Skip to main content
SpringerLink
Log in

(Zn,Mn)S/C composites for high-capacity lithium storage

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this work, two kinds of bimetallic MOFs materials (Zn-Mn-BTC) with different morphologies are prepared by a simple solvent method at room temperature by changing the amount of PVP. The (Zn,Mn)S/C composites are synthesized by calcining Zn-Mn-BTC as precursor and sulfur powder as sulfur source in high temperature inert atmosphere. The effect of the two morphologies on the lithium storage performance of (Zn,Mn)S/C composites is explored. The (Zn,Mn)S/C composites have good cycle stability and rate performance. The porous carbon formed by carbonization of organic ligand H3BTC can exert its excellent mechanical properties and electrical conductivity, buffer the volume stress in the process of charge-discharge and promote the transfer of electrons.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

Data availability

All data generated or analyzed during this study are included in this published article.

References

  1. A. Sharif, S. Saha, N. Campbell, A. Sinha, D.M. Ibrahiem, Curr. Issues Tour. 23, 2930 (2020)

    Article  Google Scholar 

  2. M.B. Tahir, T. Nawaz, G. Nabi, M. Sagir, M.A. Shehzad, A. Yasmin, S. Hussain, M.P. Bhatti, A. Ahmed, S.S.A. Gilani, Int. J. Environ. Anal. Chem. 101, 2016 (2021)

    Article  CAS  Google Scholar 

  3. M.A. Mahdi, S.R. Yousefi, L.S. Jasim, M. Salavati-Niasari, Int. J. Hydrog. Energy 47, 14319 (2022)

    Article  CAS  Google Scholar 

  4. S.R. Yousefi, H.A. Alshamsi, O. Amiri, M. Salavati-Niasari, J. Mol. Liq. 337, 116405 (2021)

    Article  CAS  Google Scholar 

  5. S.R. Yousefi, D. Ghanbari, M. Salavati-Niasari, M. Hassanpour, J. Mater. Sci. Mater. Electron. 27, 1244 (2016)

    Article  CAS  Google Scholar 

  6. S. Hussain, X. Yang, M.K. Aslam, A. Shaheen, M.S. Javed, N. Aslam, B. Aslam, G. Liu, G. Qiao, Chem. Eng. J. 391, 123595 (2020)

    Article  CAS  Google Scholar 

  7. S. Hussain, A.J. Khan, M. Arshad, M.S. Javed, A. Ahmad, S.S.A. Shah, M.R. Khan, S. Akram, S. Zulfiqar, Z.A. Ali, G. Alothman, A. Liu, G. Shaheen, Qiao, Ceram. Int. 47, 8659 (2021)

    Article  CAS  Google Scholar 

  8. S. Hussain, M. Hassan, M.S. Javed, A. Shaheen, S.S.A. Shah, M.T. Nazir, T. Najam, A.J. Khan, X. Zhang, G. Liu, Ceram. Int. 46, 25942 (2020)

    Article  CAS  Google Scholar 

  9. L. Fei, B.P. Williams, S.H. Yoo, J.M. Carlin, Y.L. Joo, Chem. Commun. 52, 1501 (2016)

    Article  CAS  Google Scholar 

  10. S. Zhang, R. Lin, W. Yue, F. Niu, J. Ma, X. Yang, Chem. Eng. J. 314, 19 (2017)

    Article  CAS  Google Scholar 

  11. S. Hussain, N. Ullah, Y. Zhang, A. Shaheen, M.S. Javed, L. Lin, S.B. Zulfiqar, G. Shah, G. Liu, Qiao, Int. J. Hydrog. Energy 44, 24525 (2019)

    Article  CAS  Google Scholar 

  12. S. Hussain, M.S. Javed, S. Asim, A. Shaheen, A.J. Khan, Y. Abbas, N. Ullah, A. Iqbal, M. Wang, G. Qiao, S. Yun, Ceram. Int. 46, 6406 (2020)

