage properties and remarkable charge-discharge performances under low working electric fields for dielectric capacitor applications. Ceram. Int. 47, 25800–25809 (2021)

    Article  CAS  Google Scholar 

  18. H. Ye, F. Yang, Z. Pan, D. Hu, X. Lv, H. Chen, F. Wang, J. Wang, P. Li, J. Chen, J. Liu, J. Zhai, Significantly improvement of comprehensive energy storage performances with lead-free relaxor ferroelectric ceramics for high-temperature capacitors applications. Acta Mater. 203, 116484 (2021)

    Article  CAS  Google Scholar 

  19. X. Zhang, D. Hu, Z. Pan, X. Lv, Z. He, F. Yang, P. Li, J. Liu, J. Zhai, Enhancement of recoverable energy density and efficiency of lead-free relaxor-ferroelectric BNT-based ceramics. Chem. Eng. J. 406, 126818 (2021)

    Article  CAS  Google Scholar 

  20. X. Zhao, W. Bai, Y. Ding, L. Wang, S. Wu, P. Zheng, P. Li, J. Zhai, Tailoring high energy density with superior stability under low electric field in novel (Bi0.5Na0.5)TiO3-based relaxor ferroelectric ceramics. J. Eur. Ceram. Soc. 40, 4475–4486 (2020)

    Article  CAS  Google Scholar 

  21. P. Shi, L. Zhu, W. Gao, Z. Yu, X. Lou, X. Wang, Z. Yang, S. Yang, Large energy storage properties of lead-free (1-x)(0.72Bi0.5Na0.5TiO3-0.28SrTiO3)-xBiAlO3 ceramics at broad temperature range. J. Alloys Compd. 784, 788–793 (2019)

    Article  CAS  Google Scholar 

  22. S. Pattipaka, S. Bora, D. Pamu, Structural, electrical, and ac-resistivity studies of BNT-KN piezoelectric ceramics. Ferroelectrics 557, 28–42 (2020)

    Article  CAS  Google Scholar 

  23. S. Jiao, F. Chen, Y. Zhang, Z. Hu, Z. Duan, F. Wang, D. Sun, Phonon behaviors and dielectric functions in Bi0.5Na0.5TiO3-based ceramics by Raman scattering and optical ellipsometry. J. Am. Ceram. Soc. 102, 2791–2799 (2019)

    Article  CAS  Google Scholar 

  24. D. Hu, Z. Pan, X. Zhang, H. Ye, Z. He, M. Wang, S. Xing, J. Zhai, Q. Fu, J. Liu, Greatly enhanced discharge energy density and efficiency of novel relaxation ferroelectric BNT–BKT-based ceramics. J. Mater. Chem. C 8, 591–601 (2020)

    Article  CAS  Google Scholar 

  25. X. Qiao, D. Wu, F. Zhang, M. Niu, B. Chen, X. Zhao, P. Liang, L. Wei, X. Chao, Z. Yang, Enhanced energy density and thermal stability in relaxor ferroelectric Bi0.5Na0.5TiO3-Sr0.7Bi0.2TiO3 ceramics. J. Eur. Ceram. Soc. 39, 4778–4784 (2019)

    Article  CAS  Google Scholar 

  26. G. Viola, H. Ning, X. Wei, M. Deluca, A. Adomkevicius, J. Khaliq, M. John Reece, H. Yan, Dielectric relaxation, lattice dynamics and polarization mechanisms in Bi0.5Na0.5TiO3-based lead-free ceramics. J. Appl. Phys. 114, 014107 (2013)

    Article  Google Scholar 

  27. F. Yan, K. Huang, T. Jiang, X. Zhou, Y. Shi, G. Ge, B. Shen, J. Zhai, Significantly enhanced energy storage density and efficiency of BNT-based perovskite ceramics via A-site defect engineering. Energy Storage Mater. 30, 392–400 (2020)

    Article  Google Scholar 

  28. X. Qiao, A. Sheng, D. Wu, F. Zhang, B. Chen, P. Liang, J. Wang, X. Chao, Z. Yang, A novel multifunctional ceramic with photoluminescence and outstanding energy storage properties. Chem. Eng. J. 408, 127368 (2021)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by Education Science and Technology Innovation Project of Ganshu Province, China, year of 2022, the project: Study on the mechanism of the fatigue behavior of sodium-bismuth-titanate based relaxor ferroelectric capacitors after electrical charge-discharge cycles (Grant No. 2022QB-213) and the National Natural Science Foundation of China (NSFC NO.52172125).

Author information

Authors and Affiliations

  1. Gansu Vocational College of Architecture, Lanzhou, 730050, Gansu Province, China

    Cheng Wang

  2. College of Physics and Information Technology, Shaanxi Normal University, Xi’an, 710062, Shaanxi, China

    Peng Shi

Authors
  1. Cheng Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Peng Shi
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

SP: Methodology, Writing—Original Draft, Writing—Review and Editing, Methodology; CW: Project administration, Supervision, Conceptualization.

Corresponding author

Correspondence to Cheng Wang.

Ethics declarations

Competing interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, C., Shi, P. Bi0.2Sr0.7TiO3–doped Bi0.5Na0.5TiO3–based lead-free ceramics with good energy storage properties. J Mater Sci: Mater Electron 34, 1774 (2023). https://doi.org/10.1007/s10854-023-11119-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10854-023-11119-w

Search

Navigation