Abstract
The present paper focuses on the study of influence of copper incorporation in the cadmium telluride (CdTe) films. CdTe absorber layers have been grown by thermal evaporation technique and cadmium sulfide (CdS) buffer layers have been deposited by Chemical bath deposition method. Copper incorporated CdTe films have been characterized by X-ray diffraction (XRD), Atomic force microscopy (AFM), scanning electron microscopy (SEM), UV–Vis spectroscopy, Raman spectroscopy and Hall Effect measurements. XRD analysis illustrated that all the CdTe thin films were of polycrystalline nature possessing cubic structure showing sharp peak at (111) orientation, while the intensities of peaks varied from sample to sample with respect to copper incorporation in the CdTe films. SEM analysis demonstrated that maximum grain size and morphology were dependent on the incorporation of copper on buffer layer. From the AFM results, it was observed that the surface roughness of CdTe thin films varied with respect to different copper incorporation in the thin films. From the Raman spectra analysis, it was observed that the intensities of A1, E1 modes of Te and TO modes of CdTe thin films varied with copper incorporated sample displaying maximum intensities of the shoulder peaks followed by other samples. From the optical properties of CdTe thin films it was demonstrated that bandgap of samples slightly decreased with higher copper amount. From the electrical properties of CdTe thin films it was observed that higher mobility and reduced resistivity were observed for copper incorporated samples. Thus, all these characterization results suggest that with controlled amount of copper incorporation these CdTe thin films possess the potential to be used as absorber layer for solar cells.
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References
T. Manimozhi, T. Logu, J. Archana, M. Navaneethan, K. Sethuraman, K. Ramamurthi, Enhanced photo-response of CdTe Thin film via Mo doping prepared using electron beam evaporation technique. J Mater Sci Mater Electron 31(23), 21059–21072 (2020). https://doi.org/10.1007/s10854-020-04618-7
R.S. Kapadnis, S.B. Bansode, A.T. Supekar, P.K. Bhujbal, S.S. Kale, S.R. Jadkar, H.M. Pathan, Cadmium telluride/cadmium sulfide thin films solar cells: a review. ES Energy Environ (2020). https://doi.org/10.30919/esee8c706
J.M. Kestner, S. McElvain, S. Kelly, T.R. Ohno, L.M. Woods, C.A. Wolden, An experimental and modeling analysis of vapor transport deposition of cadmium telluride. Sol Energy Mater Sol Cells. 83(1), 55–65 (2004). https://doi.org/10.1016/j.solmat.2004.02.013
X. Wen, Z. Lu, X. Sun, Y. Xiang, Z. Chen, J. Shi, I. Bhat, G.C. Wang, M. Washington, T.M. Lu, Epitaxial CdTe thin films on mica by vapor transport deposition for flexible solar cells. ACS Appl Energy Mater 3(5), 4589–4599 (2020). https://doi.org/10.1021/acsaem.0c00265
M.N. Harif, K.S. Rahman, C. Doroody, H.N. Rosly, M. Isah, M.A. Alghoul, H. Misran, N. Amin, Microstructural evolution of oxygen incorporated CdTe thin films deposited by close-spaced sublimation. Mater Lett (2022). https://doi.org/10.1016/j.matlet.2021.130552
N. Amin, M.R. Karim, Z.A. Alothman, An in-depth analysis of CdTe thin-film deposition on ultra-thin glass substrates via close-spaced sublimation(CSS). Coatings (2022). https://doi.org/10.3390/coatings12050589
H. Trivedi, A. Boochani, N. Shagya, J. Lahiri, Z. Ghorannevis, A.S. Parmar, Investigating optical, structural and morphological properties of polycrystalline CdTe thin-film deposited by RF magnetron sputtering. Mater Lett 11, 100087 (2021). https://doi.org/10.1016/j.mlblux.2021.100087
