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One-pot synthesis of reduced graphene oxide-based PANI/MnO2 ternary nanostructure for high-efficiency supercapacitor applications

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Abstract

Energy shortage imposes major global issues, and developing new energy storage devices has become extremely urgent. Because supercapacitors (SCs) have been regarded as inspirational energy storage technologies. Herein, a novel rGO/PANI/MnO2 material was developed via a chemical reduction method for high-rate supercapacitors. The morphological structural & textural properties of fabricated  nanostructure been investigated with X-ray diffraction, scanning electron microscope (SEM) & Brunauer–Emmett–Teller (BET). Electrochemical characterization of advanced nanocomposite contains specific capacitance (Csp) of 1613.7 F g−1 with enhanced rate capabilities and cycling stability retention of 99.7% with original capacity after 2000 cycles in 2 M KOH. Excellent efficiency of fabricated material is attributed due to small crystallite size, good morphology, and enhanced electrochemical surface area. This study emphasizes the good electrochemical performance of rGO/PANI/MnO2 on carbon fiber. The flake like morphology of the composite provides numerous electronic conduction routes, and more active sites refer it to be potential candidate for energy storage devices.

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Data availability

The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

References

  1. B.G. Pollet, I. Staffell, J.L. Shang, V. Molkov, Fuel-cell (hydrogen) electric hybrid vehicles. Altern. Fuels Adv. Veh. Technol. Improv. Environ. Perform. Towar. Zero Carbon Transp. (2014). https://doi.org/10.1533/9780857097422.3.685

    Article  Google Scholar 

  2. Y. Li, Y. Li, P. Ji, J. Yang, development of energy storage industry in China: a technical and economic point of review. Renew. Sustain. Energy Rev. 49, 805–812 (2015). https://doi.org/10.1016/J.RSER.2015.04.160

    Article  Google Scholar 

  3. H. Wang, D. Tran, J. Qian et al., MoS2/graphene composites as promising materials for energy storage and conversion applications. Adv. Mater. Interfaces 6, 1900915 (2019). https://doi.org/10.1002/ADMI.201900915

    Article  CAS  Google Scholar 

  4. H. Chen, T.N. Cong, W. Yang et al., Progress in electrical energy storage system: a critical review. Prog. Nat. Sci. 19, 291–312 (2009). https://doi.org/10.1016/J.PNSC.2008.07.014

    Article  CAS  Google Scholar 

  5. J. Zhu, D. Yang, Z. Yin et al., Graphene and graphene-based materials for energy storage applications. Small 10, 3480–3498 (2014). https://doi.org/10.1002/SMLL.201303202

    Article  CAS  Google Scholar 

  6. X. Wang, D. Wu, X. Song et al., Review on carbon, polyaniline hybrids: design and synthesis for supercapacitor. Page 2263(24), 2263 (2019). https://doi.org/10.3390/MOLECULES24122263

    Article  Google Scholar 

  7. Liao CH, Huang CW, Wu JCS (2012) Hydrogen Production from Semiconductor-based Photocatalysis via Water Splitting. Catal 2012, Vol 2, Pages 490–516 2:490–516. https://doi.org/10.3390/CATAL2040490

  8. A. Mishra, A. Mehta, S. Basu et al., Graphitic carbon nitride (g–C3N4)–based metal-free photocatalysts for water splitting: a review. Carbon N Y 149, 693–721 (2019). https://doi.org/10.1016/J.CARBON.2019.04.104

    Article  CAS  Google Scholar 

  9. T. Ma, H. Yang, L. Lu, Development of hybrid battery–supercapacitor energy storage for remote area renewable energy systems. Appl. Energy 153, 56–62 (2015). https://doi.org/10.1016/J.APENERGY.2014.12.008

    Article  Google Scholar 

  10. Hu X, Tseng KJ, Srinivasan M (2011) Optimization of battery energy storage system with super-capacitor for renewable energy applications. 8th Int Conf Power Electron - ECCE Asia "Green World with Power Electron ICPE 2011-ECCE Asia. 1552–1557 https://doi.org/10.1109/ICPE.2011.5944515

  11. A. Pramitha, Y. Raviprakash, Recent developments and viable approaches for high-performance supercapacitors using transition metal-based electrode materials. J. Energy Storage 49, 104120 (2022). https://doi.org/10.1016/J.EST.2022.104120

    Article  Google Scholar 

  12. Electrodeposition of Nickel Cobalt Oxide for the Application of Asymmetric Flexible Microsupercapacitor. http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/818. Accessed 27 May 2022

  13. F. Qi, X. Lu, Y. Wang et al., Fabrication of hierarchical MoO3@NixCo2x(OH)6x core–shell arrays on carbon cloth as enhanced-performance electrodes for asymmetric supercapacitors. J. Colloid. Interface Sci. 607, 1253–1261 (2022). https://doi.org/10.1016/J.JCIS.2021.09.046

