Abstract
This study investigated the modification effects of ion-beam exposure on polyacrylamide films according to molecular concentrations. Surface morphological examination using scanning electron microscopy showed increasing polyacrylamide particle size and film thicknesses with increasing concentrations. X-ray photoelectron spectroscopy and contact angle analysis were used to confirm the surface chemical reconstruction and increased surface energy after ion-beam exposure. As the molecular concentration increased, the changes were also observed to increase. The anisotropic ion-beam exposure induced strong van der Waals interactions with the liquid-crystals, leading to their uniform alignment. The uniform and homogeneous liquid-crystal alignment state was confirmed by polarized optical microscopy and pretilt angle analysis. Electro-optical performance evaluations showed the high potential of the ion-beam-exposed polyacrylamide film for use in liquid-crystal devices. Therefore, the correlation between the film molecular concentration and the IB process is successfully verified, and its applicability to liquid-crystal devices is confirmed.
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The data that support the findings of this study are available from the corresponding author upon reasonable request.
References
Y. Chen, D. Xu, S.-T. Wu, S. Yamamoto, Y. Haseba, Appl. Phys. Lett. 102, 141116 (2013)
Y. Garbovskiy, Appl. Phys. Lett. 108, 121104 (2016)
D.-M. Song, K.-H. Jung, J.-H. Moon, D.-M. Shin, Opt. Mater. 21, 667 (2003)
N.J. V, E. Shiju, R. Arun, M.K.R. Varma, K. Chandrasekharan, N. Sandhyarani, S. Varghese, Opt. Mater. 67, 7 (2017)
X. Yan, F.W. Mont, D.J. Poxson, M.F. Schubert, J.K. Kim, J. Cho, E.F. Schubert, Jpn J. Appl. Phys. 48, 120203 (2009)
T.-H. Lin, H.-C. Jau, Appl. Phys. Lett. 88, 061122 (2006)
D.W. Lee, Y. Liu, D.H. Kim, J.Y. Oh, H.-C. Jeong, D.-S. Seo, Eur. Polym. J. 163, 110937 (2022)
M. Schadt, K. Schmitt, V. Kozinkov, V. Chigrinov, Jpn J. Appl. Phys. 31, 2155 (1992)
W.M. Gibbon, P.J. Shannon, S.-T. Sun, B.J. Swetlin, Nature 351, 49 (1991)
M.F. Toney, T.P. Russell, J.A. Logan, H. Kikuchi, J.M. Sands, S.K. Kumar, Nature 374, 709 (1995)
T.J. Lee, S.G. Hahm, S.W. Lee, B. Chae, S.J. Lee, G. Kim, S.B. Kim, J.C. Jung, M. Ree, Mater. Sci. Eng. B 132, 64 (2006)
P.S.H. Henry, Br. J. Appl. Phys. 4, S31 (1953)
J.V. Haaren, Nature 411, 29 (2001)
M. Lu, Jpn J. Appl. Phys. 43, 8156–8160 (2004)
W.A. Crossland, J.H. Morrissy, B. Needham, J. Phys. D-Appl Phys. 9, 2001–2014 (1976)
P. Chaudhari, J.A. Lacey, S.-C.A. Lien, J.L. Speidell, Jpn J. Appl. Phys. 37, L55–L56 (1998)
P. Chaudhari, J. Lacey, J. Doyle, E. Galligan, S.C.A. Lien, A. Callegary, G. Hougham, N.D. Lang, P.S. Andry, R. John, K.H. Yang, M. Lu, C. Cai, J. Speidell, S. Purushothaman, J. Ritsko, M. Samant, J. Stöhr, Y. Nakagawa, Y. Katoh, Y. Saitoh, K. Sakai, H. Satoh, S. Odahara, H. Nakano, J. Nakagaki, Y. Shiota, Nature 411, 56–59 (2001)
C. Satriano, E. Conte, G. Marletta, Langmuir 17, 2243–2250 (2001)
D.W. Lee, D.H. Kim, J.Y. Oh, D.-S. Seo, Plasma Process. Polym. 19, 2100207 (2022)
K.S. Kim, K.H. Lee, K. Cho, C.E. Park, J. Membr. Sci. 199, 135–145 (2002)
D.-W. Lee, D.-H. Kim, J.-Y. Oh, D.-S. Seo, J. Vac Sci. Technol. A 40, 023408 (2022)
W.-M. Kulicke, R. Kniewske, J. Klein, Progr Polym. Sci. 8, 373 (1982)
G. Huang, J. Yang, J. Gao, X. Wang, Ind. Eng. Chem. Res 51, 12355–12366 (2012)
X. Jin, G. Sun, G. Zhang, H. Yang, Y. Xiao, J. Gao, Z. Zhang, L. Qu, Nano Res. 12, 1199–1206 (2019)
K.Y. Han, T. Miyashita, T. Uchida, Mol. Cryst. Liq Cryst. Sci. Technol. Sect. A-Mol Cryst. Liq Cryst. 241, 147 (1994)
T.J. Scheffer, J. Nehring, J. Appl. Phys. 48, 1783 (1977)
J. Stöhr, M.G. Samant, J. Lüning, A.C. Callegari, P. Chaudhari, J.P. Doyle, J.A. Lacey, S.A. Lien, S. Purushothaman, J.L. Speidell, Science 292, 2299–2302 (2001)
O. Yaroshchuk, R. Kravchuk, A. Dobrovolskyy, L. Qiu, O.D. Lavrentovich, Liq Cryst. 31, 859–869 (2004)
A.W. Adamson, Physical Chemistry of Surfaces, fifth edn. (Wiley-Interscience, New York, 1990)
W.-K. Lee, Y.S. Choi, Y.-G. Kang, J. Sung, D.-S. Seo, C. Park, Adv. Funct. Mater. 21, 3843–3850 (2011)
H.-C. Jeong, J.H. Lee, J. Won, B.Y. Oh, D.H. Kim, D.W. Lee, I.H. Song, Y. Liu, D.-S. Seo, Opt. Express 27, 18096 (2019)
N.J. V, S.P. Rajeev, S. Varghese, Liquid Cryst. 46, 736 (2019)
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This research was supported by the National Research Foundation of Korea (Grant No. 2022R1F1A106419212).
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DWL contributed to writing-original draft. DHK contributed to methodology. JYO contributed to measurement, JW contributed to material preparation. DBY contributed to investigation. HCJ contributed to formal analysis. DSS contributed to administration.
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Lee, D.W., Kim, D.H., Oh, J.Y. et al. Ion-beam exposure on PAM surface according to molecular concentration for application to liquid-crystal device. J Mater Sci: Mater Electron 34, 1102 (2023). https://doi.org/10.1007/s10854-023-10523-6
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DOI: https://doi.org/10.1007/s10854-023-10523-6