E. Camacho-Espinosa, A. López-Sánchez, I. Rimmaudo, R. Mis-Fernández, J.L. Peña, All-sputtered CdTe solar cell activated with a novel method. Sol. Energy 193, 31–36 (2019). https://doi.org/10.1016/j.solener.2019.09.023
G.K.U.P. Gajanayake, D.S.M. De Silva, H.Y.R. Atapattu, Altering NH4OH concentration in producing chemical bath deposited CdS to steadily support electrodeposited CdTe. Mater Sci Eng Solid-State Mater Adv Technol (2021). https://doi.org/10.1016/j.mseb.2020.114952
H. Soonmin, C.U. Vyas, P. Pataniya, K.D. Patel, S. Mahato, A short review of CdTe and CdSe films: growth and characterization. Mediterr J Chem 7(2), 115–124 (2018). https://doi.org/10.13171/mjc72/01808011619-soonmin
M.F. Al-Kuhaili, M.B. Mekki, S.A. Abdalla, Influence of vacuum annealing on the photoresponse of thermally evaporated cadmium telluride thin films. Thin Solid Films (2019). https://doi.org/10.1016/j.tsf.2019.137412
K.S. Rahman, Cadmium telluride (CdTe) thin film solar cells, in Comprehensive guide on organic and inorganic solar cells. ed. by R. Din (Academic Press, 2022), pp.65–83
B. Alshahrani, S. Nabil, H.I. Elsaeedy, H.A. Yakout, A. Qasem, The pivotal role of thermal annealing of cadmium telluride thin film in optimizing the performance of CdTe/Si solar cells. J. Electron. Mater. 50(8), 4586–4598 (2021). https://doi.org/10.1007/s11664-021-08989-3
S. Lalitha, S.Z. Karazhanov, P. Ravindran, S. Senthilarasu, R. Sathyamoorthy, J. Janabergenov, Electronic structure, structural and optical properties of thermally evaporated CdTe thin films. Phys B Condensed Matter 387(1–2), 227–238 (2007). https://doi.org/10.1016/j.physb.2006.04.008
J. Huang, D. Yang, W. Li, J. Zhang, L. Wu, W. Wang, Copassivation of polycrystalline CdTe absorber by CuCl thin films for CdTe solar cells. Appl Surface Sci (2019). https://doi.org/10.1016/j.apsusc.2019.03.253
M.F. Hasaneen, W.S. Mohamed, Effect of CdCl2 heat treatment in (Ar + O2) atmosphere on structural and optical properties of CdTe thin films. Optik 160, 307–321 (2018). https://doi.org/10.1016/j.ijleo.2018.01.112
A. Abbas, G.D. West, J.W. Bowers, P. Isherwood, P.M. Kaminski, B. Maniscalco, P. Rowley, J.M. Walls, K. Barricklow, W.S. Sampath, K.L. Barth, The effect of cadmium chloride treatment on close-spaced sublimated cadmium telluride thin-film solar cells. IEEE J Photovoltaics 3(4), 1361–1366 (2013). https://doi.org/10.1109/JPHOTOV.2013.2264995
E.D. Jones, N.M. Stewart, J.B. Mullin, The diffusion of copper in cadmium telluride. J. Cryst. Growth 117, 244–248 (1992). https://doi.org/10.1016/0022-0248(92)90753-6
J. Perrenoud, L. Kranz, C. Gretener, F. Pianezzi, S. Nishiwaki, S. Buecheler, A.N. Tiwari, A comprehensive picture of Cu doping in CdTe solar cells. J Appl Phys 114, 174505 (2013). https://doi.org/10.1063/1.4828484
K.K. Chin, T.A. Gessert, S.H. Wei, The roles of Cu impurity states in CdTe thin film solar cells, in 35th IEEE photovoltaic specialists conference. (IEEE, Honolulu, 2010), pp.001915–001918
K.D. Dobson, I. Visoly-Fisher, G. Hodes, D. Cahen, Stability of CdTe/CdS thin-film solar cells. Sol. Energy Mater. Sol. Cells 62(3), 295–325 (2000). https://doi.org/10.1016/s0927-0248(00)00014-3
A. Morales-Acevedo, Thin film CdS/CdTe solar cells: research perspectives. Sol Energy 80(6), 675–681 (2006)
J. Matthew Kurley, M.G. Panthani, R.W. Crisp, S.U. Nanayakkara, G.F. Pach, M.O. Reese, M.H. Hudson, Transparent ohmic contacts for solution-processed, ultrathin CdTe solar cells. ACS Energy Lett 2(1), 270–278 (2017)
