Abstract
A fabric electrode with a 3D structure consisting of copper nanoparticles (CuNPs), reduced graphene oxide (RGO), and cotton was fabricated by a simple, efficient, environmentally friendly, and low-cost method. With cotton fabric as the textile base, RGO provides double electric layer capacitors, which also can help connect the cotton fibers in series, making the cotton fabric a high-speed conductive channel. Additionally, the CuNPs provide pseudocapacitance and storage space for ions. This three-dimensional synergistic effect in the fabric electrode led to a specific capacitance of 197.4 F g−1 and a good charge–discharge performance. The assembled all-solid symmetric supercapacitor showed a specific capacitance of 179.4 F g−1, with a maximum energy density of 8.52 Wh kg−1 and power density of 100.05 W kg−1. The cheap and readily available raw materials make this fabric-based electrode easy to manufacture on a large scale, making it a promising candidate for wearable devices.
Similar content being viewed by others
Data availability
All data included in this study are available upon request by contact with the corresponding author.
References
V. Rajendran, A.M. Mohan, M. Jayaraman, T. Nakagawa, All-printed, interdigitated, freestanding serpentine interconnects based flexible solid state supercapacitor for self- powered wearable electronics. Nano Energy 65, 1 (2019)
C.J. Raj, R. Manikandan, W. Cho, K.H. Yu, B.C. Kim, High-performance flexible and wearable planar supercapacitor of manganese dioxide nanoflowers on carbon fiber cloth. Ceram. Int. 46, 21736 (2020)
W.J. Ma, S.H. Chen, S.Y. Yang, W.P. Chen, W. Wang, Y.H. Cheng, M.F. Zhu, Flexible all-solid-state asymmetric supercapacitor based on transition metal oxide nanorods/reduced graphene oxide hybrid fibers with high energy density. Carbon 113, 151 (2017)
M.Y. Zhou, H.H. Zhang, Y. Qiao, C.M. Li, Z.S. Lu, A flexible sandwich-structured supercapacitor with poly(vinyl alcohol)/H3PO4-soaked cotton fabric as solid electrolyte, separator and supporting layer. Cellulose 25, 3459 (2018)
Q.Y. Huang, L.B. Liu, D.R. Wang, J.J. Liu, Z.F. Huang, Z.J. Zheng, One-step electrospinning of carbon nanowebs on metallic textiles for high-capacitance supercapacitor fabrics. J. Mater. Chem. A 4, 6802 (2016)
D. Park, S. Selvam, J. Yim, Conformable on-skin supercapacitor-integrated, strain sensor based on multioxidant-functionalized thermoplastic polyurethane/reduced graphene oxide/polypyrrole composite films. N. J. Chem. 46, 10535 (2022)
Z.W. Sun, X.F. Wang, Z.W. Liu, Q.S. Gu, Y. Zhang, Z.K. Li, H.F. Ke, J. Yang, J.H. Wu, L.Q. Wu, G.Y. Zhang, C.Y. Zhang, Z.Y. Ma, Genome-wide association study discovered genetic variation and candidate genes of fibre quality traits in Gossypium hirsutum L. Plant Biotechnol. J. 8, 982 (2017)
S. Najib, E. Erdem, Current progress achieved in novel materials for supercapacitor electrodes: mini review. Nanoscale Adv. 1, 2817 (2019)
Y.B. Tan, J. Lee, Graphene for supercapacitor applications. J. Mater. Chem. A 1, 14814 (2013)
J. Ren, L. Li, C. Chen, X.L. Chen, Z.B. Cai, L.B. Qiu, Y.G. Wang, X.R. Zhu, H.S. Peng, twisting Carbon Nanotube fibers for both wire-shaped Micro-Supercapacitor and Micro-Battery. Adv. Mater. 25, 1155 (2013)
J. Noh, C.M. Yoon, Y.K. Kim, J. Jang, High performance asymmetric supercapacitor twisted from carbon fiber/MnO2 and carbon fiber/MoO3. Carbon 116, 470 (2017)
Y. Wang, S.S. Li, H.Y. Yang, J. Luo, Progress in the functional modification of graphene/graphene oxide: a review. RCS Adv. 10, 15328 (2020)
Z. Karami, M. Youssefi, K. Raeissi, M. Zhiani, An efficient textile-based electrode utilizing silver nanoparticles/reduced graphene oxide/cotton fabric composite for high-performance wearable supercapacitors. Electrochim. Acta 20, 1 (2020)
