Abstract
Multiferroics particles with the chemical formula of FeTiVO6 (FTVO) were synthesized using a solid-state reaction and blended with PDMS to obtain flexible composites. The FTVO particles crystallize in orthorhombic symmetry, and the multiferroic nature was confirmed using room temperature M-H and P-E hysteresis loops. A triboelectric nanogenerator (TENG) device was prepared using the composite at different wt% of FTVO-PDMS as a triboelectric layer. To enhance the output performance of TENG, microroughness composites were prepared following a cost-effective route. The 5 wt% of FTVO in the PDMS composite-based device delivered a higher electrical output of 110 V, 0.8 µA, and power of 65 µW at 108 Ω. The demonstration of charging capacitors confirms that the TENG can act as a sustainable power source. The long-term stability of the device output confirms that fabricated TENG can be utilized as self-powered sensors. Humidity is a factor that limits the performance of the TENG. The packing of the TENG could solve this problem by stopping the interaction of triboelectric layers with moisture and humidity. Hence, demonstration of the packed TENG under harsh conditions such as inside the water tub and at varying humidity levels was carried out to confirm the stability of the output.
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References
T. Li, P.S. Lee, Small Struct. 3, 2100128 (2022)
T. Ahmad, D. Zhang, Energy Rep. 6, 1973–1991 (2020)
G. Grancini, M.K. Nazeeruddin, Nat. Rev. Mater. 4, 4–22 (2019)
S. Panda, S. Hajra, H. Jeong, B.K. Panigrahi, P. Pakawanit, D. Dubal, S. Hong, H.J. Kim, Nano Energy 102, 107682 (2022)
Z. Yang, S. Zhou, J. Zu, D. Inman, Joule 2, 642–697 (2018)
Y. Yun, S. Jang, S. Cho, S.H. Lee, H.J. Hwang, D. Choi, Nano Energy 80, 105525 (2021)
S. Hajra, Y. Oh, M. Sahu, K. Lee, H.-G. Kim, B.K. Panigrahi, K. Mistewicz, H.J. Kim, Sustain. Energy Fuels 5, 6049–6058 (2021)
S. Hajra, M. Sahu, R. Sahu, A.M. Padhan, P. Alagarsamy, H.-G. Kim, H. Lee, S. Oh, Y. Yamauchi, H.J. Kim, Nano Energy 98, 107253 (2022)
S. Hajra, M. Sahu, A.M. Padhan, J. Swain, B.K. Panigrahi, H.-G. Kim, S.-W. Bang, S. Park, R. Sahu, H.J. Kim, J. Mater. Chem. C 9, 17319–17330 (2021)
S. Panda, S. Hajra, K. Mistewicz, P. In-na, M. Sahu, P.M. Rajaitha, H.J. Kim, Nano Energy 100, 107514 (2022)
F.-R. Fan, Z.-Q. Tian, Z.Lin Wang, Nano Energy 1, 328–334 (2012)
A. Ahmed, I. Hassan, I.M. Mosa, E. Elsanadidy, G.S. Phadke, M.F. El-Kady, J.F. Rusling, P.R. Selvaganapathy, R.B. Kaner, Nano Energy 60, 17–25 (2019)
X.-S. Zhang, M. Han, B. Kim, J.-F. Bao, J. Brugger, H. Zhang, Nano Energy 47, 410–426 (2018)
Y.Y. Ke, T.M. Chou, Z.H. Lin, ECS Trans. 72, 53–57 (2016)
Y. Li, G. Li, P. Zhang, H. Zhang, C. Ren, X. Shi, H. Cai, Y. Zhang, Y. Wang, Z. Guo, H. Li, G. Ding, H. Cai, Z. Yang, C. Zhang, Z.L. Wang, Adv. Energy Mater. 11, 2003921 (2021)
C. Huang, G. Chen, A. Nashalian, J. Chen, Nanoscale 13, 2065–2081 (2021)
M. Sahu, V. Vivekananthan, S. Hajra, D.K. Khatua, S.-J. Kim, Appl. Mater. Today 22, 100900 (2021)
X.-S. Zhang, M.-D. Han, R.-X. Wang, B. Meng, F.-Y. Zhu, X.-M. Sun, W. Hu, W. Wang, Z.-H. Li, H.-X. Zhang, Nano Energy 4, 123–131 (2014)
X. Cheng, Z. Song, L. Miao, H. Guo, Z. Su, Y. Song, H.-X. Zhang, J. Microelectromech. Syst. 27, 106–112 (2017)
