Abstract
NaNbO3-based antiferroelectric ceramics are considered to be popular candidates for lead-free dielectric capacitors. However, the instability of the antiferroelectric phase of pure NaNbO3 (NN) ceramics under high electric fields leads to poor energy storage density and efficiency. Therefore, in order to stabilize the antiferroelectric phase of NN, (1 − x)NaNbO3-xBi0.2Sr0.7SnO3 [(1 − x)NN-xBSS] (x = 0.06–0.20) system was successfully prepared by the solid-state reaction method. The solid solution transforms from the antiferroelectric phase (AFE) to the paraelectric phase (PE) with increasing BSS doping. In addition, the Curie temperature (Tm) changes abruptly from nearly 250 °C to − 120 °C at x = 0.10 and exhibits relaxation behavior. The best performance with a recoverable energy density (Wrec) of 0.80 J/cm3 and efficiency (η) of 80.2% in this system is obtained simultaneously at 180 kV/cm in the component with x = 0.10. Furthermore, the 0.90NN-0.10BSS ceramic has good frequency stability. This work provides a new doping strategy and systematically investigates phase structure, microscopic morphology, and macroscopic electrical properties of (1 − x)NN-xBSS ceramics.
Similar content being viewed by others
Data availability
The data used to support the findings of this study are included within the article.
References
K. Zou, Y. Dan, H. Xu, Q. Zhang, Y. Lu, H. Huang, Y. He, Mater. Res. Bull. 113, 190–201 (2019). https://doi.org/10.1016/j.materresbull.2019.02.002
F. Li, J. Zhai, B. Shen, H. Zeng, J. Adv. Dielectr. 08, 1830005 (2018). https://doi.org/10.1142/S2010135X18300050
D. Hou, H. Fan, A. Zhang, Y. Chen, F. Yang, Y. Jia, H. Wang, Q. Quan, W. Wang, Ceram. Int. 47, 34059–34067 (2021). https://doi.org/10.1016/j.ceramint.2021.08.315
P. Zhao, Z. Cai, L. Chen, L. Wu, Y. Huan, L. Guo, L. Li, H. Wang, X. Wang, Energ. Environ. Sci. 13, 4882–4890 (2020). https://doi.org/10.1039/D0EE03094E
H. Qi, A. Xie, A. Tian, R. Zuo, Adv. Energy Mater. 10, 1903338 (2020). https://doi.org/10.1002/aenm.201903338
K. Han, N. Luo, S. Mao, F. Zhuo, L. Liu, B. Peng, X. Chen, C. Hu, H. Zhou, Y. Wei, J. Mater. Chem. A 7, 26293–26301 (2019). https://doi.org/10.1039/C9TA06457E
X. Hao, J. Adv. Dielectr. (2013). https://doi.org/10.1142/S2010135X13300016
Z. Dai, J. Xie, W. Liu, X. Wang, L. Zhang, Z. Zhou, J. Li, X. Ren, ACS Appl. Mater. Interfaces 12, 30289–30296 (2020). https://doi.org/10.1021/acsami.0c02832
N. Luo, K. Han, M.J. Cabral, X. Liao, S. Zhang, C. Liao, G. Zhang, X. Chen, Q. Feng, J.-F. Li, Y. Wei, Nat. Commun. 11, 4824 (2020). https://doi.org/10.1038/s41467-020-18665-5
Q. Yuan, G. Li, F.-Z. Yao, S.-D. Cheng, Y. Wang, R. Ma, S.-B. Mi, M. Gu, K. Wang, J.F. Li, H. Wang, Nano Energy. 52, 203–210 (2018). https://doi.org/10.1016/j.nanoen.2018.07.055