T. Kim, E.P. Samuel, C. Park, Y. Kim, A. Aldalbahi, F. Alotaibi, S.S. Yoon, Wearable fabric supercapacitors using supersonically sprayed reduced graphene and tin oxide. J. Alloys Compd. 856, 157902 (2021)
G. Bharath, A. Hai, K. Rambabu, F. Ahmed, A.S. Haidyrah, N. Ahmad, S.W. Hasan, F. Banat, Hybrid capacitive deionization of NaCl and toxic heavy metal ions using Faradic electrodes of silver nanospheres decorated pomegranate peel-derived activated carbon. Environ. Res. 197, 111110 (2021)
G. Bharath, K. Rambabu, F. Banat, A. Hai, A.F. Arangadi, N. Ponpandian, Enhanced electrochemical performances of peanut shell derived activated carbon and its Fe3O4 nanocomposites for capacitive deionization of Cr(VI) ions. Sci. Total Environ. 691, 713 (2019)
G. Bharath, K. Rambabu, C. Aubry, M.A. Haija, A.K. Nadda, N. Ponpandian, F. Banat, Self-assembled Co3O4 nanospheres on N-Doped reduced Graphene Oxide (Co3O4/N-RGO) Bifunctional Electrocatalysts for Cathodic reduction of CO2 and anodic oxidation of Organic Pollutants. ACS Appl. Energy Mater. 4, 11408 (2021)
G. Bharath, A. Hai, K. Rambabu, D. Savariraj, Y. Ibrahim, F. Banat, The fabrication of activated carbon and metal-carbide 2D framework-based asymmetric electrodes for the capacitive deionization of Cr(VI) ions toward industrial wastewater remediation. Environ. Sci. Water Res. Technol. 6, 351 (2020)
F. Ran, Y.T. Tan, W.J. Dong, Z. Liu, L.B. Kong, L. Kang, In situ polymerization and reduction to fabricate gold nanoparticle-incorporated polyaniline as supercapacitor electrode materials. Polym. Adv. Technol. 29(6), 1697-1705 (2018)
V. Vijayakumar, B. Anothumakkool, S. Kurungot, M. Winter, J.R. Nair, In situ polymerization process: an essential design tool for lithium polymer batteries. Energy Environ. Sci. 14, 2708 (2021)
X.Y. Xie, B.J. Xin, Z.M. Chen, Y.Q. Xu, Preparation and characterization of PANI-PPY/PET fabric conductive composite for supercapacitors. J. Text. Inst. 11, 2443 (2021)
A.I. Oje, A.A. Ogwu, M. Mirzaeian, N. Tsendzughul, A.M. Oje, Pseudo-capacitance of silver oxide thin film electrodes in ionic liquid for electrochemical energy application. J. Sci. Adv. Mater. Devices 4, 213 (2018)
X.T. Xu, Y. Liu, M. Wang, C. Zhu, T. Lu, R. Zhao, L.K. Pan, Hierarchical hybrids with microporous carbon spheres decorated three-dimensional graphene frameworks for capacitive applications in supercapacitor and deionization. Electrochim. Acta 193, 88 (2016)
W.W. Liu, X.B. Yan, J.W. Lang, C. Peng, Q. Xue, Flexible and conductive nanocomposite electrode based on graphene sheets and cotton cloth for supercapacitor. J. Mater. Chem. 22, 17245 (2012)
N. Sreeju, A. Rufus, D. Philip, Microwave-assisted rapid synthesis of copper nanoparticles with exceptional stability and their multifaceted applications. J. Mol. Liq. 221, 1008-1021 (2016)
A. Khan, A. Rashid, R. Younas, R. Chong, A chemical reduction approach to the synthesis of copper nanoparticles. Nano Lett. 6, 21 (2016)
Z. Tang, W.Y. Li, X.X. Lin, H. Xiao, Q.X. Miao, L.L. Huang, L.H. Chen, H. Wu, TEMPO-Oxidized cellulose with high degree of Oxidation. Polymers 9, 421 (2017)
S. Jadhav, R.S. Kalubarme, C. Terashima, B.B. Kale, V. Goadbole, Manganese dioxide/reduced graphene oxide composite an electrode material for high-performance solid state supercapacitor. Electrochim. Acta 299, 34 (2019)
G.Q. Xie, J. Cheng, Y.F. Li, P.X. Xi, F.J. Chen, H.Y. Liu, F.P. Hou, Y.J. Shi, L. Huang, Z.H. Xu, D.C. Bai, Z.Z. Zeng, Fluorescent graphene oxide composites synthesis and its biocompatibility study. J. Mater. Chem. 22, 9308 (2012)
X.R. He, Y.L. Hu, H.Q. Tian, Z.P. Li, P. Huang, J. Jiang, C. Wang, In situ growth of flexible 3D hollow tubular Cu2S nanorods on Cu foam for high electrochemical performance supercapacitor. J. Materiomics 6, 192 (2020)
J. Li, C.L. Chen, R. Zhang, X.K. Wang, Nanoscale Zero-Valent Iron particles supported on reduced Graphene Oxides by using a plasma technique and their application for removal of heavy-metal ions. Chem. Asian J. 10, 1410 (2015)