X.-S. Zhang, M.-D. Han, R.-X. Wang, F.-Y. Zhu, Z.-H. Li, W. Wang, H.-X. Zhang, Nano Lett. 13, 1168–1172 (2013)
Y.H. Kwon, S.-H. Shin, J.-Y. Jung, J. Nah, Nanotechnology 27, 205401 (2016)
S. Hajra, A.M. Padhan, M. Sahu, P. Alagarsamy, K. Lee, H.J. Kim, Nano Energy 89, 106316 (2021)
M. Sahu, R.N.P. Choudhary, S.K. Das, S. Otta, B.K. Roul, J. Mater. Sci.: Mater. Electron. 28, 15676–15684 (2017)
S. Sriphan, N. Vittayakorn, Smart Mater. Struct. 27, 105026 (2018)
H.J. Hwang, Y. Lee, C. Lee, Y. Nam, J. Park, D. Choi, D. Kim, Micromachines 9, 656 (2018)
D. Jang, Y. Kim, T.Y. Kim, K. Koh, U. Jeong, J. Cho, Nano Energy 20, 283–293 (2016)
D. Kim, S. Lee, Y. Ko, C.H. Kwon, J. Cho, Nano Energy 44, 228–239 (2018)
Q. Guan, X. Lu, Y. Chen, H. Zhang, Y. Zheng, R.E. Neisiany, Z. You, Adv. Mater. 34, 2204543 (2022)
M. Li, H.-W. Lu, S.-W. Wang, R.-P. Li, J.-Y. Chen, W.-S. Chuang, F.-S. Yang, Y.-F. Lin, C.-Y. Chen, Y.-C. Lai, Nat. Commun. 13, 938 (2022)
Y. Xiao, B. Xu, Q. Bao, Y. Lam, Polymers 14, 3029 (2022)
B. Li, H. Liu, Y. Sun, Y. Cao, Y. Guo, J. Mater. Sci.: Mater. Electron. 33, 5335–5340 (2022)
N. Bhalla, N. Ingle, H. Patel, A. Jayaprakash, S.V. Patri, A. Kaushik, D. Haranath, Arab. J. Chem. 15, 103862 (2022)
P. Manickam, S.A. Mariappan, S.M. Murugesan, S. Hansda, A. Kaushik, R. Shinde, S.P. Thipperudraswamy, Biosensors 12, 562 (2022)
Y.-H. Chu, L.W. Martin, M.B. Holcomb, M. Gajek, S.-J. Han, Q. He, N. Balke, C.-H. Yang, D. Lee, W. Hu, Q. Zhan, P.-L. Yang, A. Fraile-Rodríguez, A. Scholl, S.X. Wang, R. Ramesh, Nat. Mater. 7, 478–482 (2008)
R. Hochleitner, E. Schmidbauer, J. Electroceram. 29, 240–249 (2012)
F. Zhou, S. Kotru, R.K. Pandey, Mater. Lett. 57, 2104–2109 (2003)
P. Sharma, S. Hajra, S. Sahoo, P.K. Rout, R.N.P. Choudhary, Process. Appl. Ceram. 11, 171–176 (2017)
S. Hajra, S. Sahoo, M. De, P.K. Rout, H.S. Tewari, R.N.P. Choudhary, J. Mater. Sci.: Mater. Electron. 29, 1463–1472 (2018)
S. Divya, K. Jeyadheepan, J. Hemalatha, J. Magn. Magn. Mater. 492, 165689 (2019)
P. Gupta, P.K. Mahapatra, R.N.P. Choudhary, Cryst. Res. Technol. 53, 1800045 (2018)
X. Zhang, Q. Zhao, Z. Cai, J. Pan, Metals 10, 141 (2020)
Funding
This study is supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT of Korea (2021R1C1C1011588) and the DGIST R&D Program (22-RT-01; 22-SENS-01). The authors also would like to thank the DGIST Undergraduate Group Research Program (UGRP) Grant (2022020012).
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YO contributed to investigation and formal analysis. SH contributed to conceptualization and writing-original draft. SD contributed to formal analysis. SP contributed to data curation and investigation. HS and WO contributed to data curation. JL contributed to visualization. THO contributed to writing: review and editing. PLD contributed to investigation. HJK contributed to supervision, funding acquisition, and writing: review and editing.
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Oh, Y., Hajra, S., Divya, S. et al. Polymer-multiferroics composite-based sustainable triboelectric energy harvester. J Mater Sci: Mater Electron 33, 26852–26860 (2022). https://doi.org/10.1007/s10854-022-09350-y
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DOI: https://doi.org/10.1007/s10854-022-09350-y