A. Mukherjee, P. Ghosh, A.A. Aboud, P. Mitra, Influence of copper incorporation in CdS: structural and morphological studies. Mater. Chem. Phys. 184, 101–109 (2016). https://doi.org/10.1016/j.matchemphys.2016.09.030
S. Chandramohan, R. Sathyamoorthy, S. Lalitha, S. Senthilarasu, Structural properties of CdTe thin films on different substrates. Sol. Energy Mater. Sol. Cells 90, 686–693 (2006). https://doi.org/10.1016/j.solmat.2005.04.005
S.L. Patel, S. Chander, M.D. Kannan, M.S. Dhaka, Impact of chloride treatment on the physical properties of polycrystalline thin CdTe films for solar cell applications. Phys Lett Sect General Atomic Solid State Phys 383(15), 1778–1781 (2019). https://doi.org/10.1016/j.physleta.2019.03.001
H. Liu, A. Wang, Q. Sun, T. Wang, H. Zeng, Cu nanoparticles/fluorine-doped tin oxide (FTO) nanocomposites for photocatalytic H2 evolution under visible light irradiation. Catalysts (2017). https://doi.org/10.3390/catal7120385
S.R. Sam, S.L. Rayar, P. Selvarajan, Effect of annealing and dopants on the physical properties of CdS nanoparticles. J Chem Pharm Res 7(3), 957–963 (2015)
A.A. Aboud, A. Mukherjee, N. Revaprasadu, A.N. Mohamed, The effect of Cu-doping on CdS thin films deposited by the spray pyrolysis technique. J. Market. Res. 8(2), 2021–2030 (2019). https://doi.org/10.1016/j.jmrt.2018.10.017
Y. Deng, J. Yang, R. Yang, K. Shen, D. Wang, D. Wang, Cu-doped CdS and its application in CdTe thin film solar cell. AIP Adv. (2016). https://doi.org/10.1063/1.4939817
R. Panda, M. Panda, H. Rath, U.P. Singh, R. Naik, N.C. Mishra, Annealing induced AgInSe2 formation from Ag/In/Ag/In multilayer film for solar cell absorbing layer. Opt. Mater. 84, 618–624 (2018). https://doi.org/10.1016/j.optmat.2018.07.049
B. Cullity, S. Stock, Elements of X-ray diffraction, 3rd edn. (Princeton Hall, 2001)
M.N.M. Daud, A. Zakaria, A. Jafari, M.S.M. Ghazali, W.R. Wan Abdullah, Z. Zainal, Characterization of CdTe films deposited at various bath temperatures and concentrations using electrophoretic deposition. Int J Mol Sci 13(5), 5706–5714 (2012). https://doi.org/10.3390/ijms13055706
K.S. Rahman, F. Haque, N.A. Khan, M.A. Islam, M.M. Alam, Z.A. Alothman, K. Sopian, N. Amin, Effect of CdCl2 treatment on thermally evaporated CdTe thin films. Chalcogen Lett 11(3), 129–139 (2014). https://doi.org/10.13140/2.1.2716.2883
S. Chander, M.S. Dhaka, Impact of thermal annealing on physical properties of vacuum evaporated polycrystalline CdTe thin films for solar cell applications. Phys E Low-dimensional Syst Nanostruct 80, 62–68 (2016). https://doi.org/10.1016/j.physe.2016.01.012
I.M. Dharmadasa, P.A. Bingham, O.K. Echendu, H.I. Salim, T. Druffel, R. Dharmadasa, G.U. Sumanasekera, R.R. Dharmasena, M.B. Dergacheva, K.A. Mit, K.A. Urazov, L. Bowen, M. Walls, A. Abbas, Fabrication of CdS/CdTe-based thin film solar cells using an electrochemical technique. Coatings 4(3), 380–415 (2014). https://doi.org/10.3390/coatings4030380
A.A. Ojo, I.M. Dharmadasa, Analysis of electrodeposited CdTe thin films grown using cadmium chloride precursor for applications in solar cells. J. Mater. Sci.: Mater. Electron. 28(19), 14110–14120 (2017). https://doi.org/10.1007/s10854-017-7264-0
T.P. Shalvey, J.D. Major, Impact of NaF during chloride treatment of CdTe solar cells. Mater Sci Semicond Process (2020). https://doi.org/10.1016/j.mssp.2019.104827
S. Chander, M.S. Dhaka, CdCl2 treatment concentration evolution of physical properties correlation with surface morphology of CdTe thin films for solar cells. Mater Res Bull (2018). https://doi.org/10.1016/j.materresbull.2017.08.038