    Article  CAS  Google Scholar 

  13. R.A.P. Camacho, A.-M. Wu, X.-Z. Jin, X.-F. Dong, X.-N. Li, H. Huang, J. Power Sources 437, 226931 (2019)

    Article  Google Scholar 

  14. D. Wang, D. Cai, B. Qu, T. Wang, Crystengcomm 18, 6200 (2016)

    Article  CAS  Google Scholar 

  15. Y. Fu, Z. Zhang, X. Yang, Y. Gan, W. Chen, RSC Adv. 5, 86941 (2015)

    Article  CAS  Google Scholar 

  16. H. Wu, G. Li, Y. Li, Z. Geng, T. Ren, T. Cai, Z. Yang, Cryst. Res. Technol. 54, 1800281 (2019)

    Article  Google Scholar 

  17. D. Wang, W. Zhou, R. Zhang, X. Huang, J. Zeng, Y. Mao, C. Ding, J. Zhang, J. Liu, G. Wen, J. Mater. Chem. A 6, 2974 (2018)

    Article  CAS  Google Scholar 

  18. M. Zhan, S. Hussain, T.S. AlGarni, S. Shah, J. Liu, X. Zhang, A. Ahmad, M.S. Javed, G. Qiao, G. Liu, Mater. Res. Bull. 136, 111133 (2021)

