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Electro-optical properties of silver nanowire thin film

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Abstract

High electrical conductivity, high transparency and mechanical flexibility are important properties in generations of transparent conductive electrodes. Currently the most efficient and widely used transparent conductive material is Indium Tin Oxide. Searching for alternative materials has been being followed due to the lack of Indium resources, ITO inflexibility and its high manufacturing costs. In the present study, silver nanowire as a promising alternative to ITO was synthesized through polyol method and then silver nanowire layer was applied on glassy substrates using drop-casting method. Adhesion between the layer and the substrate was established using polyaniline. Characterization of the thin film was conducted using X-ray diffraction methods, field emission scanning electron microscopy, UV–Vis spectroscopy and a four-point probe. The results show that corrective deoxidation operations and separation of nanowires from nanoparticles, leads to an increase in transparency from 79 to 81.4% and decrease sheet resistance of 89 to 76 Ω/.

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References

  1. X. Li, J. Zhou, D. Yan, Y. Peng, Y. Wang, Q. Zhou, K. Wang, Effects of concentration and spin speed on the optical and electrical properties of silver nanowire transparent electrodes. Materials 14, 2219 (2021)

    Article  CAS  Google Scholar 

  2. Y. Zhang, J.N. Guo, D. Xu, Y. Sun, F. Yan, one-pot synthesis and purification of ultralong silver nanowires for flexible transparent conductive electrodes. ACS Appl. Mater. Interfaces 9, 25465–25473 (2017)

    Article  CAS  Google Scholar 

  3. F. Qiang, M. Jinlei, L. Xuhua, Z. Xingwei, Z. Wenxiao, T. Mingwei, Z. Shiefeng, Q. Lijun, Z. Xueji, Biomimetic hierarchically silver nanowire interwoven MXene mesh for flexible transparent electrodes and invisible camouflage electronics. ACS Nano Lett. 22, 740–750 (2022)

    Article  Google Scholar 

  4. M. Oh, W. Jin, H. Jeong, M. Jeong, J. Kang, H. Kim, Silver nanowire transparent conductive electrodes for high-efficiency III-nitride light-emitting diodes. Sci. Rep. 5, 13483 (2015)

    Article  Google Scholar 

  5. D.H. Kim, N.H. Park, T.W. Kim, Highly efficient flexible organic light-emitting devices based on PEDOT:PSS electrodes doped with highly conductive Pyronin B. Nano Energy 65, 104027 (2019)

    Article  CAS  Google Scholar 

  6. S. Fahad, H. Yu, L. Wang, Recent progress in the synthesis of silver nanowires and their role as conducting materials. Mater. Sci. 54, 997–1035 (2019)

    Article  CAS  Google Scholar 

  7. F. Fiévet, F. Ammar-Merah, R. Brayner, The polyol process a unique method for easy access to metal nanoparticles with tailored sizes, shapes and compositions. Chem. Soc. Rev. 47, 5187–5233 (2018)

    Article  Google Scholar 

  8. L. Zhang, T. Song, L. Shi, N. Wen, Z. Wu, C. Sun, D. Jiang, Z. Guo, Recent progress for silver nanowires conducting film for flexible electronics. Nanostruct. Chem. 11, 323–341 (2021)

    Article  CAS  Google Scholar 

  9. J. Han, J. Yang, W. Gao, H. Bai, Ice-Templated, Large-area silver nanowire pattern for flexible transparent electrode. Adv. Func. Mater. 31, 2010155 (2021)

    Article  CAS  Google Scholar 

  10. S. Lim, Cu-based multilayer transparent electrodes: a low-cost alternative to ITO electrodes in organic solar cells. Sol. Energy Mater. Sol. Cells 101, 170–175 (2013)

    Article  Google Scholar 

  11. R. Yin, Sh. Yang, Q. Li, Sh. Zhang, H. Liu, J. Han, Ch. Liu, Flexible conductive Ag nanowire nanofibril hybrid nanopaper for strain and temperature sensing applications. Sci. Bull. 65, 899–908 (2020)

    Article  CAS  Google Scholar 

  12. R. Chen, S.R. Das, Ch. Jeong, M.R. Khan, D.B. Janes, M.A. Alam, Co-Percolating graphene-wrapped silver nanowire network for high performance, highly stable transparent conducting electrodes. Adv Funct. Mater. 23, 5150 (2016)

    Article  Google Scholar 

  13. J. Kim, S. Kim, H. Kil, Y. Kim, J. Park, Highly conformable, transparent electrodes for epidermal electronics. Nano Lett. 18, 4531–4540 (2018)

    Article  CAS  Google Scholar 

  14. F. Xu, W. Xu, B. Mao, W. Shen, Y. Yu, R. Tan, W. Song, Preparation and cold welding of silver nanowire based transparent electrodes with optical transmittances >90% and sheet resistances <10 ohm/sq. J. Colloid Interface Sci. 512, 201–208 (2018)

    Article  Google Scholar 

  15. B. Bari, J. Lee, T. Jang, P. Won, S. Ko, Kh. Alamgir, M. Arshadd, L. Guo, Simple hydrothermal synthesis of very-long and thin silver nanowires and their application in high quality transparent electrodes. Mater. Chem. A 29, 11141 (2016)

    Google Scholar 

  16. S. Na, S. Kim, Efficient and flexible ITO-free organic solar cells using highly conductive polymer anodes. Adv. Mater. 20, 4061–4067 (2018)

    Article  Google Scholar 

  17. I. Hu, Sh. Tu, Zh. Huang, Y. Wei, Silver nanowires: synthesis technologies, growth mechanism and multifunctional applications. Mater. Sci. Eng. 223, 1–23 (2017)

    Article  Google Scholar 

  18. M. Talukdar, E. Baker, Conductivity studies on silver oxide. Solid State Commun. 7, 309–310 (1969)

    Article  CAS  Google Scholar 

  19. B. L’vov, Kinetics and mechanism of thermal decomposition of silver oxide. Thermochim. Acta 333, 13–19 (1999)

    Article  Google Scholar 

  20. M.T. Molares, A.G. Balogh, T. Cornelius, R. Neumann, C. Trautmann, Fragmentation of nanowires driven by Rayleigh instability. Appl. Phys. 85, 5337–5339 (2004)

    Google Scholar 

  21. G. Haacke, New figure of merit for transparent conductors. Appl. Phys. 47, 4086 (1976)

    Article  CAS  Google Scholar 

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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by MS, AE and AAA. The first draft of the manuscript was written by MS and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Muhammad Saeidi.

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Saeidi, M., Eshaghi, A. & Aghaei, A.A. Electro-optical properties of silver nanowire thin film. J Mater Sci: Mater Electron 34, 110 (2023). https://doi.org/10.1007/s10854-022-09621-8

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