K.S. Rahman, F. Haque, N.A. Khan, M.A. Islam, M.M. Alam, Z.A. AlOthman, K. Sopian, N. Amin, Influence of thermal annealing on CdTe thin film deposited by thermal evaporation technique, in Proceeding of 2014 3rd international conference on the developments in renewable energy technology. (ICDRET, 2014)
K.S. Rahman, M.N. Harif, H.N. Rosly, M.I. Bin Kamaruzzaman, M. Akhtaruzzaman, M. Alghoul, H. Misran, N. Amin, Influence of deposition time in CdTe thin film properties grown by close-spaced sublimation (CSS) for photovoltaic application. Res Phys (2019). https://doi.org/10.1016/j.rinp.2019.102371
A. Salavei, I. Rimmaudo, F. Piccinelli, D. Menossi, A. Bosio, N. Romeo, A. Romeo, Analysis of CdTe activation treatment with a novel approach, in 28th European photovoltaic solar energy conference and exhibition. (Research gate, 2014)
S.L. Patel, S. Chander, A. Purohit, M.D. Kannan, M.S. Dhaka, Influence of NH4Cl treatment on physical properties of CdTe thin films for absorber layer applications. J. Phys. Chem. Solids 123, 216–222 (2018). https://doi.org/10.1016/j.jpcs.2018.07.021
S. Chandramohan, R. Sathyamoorthy, P. Sudhagar, D. Kanjila, D. Kabiraj, K. Asokan, V. Ganesan, Influence of SHI irradiation on the structure and surface topography of CdTe thin films on flexible substrate. J. Mater. Sci.: Mater. Electron. 18(11), 1093–1098 (2007). https://doi.org/10.1007/s10854-007-9137-4
J. Rangel-Cárdenas, H. Sobral, Optical absorption enhancement in CdTe thin films by microstructuration of the silicon substrate. Materials (2017). https://doi.org/10.3390/ma10060607
J.G. Quiñones-Galván, E. Camps, E. Campos-González, A. Hernández-Hernández, M.A. Santana- Aranda, A. Pérez-Centeno, J. Guillén-Cervantes, O. Santoyo-Salazar, F.M.F. Zelaya-Angel, Influence of plasma parameters and substrate temperature on the structural and optical properties of CdTe thin films deposited on glass by laser ablation. J Appl Phys 118(12), 125304 (2015). https://doi.org/10.1063/1.4931677
F. Moure-Flores, J.G. Quiñones-Galván, A. Guillén-Cervantes, J.S. Arias-Cerón, A. Hernández-Hernández, J. Santoyo-Salazar, J. Santos-Cruz, S.A. Mayén-Hernández, M.L. de la Olvera, J.G. Mendoza-Álvarez, M. Meléndez-Lira, G. Contreras-Puente, CdTe thin films grown by pulsed laser deposition using powder as target: effect of substrate temperature. J. Cryst. Growth 386(27), 31 (2014). https://doi.org/10.1016/j.jcrysgro.2013.09.036
J.M. Lugo, E. Rosendo, R. Romano-Trujillo, A.I. Oliva, H.P.L. De Guevara, C.I. Medel-Ruiz, L. Treviño-Yarce, J.S. Arellano, C. Morales, T. Díaz, G. García, Effects of the applied power on the properties of RF-sputtered CdTe films. Mater Res Exp 6(7), 076428 (2019). https://doi.org/10.1088/2053-1591/ab17c0
J.I. Watanabe, T. Sekine, K. Uchinokura, E. Matsuura, Observation of increase in Raman intensity of surface phonon polaritons on rough surfaces of ZnTe. Solid State Commun. 51(5), 289–291 (1984)
C. Frausto-Reyes, J.R. Molina-Contreras, C. Medina-Gutiérrez, S. Calixto, CdTe surface roughness by Raman spectroscopy using the 830 nm wavelength. Spectrochim Acta Part A Mol Biomol Spectrosc 65(1), 51–55 (2006). https://doi.org/10.1016/j.saa.2005.07.082
N.K. Das, S.F.U. Farhad, J. Chakaraborty, A.K.S. Gupta, M. Dey, M. Al-Mamun, M.A. Matin, N. Amin, Structural and optical properties of RF-sputtered CdTe thin films grown on CdS:O/CdS bilayers. Int J Renew Energy Res 10(1), 293–302 (2020). https://doi.org/10.20508/ijrer.v10i1.10431.g7918