    Article  CAS  Google Scholar 

  19. Y. Feng, Y. Zhang, Y. Wei, X. Song, Y. Fub, V.S. Battaglia, Phys. Chem. Chem. Phys. 18, 30630 (2016)

    Article  CAS  Google Scholar 

  20. L. He, X.-Z. Liao, K. Yang, Y.-S. He, W. Wen, Z.-F. Ma, Electrochim. Acta 56, 1213 (2011)

    Article  CAS  Google Scholar 

  21. M. Mao, L. Jiang, L. Wu, M. Zhang, T. Wang, J. Mater. Chem. A 3, 13384 (2015)

    Article  CAS  Google Scholar 

  22. D. Chen, H. Quan, X. Luo, S. Luo, Scripta Mater. 76, 1 (2014)

    Article  Google Scholar 

  23. Z. Shami, N. Sharifi-Sanjani, Crystengcomm 16, 910 (2014)

    Article  CAS  Google Scholar 

  24. D. Chen, H. Quan, G.-S. Wang, L. Guo, Chempluschem 78, 843 (2013)

    Article  CAS  Google Scholar 

  25. L. Shi, X. Hu, Y. Huang, J. Nanopart. Res. 16, 2332 (2014)

    Article  Google Scholar 

  26. L. Wang, J. Ju, N. Deng, G. Wang, B. Cheng, W. Kang, Electrochem. Commun. 96, 1 (2018)

    Article  Google Scholar 

  27. J. Zhao, R. Liu, Mater. Lett. 124, 239 (2014)

    Article  CAS  Google Scholar 

  28. D.-H. Ha, T. Ly, J.M. Caron, H. Zhang, K.E. Fritz, R.D. Robinson, ACS Appl. Mater. Interfaces 7, 25053 (2015)

    Article  CAS  Google Scholar 

  29. M.S. Javed, X. Han, C. Hu, M. Zhou, Z. Huang, X. Tang, X. Gu, ACS Appl. Mater. Interfaces 8, 24621 (2016)

    Article  CAS  Google Scholar 

  30. K.M. Jeon, J.S. Cho, Y.C. Kang, J. Power Sources 295, 9 (2015)

    Article  CAS  Google Scholar 

  31. X. Li, J. Shen, N. Li, M. Ye, J. Power Sources 282, 194 (2015)

    Article  CAS  Google Scholar 

  32. Y. Liu, Y. Qiao, W.-X. Zhang, Z. Li, X.-L. Hu, L.-X. Yuan, Y.-H. Huang, J. Mater. Chem. 22, 24026 (2012)

    Article  CAS  Google Scholar 

  33. Y. Ren, J. Wang, X. Huang, J. Ding, Solid State Ion. 278, 138 (2015)

    Article  CAS  Google Scholar 

  34. X. Xu, S. Ji, M. Gu, J. Liu, ACS Appl. Mater. Interfaces 7, 20957 (2015)

    Article  CAS  Google Scholar 

  35. Y. Lin, L. Zhang, J. Xiao, H. Liu, Sustain. Energy Fuels 4, 633 (2020)

    Article  CAS  Google Scholar 

  36. Y. Lin, L. Zhang, H. Li, Int. J. Hydrog. Energy 45, 6874 (2020)

    Article  CAS  Google Scholar 

  37. L. Zhao, X. Yu, J. Yu, Y. Zhou, S.N. Ehrlich, Y.-S. Hu, D. Su, H. Li, X.-Q. Yang, L. Chen, Adv. Funct. Mater. 24, 5557 (2014)

    Article  CAS  Google Scholar 

  38. S. Tan, D.J. Payne, J.P. Hallett, G.H. Kelsall, Curr. Opin. Electrochem. 16, 83 (2019)

    Article  CAS  Google Scholar 

  39. Q. Yang, L. Xu, S. Luo, M. Chen, X. Wang, L. Ma, Mater. Lett. 254, 386 (2019)

    Article  CAS  Google Scholar 

  40. Q. Li, M. Zhang, Y. Nong, Q. Pan, Y. Huang, H. Wang, F. Zheng, Q. Li, New J. Chem. 46, 18069 (2022)

    Article  CAS  Google Scholar 

  41. P. Jin, X. Zhang, J. Wang, Mater. Lett. 188, 13 (2017)

    Article  CAS  Google Scholar 

  42. J. Beltran-Huarac, O. Resto, J. Carpena-Nunez, W.M. Jadwisienczak, L.F. Fonseca, B.R. Weiner, G. Morell, ACS Appl. Mater. Interfaces 6, 1180 (2014)

    Article  CAS  Google Scholar 

  43. S.M. Lee, J.-K. Lee, Y.C. Kang, Chem. Asian J. 9, 590 (2014)

    Article  CAS  Google Scholar 

Download references

Funding

This work is financially supported by Science and Technology Project of Chongqing Education Commission (KJQN201900504) and (KJQN201800505), Major cultivation project of Chongqing University of Arts and Science (P2020CL03) and Creative Research Group of Micro-Nano Semiconductor & Photonic Materials of Chongqing Municipal Education Commission.

Author information

Author notes

  1. Hongdong Liu and Jiaoyu Xiao are co-first authors.

Authors and Affiliations

  1. College of Materials Science and Engineering, Chongqing University of Arts and Sciences, 402160, Chongqing, People’s Republic of China

    Hongdong Liu & Kai Yang

  2. College of Materials Science and Engineering, Chongqing University, 400045, Chongqing, People’s Republic of China

    Jiaoyu Xiao

  3. College of Life Science, Chongqing Normal University, 401331, Chongqing, People’s Republic of China

    Yan Wu & Lei Zhang

  4. College of Biological and Chemical Engineering, Guangxi University of Science and Technology, 545006, Liuzhou, People’s Republic of China

    Yao Lu

Authors
  1. Hongdong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jiaoyu Xiao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yan Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kai Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Lei Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yao Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

HL and JX contributed to writing—original draft preparation. JX and YW contributed to the preparation of the materials. KY and YW contributed to materials characterizations. LZ and YL contributed to writing—review and editing. All authors have read and agreed to the published version of the manuscript.

Corresponding author

Correspondence to Lei Zhang.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Ethical approval

Not applicable.

Consent to participate

Not applicable.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, H., Xiao, J., Wu, Y. et al. (Zn,Mn)S/C composites for high-capacity lithium storage. J Mater Sci: Mater Electron 34, 1120 (2023). https://doi.org/10.1007/s10854-023-10544-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10854-023-10544-1

Search

Navigation