    Article  CAS  Google Scholar 

  14. F. Qi, L. Shao, X. Shi et al., “Carbon quantum dots-glue” enabled high-capacitance and highly stable nickel sulphide nanosheet electrode for supercapacitors. J. Colloid. Interface Sci. 601, 669–677 (2021). https://doi.org/10.1016/J.JCIS.2021.05.099

    Article  CAS  Google Scholar 

  15. S. Wang, L. Shao, L. Yu et al., Niobium carbide as a promising pseudocapacitive sodium-ion storage anode. Energy Technol. 9, 2100298 (2021). https://doi.org/10.1002/ENTE.202100298

    Article  CAS  Google Scholar 

  16. Y. Pi, W. Sun, M. Yan et al., Achieving high-performance energy storage device of Li3V2(PO4)3 // LiCrTiO4 Li-ion full cell. J. Power Sources 518, 230770 (2022). https://doi.org/10.1016/J.JPOWSOUR.2021.230770

    Article  CAS  Google Scholar 

  17. L. Pu, J. Zhang, N.K.L. Jiresse et al., N-doped MXene derived from chitosan for the highly effective electrochemical properties as supercapacitor. Adv. Compos. Hybrid. Mater. 5, 356–369 (2022). https://doi.org/10.1007/S42114-021-00371-5/FIGURES/10

    Article  CAS  Google Scholar 

  18. M. Sivakumar, B. Muthukutty, G. Panomsuwan et al., Facile synthesis of NiFe2O4 nanoparticle with carbon nanotube composite electrodes for high-performance asymmetric supercapacitor. Colloids. Surfaces A Physicochem. Eng. Asp 648, 129188 (2022). https://doi.org/10.1016/J.COLSURFA.2022.129188

    Article  CAS  Google Scholar 

  19. H.T. Das, T EB, Dutta S, et al., Recent trend of CeO2-based nanocomposites electrode in supercapacitor: a review on energy storage applications. J. Energy Storage 50, 104643 (2022). https://doi.org/10.1016/J.EST.2022.104643

    Article  Google Scholar 

  20. M.S. Islam, Y. Shudo, S. Hayami, Energy conversion and storage in fuel cells and super-capacitors from chemical modifications of carbon allotropes: state-of-art and prospect. Bulletin Chem. Soc. Japan (2021). https://doi.org/10.1246/BCSJ.20210297

    Article  Google Scholar 

  21. N. Devi, S. Sahoo, R. Kumar, R.K. Singh, A review of the microwave-assisted synthesis of carbon nanomaterials, metal oxides/hydroxides and their composites for energy storage applications. Nanoscale 13, 11679–11711 (2021). https://doi.org/10.1039/D1NR01134K

    Article  CAS  Google Scholar 

  22. J. Luo, W. Zhong, Y. Zou et al., Preparation of morphology-controllable polyaniline and polyaniline/graphene hydrogels for high performance binder-free supercapacitor electrodes. J. Power Sources 319, 73–81 (2016). https://doi.org/10.1016/J.JPOWSOUR.2016.04.004

    Article  CAS  Google Scholar 

  23. R.L. Razalli, M.M. Abdi, P.M. Tahir et al., Polyaniline-modified nanocellulose prepared from semantan bamboo by chemical polymerization: preparation and characterization. RSC Adv. 7, 25191–25198 (2017). https://doi.org/10.1039/C7RA03379F

    Article  CAS  Google Scholar 

  24. T. Tao, J. He, Y. Wang et al., Microwave-assisted hydrothermal synthesis of three-dimensional NbOPO4-reduced graphene oxide-carbon nanotube composite for high performance sodium-ion battery anode. J. Power Sources 539, 231457 (2022). https://doi.org/10.1016/J.JPOWSOUR.2022.231457

    Article  CAS  Google Scholar 

  25. S.A. Habib, S.A. Saafan, T.M. Meaz et al., Structural, magnetic, and AC measurements of nanoferrites, graphene composites. Nanomater 931(12), 931 (2022). https://doi.org/10.3390/NANO12060931

    Article  Google Scholar 

  26. G. Liu, Y. Yang, X. Lu et al., Fully active bimetallic phosphide Zn0.5Ge0.5P: a novel high-performance anode for na-ion batteries coupled with diglyme-based electrolyte. ACS Appl. Mater. Interfaces 14, 31803–31813 (2022). https://doi.org/10.1021/ACSAMI.2C03813