H. Qi, R. Zuo, A. Xie, J. Fu, D. Zhang, J. Eur. Ceram. Soc. 39, 3703–3709 (2019). https://doi.org/10.1016/j.jeurceramsoc.2019.05.043
J. Wang, H. Fan, M. Wang, P. Fan, Ceram. Int. 47, 17964–17970 (2021). https://doi.org/10.1016/j.ceramint.2021.03.110
Y. Tian, L. Jin, H. Zhang, Z. Xu, X. Wei, G. Viola, I. Abrahams, H. Yan, J. Eur. Ceram. Soc. 5, 17525–17531 (2017). https://doi.org/10.1039/C7TA03821F
L. Zhao, Q. Liu, S. Zhang, J.F. Li, J. Mater. Chem. C 4, 8380–8384 (2016). https://doi.org/10.1039/C6TC03289C
Y. Tian, L. Jin, H. Zhang, Z. Xu, X. Wei, E.D. Politova, S.Y. Stefanovich, N.V. Tarakina, I. Abrahams, H. Yan, J. Mater. Chem. A 4, 17279–17287 (2016). https://doi.org/10.1039/C6TA06353E
J. Gao, L. Zhao, Q. Liu, X. Wang, S. Zhang, J.F. Li, J. Am. Ceram. Soc. 101, 5443–5450 (2018). https://doi.org/10.1111/jace.15780
H. Guo, H. Shimizu, C.A. Randall, Appl. Phys. Lett. 107, 112904 (2015). https://doi.org/10.1063/1.4930067
D. Yang, J. Gao, L. Shu, Y.X. Liu, J. Yu, Y. Zhang, X. Wang, B.P. Zhang, J.F. Li, J. Mater. Chem. A 8, 23724–23737 (2020). https://doi.org/10.1039/D0TA08345C
Y.I. Yuzyuk, P. Simon, E. Gagarina, L. Hennet, D. Thiaudière, V.I. Torgashev, S.I. Raevskaya, I.P. Raevskii, L.A. Reznitchenko, J.L. Sauvajol, J. Phys. : Condens. Matter. 17, 4977 (2005). https://doi.org/10.1088/0953-8984/17/33/003
A. Xie, H. Qi, R. Zuo, ACS Appl. Mater. Interfaces 12, 19467–19475 (2020). https://doi.org/10.1021/acsami.0c00831
S. Li, P. Shi, X. Zhu, B. Yang, X. Zhang, R. Kang, Q. Liu, Y. Gao, H. Sun, X. Lou, J. Mater. Sci. 56, 11922–11931 (2021). https://doi.org/10.1007/s10853-021-06075-x
J. Shi, X. Chen, X. Li, J. Sun, C. Sun, F. Pang, H. Zhou, J. Mater. Chem. C 8, 3784–3794 (2020). https://doi.org/10.1039/c9tc06711f
R.D. Shannon, C.T. Prewitt, Acta. Crystallorg. B 25, 925–946 (1969). https://doi.org/10.1107/S0567740869003220
J. Ye, G. Wang, X. Chen, X. Dong, J. Materiomics. 7, 339–346 (2021). https://doi.org/10.1016/j.jmat.2020.08.007
Z. Liu, J. Lu, Y. Mao, P. Ren, H. Fan, J. Eur. Ceram. Soc. 38, 4939–4945 (2018). https://doi.org/10.1016/j.jeurceramsoc.2018.07.029
T. Pan, J. Zhang, Z.N. Guan, Y. Yan, J. Ma, X. Li, S. Guo, J. Wang, Y. Wang, Adv. Electron. Mater. 8, 2200793 (2022). https://doi.org/10.1002/aelm.202200793
L. Zhao, Q. Liu, J. Gao, S. Zhang, J.F. Li, Adv. Mater. 29, 1701824 (2017). https://doi.org/10.1002/adma.201701824
C. Liu, H. Yang, R. Hu, Y. Lin, J. Mater. Sci. Mater. Electron. 34, 668 (2023). https://doi.org/10.1007/s10854-023-10009-5
Y. Pan, X. Wang, Q. Dong, J. Wang, H. Chen, X. Dong, L. Deng, H. Zhang, X. Chen, H. Zhou, Ceram. Int. 48, 26466–26475 (2022). https://doi.org/10.1016/j.ceramint.2022.05.341
R.D. Shannon, Acta. Crystallorg. A 32, 751–767 (1976). https://doi.org/10.1107/S0567739476001551
X. Dong, X. Li, X. Chen, H. Chen, C. Sun, J. Shi, F. Pang, H. Zhou, J. Materiomics. 7, 629–639 (2021). https://doi.org/10.1016/j.jmat.2020.11.016