Y.Z. Li, Y.F. Zhang, H.R. Zhang, T.L. Xing, G.Q. Chen, A facile approach to prepare a flexible sandwich structured supercapacitor with rGO-coated cotton fabric as electrodes. RSC Adv. 9, 4180 (2019)
M. Barakzehi, M. Montazer, F. Sharif, T. Norby, A. Chatzitakis, A textile-based wearable supercapacitor using reduced graphene oxide/polypyrrole composite. Electrochim. Acta 305, 187 (2019)
J.S. Cui, S.X. Zhou, Highly conductive and ultra-durable electronic textiles via covalent immobilization of carbon nanomaterials on cotton fabric. J. Mater. Chem. C 6, 12273 (2018)
Y.J. Oh, J.J. Yoo, Y.I. Kim, J.K. Yoon, H.N. Yoon, J.H. Kim, S.B. Park, Oxygen functional groups and electrochemical capacitive behavior of incompletely reduced graphene oxides as a thin-film electrode of supercapacitor. Electrochim. Acta 116, 118 (2014)
X.L. Deng, Z.X. Wei, C.Y. Cui, Q.H. Liu, C.Y. Wang, J.M. Ma, Oxygen-deficient anatase TiO2@C nanospindles with pseudocapacitive contribution for enhancing lithium storage. J. Mater. Chem. A 10, 1 (2018)
B. Pandit, V.S. Devika, R.S. Babasaheb, Electroless-deposited Ag nanoparticles for highly stable energy-efficient electrochemical supercapacitor. J. Alloys Compd. 17, 1 (2017)
Y.L. Shao, M.F. El-Kady, J.Y. Sun, Y.J. Li, Q.H. Zhang, M.F. Zhu, H.Z. Wang, B. Dunn, R.B. Kaner, Design and mechanisms of asymmetric supercapacitors. Chem. Rev. 118, 9233 (2018)
Q. Chen, Y. Hu, C.G. Hu, H.H. Cheng, Z.P. Zhang, B.H. Shao, L.T. Qu, Graphene quantum dots–three-dimensional graphene composites for high-performance supercapacitors. Phys. Chem. Chem. Phys. 16, 19307 (2014)
L.M. Chen, H.Y. Yu, Z.H. Li, X. Chen, W.L. Zhou, Cellulose nanofiber derived carbon aerogel with 3D multiscale pore architecture for high performance supercapacitors. Nanoscale 13, 17837 (2021)
J.H. Yu, F.F. Xie, Z.C. Wu, T. Huang, J.F. Wu, D.D. Yan, C.Q. Huang, L. Li, Flexible metallic fabric supercapacitor based on graphene/polyaniline composites. Electrochim. Acta 259, 968 (2018)
D.J. Ahirrao, A.K. Pal, V. Singh, N. Jha, Nanostructured porous polyaniline (PANI) coated carbon cloth (CC) as electrodes for flexible supercapacitor device. J. Mater. Sci. Technol. 88, 168 (2021)
S. Mao, Z.H. Wen, B. Zheng, J.B. Chang, X.K. Huang, J.H. Chen, Hierarchical nanohybrids with porous CNT-Networks decorated crumpled Graphene Balls for Supercapacitors. ACS Appl. Mater. Interfaces 6, 9881 (2014)
C. Wang, K. Hu, W.J. Li, H.Y. Wang, H. Li, Y. Zou, C.C. Zhao, Z. Li, M. Yu, P.C. Tan, Z. Li, Wearable wire-shaped symmetric supercapacitors based on activated Carbon-Coated Graphite fibers. ACS Appl. Mater. Interfaces 10, 34302 (2018)
Funding
This work was supported by the Zhejiang Provincial Natural Science Foundation of China (LY21F040008, LY21E020011) and the Applied Basic Research Project of China National Textile and Apparel Council (J201801).
Author information
Authors and Affiliations
Contributions
All authors contributed to the study conception and design. XYJ contributed to conceptualization, methodology, part of investigation, data curation, writing of the original draft, and visualization. BB contributed to validation and part of investigation. Resources and formal analysis were performed by JXS. Supervision and writing, reviewing, and editing of the manuscript were performed by LLQ. PFD contributed to supervision, project administration, writing, reviewing, and editing of the manuscript, and funding acquisition. All authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interest or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Jiang, X., Bai, B., Shui, J. et al. CuNPs/RGO/cotton fabric electrode for flexible high-performance supercapacitors. J Mater Sci: Mater Electron 34, 910 (2023). https://doi.org/10.1007/s10854-023-10334-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10854-023-10334-9