    Article  CAS  Google Scholar 

  27. R. Oraon, A. De Adhikari, S.K. Tiwari, G.C. Nayak, Enhanced specific capacitance of self-assembled three-dimensional carbon nanotube/layered silicate/polyaniline hybrid sandwiched nanocomposite for supercapacitor applications. ACS Sustain. Chem. Eng. 4, 1392–1403 (2016). https://doi.org/10.1021/ACSSUSCHEMENG.5B01389/ASSET/IMAGES/LARGE/SC-2015-013896_0014.JPEG

    Article  CAS  Google Scholar 

  28. S. Sivakumar, L. Nelson Prabu, Synthesis and Characterization of α-MnO2 nanoparticles for Supercapacitor application. Mater. Today Proc. 47, 52–55 (2021). https://doi.org/10.1016/J.MATPR.2021.03.528

    Article  CAS  Google Scholar 

  29. H. Fan, H. Zhang, X. Luo et al., Hydrothermal solid-gas route to TiO2 nanoparticles/nanotube arrays for high-performance supercapacitors. J. Power Sources 357, 230–240 (2017). https://doi.org/10.1016/J.JPOWSOUR.2017.05.009

    Article  CAS  Google Scholar 

  30. S. Vijayakumar, A. Kiruthika Ponnalagi, S. Nagamuthu, G. Muralidharan, Microwave assisted synthesis of Co3O4 nanoparticles for high-performance supercapacitors. Electrochim. Acta. 106, 500–505 (2013). https://doi.org/10.1016/J.ELECTACTA.2013.05.121

    Article  CAS  Google Scholar 

  31. T. Zahra, K.S. Ahmad, C. Zequine et al., Electro-catalyst [ZrO2/ZnO/PdO]-NPs green functionalization: fabrication, characterization and water splitting potential assessment. Int. J. Hydrogen Energy 46, 19347–19362 (2021). https://doi.org/10.1016/J.IJHYDENE.2021.03.094

    Article  CAS  Google Scholar 

  32. L. Mohan, A.V. Avani, P. Kathirvel et al., Investigation on structural, morphological and electrochemical properties of Mn doped WO3 nanoparticles synthesized by co-precipitation method for supercapacitor applications. J. Alloys Compd. 882, 160670 (2021). https://doi.org/10.1016/J.JALLCOM.2021.160670

    Article  CAS  Google Scholar 

  33. Y. Zhang, J. Zheng, Q. Wang et al., One-step hydrothermal preparation of (NH4)2V3O8/carbon composites and conversion to porous V2O5 nanoparticles as supercapacitor electrode with excellent pseudocapacitive capability. Appl. Surf. Sci. 423, 728–742 (2017). https://doi.org/10.1016/J.APSUSC.2017.06.249

    Article  CAS  Google Scholar 

  34. H. Zhang, Y. Chen, Y. Wang et al., A highly electroactive poly(aniline-co-thionine) for rechargeable zinc batteries. J. Electrochem. Soc. 168, 060526 (2021). https://doi.org/10.1149/1945-7111/AC0945

    Article  CAS  Google Scholar 

  35. C. Chen, Z. Gan, C. Xu et al., Electrosynthesis of poly(aniline-co-azure B) for aqueous rechargeable zinc-conducting polymer batteries. Electrochim. Acta. 252, 226–234 (2017). https://doi.org/10.1016/J.ELECTACTA.2017.08.195

    Article  CAS  Google Scholar 

  36. Z. Gan, N. Song, H. Zhang et al., One-step electrofabrication of reduced graphene oxide/poly(N-methylthionine) composite film for high performance supercapacitors. J. Electrochem. Soc. 167, 085501 (2020). https://doi.org/10.1149/1945-7111/AB8C82

    Article  CAS  Google Scholar 

  37. M. Ramezani, M. Fathi, F. Mahboubi, Facile synthesis of ternary MnO2/graphene nanosheets/carbon nanotubes composites with high rate capability for supercapacitor applications. Electrochim. Acta. 174, 345–355 (2015). https://doi.org/10.1016/J.ELECTACTA.2015.05.155

    Article  CAS  Google Scholar 

  38. M. Kumar, X. Xiong, Z. Wan et al., Ball milling as a mechanochemical technology for fabrication of novel biochar nanomaterials. Bioresour. Technol. 312, 123613 (2020). https://doi.org/10.1016/J.BIORTECH.2020.123613

    Article  CAS  Google Scholar 

  39. H. Takahashi, H. Fujiki, S. Yokoyama et al., Synthesis of carbon nanomaterials from different pyrolysis techniques: a review. Mater. Res. Express 5, 052002 (2018). https://doi.org/10.1088/2053-1591/AAC05B

    Article  Google Scholar 

  40. T.A. Nguyen, V.N.T. Pham, H.T. Le et al., Crystal structure and magnetic properties of LaFe1-xNixO3 nanomaterials prepared via a simple co-precipitation method. Ceram. Int. 45, 21768–21772 (2019). https://doi.org/10.1016/J.CERAMINT.2019.07.178

