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CsPbCl3 and Mn:CsPbCl3 perovskite nanocubes/nanorods as a prospective cathode material for LIB application

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Abstract

CsPbCl3 and Mn:CsPbCl3 nanocubes/nanorods were prepared by a hot injection technique. The crystal structure, size and morphology of the CsPbCl3 and Mn:CsPbCl3 samples were measured by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The edgelengths of the nanocubes and the length and width of the nanorods of CsPbCl3 are between tens and hundreds of nanometers. The size and morphology of Mn:CsPbCl3 are similar to those of CsPbCl3. The introduction of Mn2+ ions led to little change in the CsPbCl3 host structure. Their electrochemical properties for LIB application were tested by cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy. The introduction of a small amount of Mn2+ ions can improve the structural stability of CsPbCl3 during charge–discharge cycles because the Mn2+ part replaces the Pb2+ ions of CsPbCl3. Thus, Mn:CsPbCl3 shows high discharge specific capacities, excellent cyclic performance, and lower electrochemical impedance values than CsPbCl3 in LIB applications.

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The supporting data of the findings of this research are available from the corresponding author upon reasonable request.

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Funding

This research was financially supported by the National Natural Science Foundation of China (Grant Nos. 11704056, 52071048, 11774042, 22075035 and 21776027), the Fundamental Research Funds for the Central Universities (Grant No. 3132019338) and the Joint Research Fund Liaoning–Shenyang National Laboratory for Materials Science (Grant No. 20180510045).

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Authors and Affiliations

  1. School of Science, Dalian Maritime University, No. 1, Linghai Road, Dalian, 116026, Liaoning, People’s Republic of China

    Hongquan Yu, Xiao Gao, Baojiu Chen & Sai Xu

  2. College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian, 116028, Liaoning, China

    Chenchen Huang, Shimin Liu, Yong Zhang & Hong Zhao

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  1. Hongquan Yu
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  2. Xiao Gao
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  3. Chenchen Huang
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  4. Shimin Liu
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  5. Baojiu Chen
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  6. Sai Xu
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  7. Yong Zhang
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  8. Hong Zhao
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Contributions

The experiments and data processing were carried out by CH and XG. The data analysis and paper writing were performed by HY and YZ. Other authors contributed to the experimental design and revision of the paper.

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Correspondence to Hongquan Yu.

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Yu, H., Gao, X., Huang, C. et al. CsPbCl3 and Mn:CsPbCl3 perovskite nanocubes/nanorods as a prospective cathode material for LIB application. J Mater Sci: Mater Electron 34, 1582 (2023). https://doi.org/10.1007/s10854-023-10998-3

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