S. Das, S. Senapati, D. Alagarasan, S. Varadhrajaperumal, R. Ganesan, R. Naik, Thermal annealing-induced transformation of structural, morphological, linear, and nonlinear optical parameters of quaternary As20Ag10Te10Se60 thin films for optical applications. ACS Appl Opt Mater 1(1), 17–31 (2023). https://doi.org/10.1021/acsaom.2c00002
R. Naik, R.G. Ramakanta, K.S. Sangunni, Optical properties change with the addition and diffusion of Bi to As2S3 in the Bi/As2S3 bilayer thin film. J Alloys Compd 554, 293–298 (2013). https://doi.org/10.1016/j.jallcom.2012.11.198
F. De Moure-Flores, J.G. Quiñones-Galván, A. Guillén-Cervantes, J. Santoyo-Salazar, A. Hernández-Hernández, M. De La Olvera, M. Zapata-Torres, M. Meléndez-Lira, Structural and optical properties of Cu-doped CdTe films with hexagonal phase grown by pulsed laser deposition. AIP Adv (2012). https://doi.org/10.1063/1.4721275
F. Moure-Flores, J.G. Quiñones-Galván, A. Guillén-Cervantes, J.S. Arias-Cerón, G. Contreras-Puente, A. Hernández-Hernández, J. Santoyo-Salazar, M. De La Olvera, M.A. Santana-Aranda, M. Zapata-Torres, J.G. Mendoza-Álvarez, M. Meléndez-Lira, Physical properties of CdTe: Cu films grown at low temperature by pulsed laser deposition. J Appl Phys (2012). https://doi.org/10.1063/1.4768455
N. Naeema, A. Kudher, G.H. Mohammed, Structural and optical properties of CdTe:Cu thin films by pulsed laser deposition technique. IOP Conf Series Mater Sci Eng (2020). https://doi.org/10.1088/1757-899X/757/1/012024
M. Singh, M. Goyal, K. Devlal, Size and shape effects on the band gap of semiconductor compound nanomaterials. J Taibah Univ Sci 12(4), 470–475 (2018). https://doi.org/10.1080/16583655.2018.1473946
S. Lalitha, R. Sathyamoorthy, S. Senthilarasu, A. Subbarayan, K. Natarajan, Characterization of CdTe thin film—Dependence of structural and optical properties on temperature and thickness. Sol. Energy Mater. Sol. Cells 82(1–2), 187–199 (2004). https://doi.org/10.1016/j.solmat.2004.01.017
D. Sahoo, P. Priyadarshini, R. Dandela, D. Alagarasan, R. Ganesan, S. Varadharajaperumal, R. Naik, Optimization of linear and nonlinear optical parameters in As40Se60 film by annealing at different temperature. Optik 219, 165286 (2020). https://doi.org/10.1016/j.ijleo.2020.165286
C. Doroody, K.S. Rahman, S.F. Abdullah, M.N. Harif, H.N. Rosly, S.K. Tiong, N. Amin, Temperature difference in close-spaced sublimation (CSS) growth of CdTe thin film on ultra-thin glass substrate. Res Phys 18, 103213 (2020). https://doi.org/10.1016/j.rinp.2020.103213
Z. Ma, K.M. Yu, Copper-doped CdTe films with improved hole mobility. Appl. Phys. Lett. 91(9), 2–5 (2007). https://doi.org/10.1063/1.2778455
D.B. Li, S.S. Bista, Z. Song, R.A. Awni, K.K. Subedi, N. Shrestha, P. Pradhan, L. Chen, E. Bastola, C.R. Grice, A.B. Phillips, M.J. Heben, R.J. Ellingson, Y. Yan, Maximize CdTe solar cell performance through copper activation engineering. Nano Energy (2020). https://doi.org/10.1016/j.nanoen.2020.104835
A.U. Ubale, D.K. Kulkarni, Studies on size dependent properties of cadmium telluride thin films deposited by using successive ionic layer adsorption and reaction method. Indian J Pure Appl Phys 44(3), 254–259 (2006)
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Jena, I., Singh, U.P. Impact of thin layer of copper on cadmium telluride and cadmium sulfide thin films. J Mater Sci: Mater Electron 34, 1117 (2023). https://doi.org/10.1007/s10854-023-10515-6
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DOI: https://doi.org/10.1007/s10854-023-10515-6