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Electronic, nano-dielectric, mass and fluorescence spectral characterizations of 2-amino 4-methyl pyridinium fumarate novel crystals for use in opto-electronics and electronic displays

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Abstract

The 2-amino 4-methyl pyridinium fumarate—AMPF crystals are successfully grown by the traditional slow evaporation solution growth method; the solubility curve represents the data for the variety of temperature scales. Single XRD data reveal that the AMPF crystalline specimen is monoclinic in nature. The mass spectral study provides the molecular mass value which is found to 224.513 for the as-grown crystals. The optical study represents the UV cut-off wavelength as 255 nm; after 320 nm, the absorbance value is nearly nullified and is the expected property for good non-linear optical (NLO) specimen; the refranging property tells that the fluorescence emission wavelength is 396 nm with a band gap of 3.1313 eV for violet emission and for value of excitation at 294 nm. The morphological picture of AMPF is shown by SEM micrograph; the hardness contour for AMPF delineates the value of n as 3.59 and is of Reverse Indentation Size Effect (RISE); the AMPF crystalline specimen is found to exhibit negative type of photoconductivity and based on Miller’s projection may practice for display devices with NLO data for opto-electronic with coupling enhancing provision and in nano-dielectrics for micro-electronic sectors utility.

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Acknowledgements

The authors would like to thank St. Joseph’s College for the studies and IITM for data and Phoenix Institute for electronic studies.

Funding

The paper attracts no funding and is authors’ own funding for this studies contributing paper.

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Authors and Affiliations

  1. Department of Chemistry, S.A. Engineering College, Poonamalle, Chennai, Tamilnadu, 600077, India

    R. Hariharasuthan

  2. Department of Chemistry, R.M.D Engineering College, Chennai, Tamilnadu, 601206, India

    K. S. Radha

  3. Department of Chemistry, C.Abdul Hakeem College (Autonomous), Melvisharam, Tamilnadu, 632509, India

    Z. Abdul Vaheith

  4. Department of Physics/R&D, Edayathangudy G.S Pillay Arts and Science College (Autonomous - Affiliated to Bharathidasan University, Trichy 620 024), Nagapattinam, Tamilnadu, 611 002, India

    K. SenthilKannan

  5. R&D (V), Phoenix Group, Nagapattinam, Tamilnadu, 611002, India

    K. SenthilKannan

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  1. R. Hariharasuthan
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Contributions

RH contributed to XRD and FL data. KSR provided mass spectral data and performed proof reading. ZAV provided hardness and UV data. KSK contributed to growth, computational, SEM, photoconductivity, write-up, and submission.

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Correspondence to K. SenthilKannan.

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Hariharasuthan, R., Radha, K.S., Abdul Vaheith, Z. et al. Electronic, nano-dielectric, mass and fluorescence spectral characterizations of 2-amino 4-methyl pyridinium fumarate novel crystals for use in opto-electronics and electronic displays. J Mater Sci: Mater Electron 34, 743 (2023). https://doi.org/10.1007/s10854-023-10158-7

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