B. Toby et al., J. Appl. Crystallogr. 34, 210–213 (2001). https://doi.org/10.1107/S0021889801002242
M. Zhou, R. Liang, Z. Zhou, X. Dong, J. Mater. Chem. A 6, 17896–17904 (2018). https://doi.org/10.1039/C8TA07303A
A. Xie, J. Fu, R. Zuo, C. Zhou, Z. Qiao, T. Li, S. Zhang, Chem. Eng. J. (2022). https://doi.org/10.1016/j.cej.2021.132534
X. Zhao, Z. Zhou, R. Liang, F. Liu, X. Dong, Ceram. Int. 12, 9060–9066 (2017). https://doi.org/10.1016/j.ceramint.2017.04.051
J. Ma, D. Zhang, F. Ying, X. Li, L. Li, S. Guo, Y. Huan, J. Zhang, J. Wang, S.T. Zhang, ACS Appl. Mater. Interfaces. 14, 19704–19713 (2022). https://doi.org/10.1021/acsami.2c02086
Q. Hu, Y. Tian, Q. Zhu, J. Bian, L. Jin, H. Du, D.O. Alikin, V.Y. Shur, Y. Feng, Z. Xu, X. Wei, Nano Energy (2020). https://doi.org/10.1016/j.nanoen.2019.104264
P. Zhao, H. Wang, L. Wu, L. Chen, Z. Cai, L. Li, X. Wang, Adv. Energy Mater. (2019). https://doi.org/10.1002/aenm.201803048
J. Fu, R. Zuo, Acta Mater. 61, 3687–3694 (2013). https://doi.org/10.1016/j.actamat.2013.02.055
I.P. Raevski, L.A. Reznitchenko, M.A. Malitskaya, L.A. Shilkina, S.O. Lisitsina, S.I. Raevskaya, E.M. Kuznetsova, Ferroelectrics. 299, 95–101 (2004). https://doi.org/10.1080/00150190490429231
L.E. Cross, Relaxor ferroelectrics. Ferroelectrics. 76, 241–267 (1987). https://doi.org/10.1080/00150198708016970
K. Uchino, S. Nomura, Ferroelectrics. 44, 55–61 (1982). https://doi.org/10.1080/00150198208260644
X. Dong, X. Li, H. Chen, Q. Dong, J. Wang, X. Wang, Y. Pan, X. Chen, H. Zhou, J. Adv. Ceram. 11, 729–741 (2022). https://doi.org/10.1007/s40145-022-0566-6
Q. Dong, X. Wang, J. Wang, Y. Pan, X. Dong, H. Chen, X. Chen, H. Zhou, Ceram. Int. 48, 776–783 (2022). https://doi.org/10.1016/j.ceramint.2021.09.158
H. Shimizu, H. Guo, S.E. Reyes-Lillo, Y. Mizuno, K.M. Rabe, C.A. Randall, Dalton. Trans. 44, 10763–10772 (2015). https://doi.org/10.1039/C4DT03919J
Q. Li, M.Y. Li, C. Wang, M. Zhang, H. Fan, Ceram. Int. 45, 19822–19828 (2019). https://doi.org/10.1016/j.ceramint.2019.06.237
Acknowledgements
This work was supported by the National Natural Science Foundation of China (51972114, 52272062).
Author information
Authors and Affiliations
Contributions
All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Yuqing Chen and Xinrong Zhong. The first draft of the manuscript was written by Yuqing Chen and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Ethical approval
The authors formally declare that the present paper is complied with ethical standards.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Chen, Y., Zhong, X., Shui, A. et al. Effect of Bi0.2Sr0.7SnO3 doping on NaNbO3-based ceramics: enhanced ferroelectric, dielectric, and energy storage performance. J Mater Sci: Mater Electron 34, 1301 (2023). https://doi.org/10.1007/s10854-023-10593-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10854-023-10593-6