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Enhanced electrical and energy storage properties of BNT-based ceramics by the nanocrystals-induced method

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Abstract

The effect of BT nanocrystals on phase structure and electrical characteristics of lead-free BNT ceramics was investigated in this study. The molten-salt method was used to make the BT nanocrystals. All ceramics showed a pure perovskite phase. The density values ranged from 5.87 to 5.91 g/cm3. The highest density value was obtained for the sample of BT seed = 5 mol%. With increasing BT seed content, the dielectric constant (εr) at room temperature tended to increase. The sample of 10BTs (x = 10 mol%) had the highest dielectric constant (εr = 1652). For compositions of BT-added, the dielectric spectra showed a broad maximum around TF–R. The sample of 5BTs (x = 5 mol%) had the highest d33 value of 161 pC/N. Furthermore, a high energy storage density (W ~ 0.69 J/cm3) with the highest energy storage efficiency (η = 70%) was obtained from the sample of BT nanocrystals added (BTs = 0.10 mol%).

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Data availability

The authors confirm that all data generated or analyzed during this study are included in this published article. The data supporting the findings of this study are available within the article.

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Acknowledgements

The authors would like to thank the Thailand Research Fund (TRF) under the Research Grant for new scholar (MRG6180111), Faculty of Science and Technology, Rajamangala University of Technology Krungthep under the Research and Development Institute for financial support. Also, this research work was partially supported by Chiang Mai University.

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Authors and Affiliations

  1. Physics Division, Faculty of Science and Technology, Rajamangala University of Technology Krungthep, Bangkok, 10120, Thailand

    Piewpan Parjansri

  2. Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand

    Manlika Kamnoy & Sukum Eittsayeam

  3. Materials for Energy and Environment Research Group (MEE), School of Science, Mae Fah Luang University, Chiang Rai, 57100, Thailand

    Uraiwan Inthata

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  1. Piewpan Parjansri
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Each author contributed significantly to the work’s conception or design; data acquisition, analysis, and interpretation; the development of new software used in the work; drafted or substantially revised the work; and approved the submitted version.

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Parjansri, P., Kamnoy, M., Eittsayeam, S. et al. Enhanced electrical and energy storage properties of BNT-based ceramics by the nanocrystals-induced method. J Mater Sci: Mater Electron 34, 48 (2023). https://doi.org/10.1007/s10854-022-09443-8

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