    Article  CAS  Google Scholar 

  41. K.H. Tam, C.K. Cheung, Y.H. Leung et al., Defects in ZnO nanorods prepared by a hydrothermal method. J. Phys. Chem. B 110, 20865–20871 (2006). https://doi.org/10.1021/JP063239W/ASSET/IMAGES/LARGE/JP063239WF00008.JPEG

    Article  CAS  Google Scholar 

  42. N. Liu, X. Chen, J. Zhang, J.W. Schwank, A review on TiO2-based nanotubes synthesized via hydrothermal method: formation mechanism, structure modification, and photocatalytic applications. Catal. Today 225, 34–51 (2014). https://doi.org/10.1016/J.CATTOD.2013.10.090

    Article  CAS  Google Scholar 

  43. L. Huang, F. Peng, H. Wang et al., Preparation and characterization of Cu2O/TiO2 nano–nano heterostructure photocatalysts. Catal. Commun. 10, 1839–1843 (2009). https://doi.org/10.1016/J.CATCOM.2009.06.011

    Article  CAS  Google Scholar 

  44. M.M. Aljumaily, M.A. Alsaadi, R. Das et al., Optimization of the synthesis of superhydrophobic carbon nanomaterials by chemical vapor deposition. Sci. Reports 81(8), 1–12 (2018). https://doi.org/10.1038/s41598-018-21051-3

    Article  CAS  Google Scholar 

  45. S. Subhadarshini, R. Singh, A. Mandal et al., Silver nanodot decorated dendritic copper foam as a hydrophobic and mechano-chemo bactericidal surface. Langmuir 37, 9356–9370 (2021). https://doi.org/10.1021/ACS.LANGMUIR.1C00698/ASSET/IMAGES/LARGE/LA1C00698_0008.JPEG

    Article  CAS  Google Scholar 

  46. D. Zhao, M. Dai, H. Liu et al., Sulfur-induced interface engineering of hybrid NiCo2O4@NiMo2S4 structure for overall water splitting and flexible hybrid energy storage. Adv. Mater. Interfaces 6, 1901308 (2019). https://doi.org/10.1002/ADMI.201901308

    Article  CAS  Google Scholar 

  47. R.B. Pujari, A.C. Lokhande, J.H. Kim, C.D. Lokhande, Bath temperature controlled phase stability of hierarchical nanoflakes CoS2 thin films for supercapacitor application. RSC Adv. 6, 40593–40601 (2016). https://doi.org/10.1039/C6RA06442F

    Article  CAS  Google Scholar 

  48. J. Yu, N. Fu, J. Zhao et al., High specific capacitance electrode material for supercapacitors based on resin-derived nitrogen-doped porous carbons. ACS Omega 4, 15904–15911 (2019). https://doi.org/10.1021/ACSOMEGA.9B01916/ASSET/IMAGES/MEDIUM/AO9B01916_M004.GIF

    Article  CAS  Google Scholar 

  49. W.Q. Chen, J. Wang, K.Y. Ma et al., Hierarchical NiCo2O4@Co-Fe LDH core-shell nanowire arrays for high-performance supercapacitor. Appl. Surf. Sci. 451, 280–288 (2018). https://doi.org/10.1016/J.APSUSC.2018.04.254

    Article  CAS  Google Scholar 

  50. D.P. Dubal, R. Holze, All-solid-state flexible thin film supercapacitor based on Mn3O4 stacked nanosheets with gel electrolyte. Energy 51, 407–412 (2013). https://doi.org/10.1016/J.ENERGY.2012.11.021

    Article  CAS  Google Scholar 

  51. K. Song, X. Wang, J. Wang et al., Bioinspired reduced graphene oxide/polyacrylonitrile-based carbon fibers/CoFe2O4 nanocomposite for flexible supercapacitors with high strength and capacitance. ChemElectroChem 5, 1297–1305 (2018). https://doi.org/10.1002/CELC.201800004

    Article  CAS  Google Scholar 

  52. H.S. Tripathi, A. Dutta, T.P. Sinha, Tailoring structural and electrochemical properties in Sr2+ incorporated nanostructured BiFeO3 for enhanced asymmetric solidstate supercapacitor. Electrochim. Acta 421, 140505 (2022). https://doi.org/10.1016/J.ELECTACTA.2022.140505

    Article  CAS  Google Scholar 

  53. Q. Zhang, Z. Liu, B. Zhao et al., Design and understanding of dendritic mixed-metal hydroxide nanosheets@N-doped carbon nanotube array electrode for high-performance asymmetric supercapacitors. Energy Storage Mater. 16, 632–645 (2019). https://doi.org/10.1016/J.ENSM.2018.06.026

    Article  Google Scholar 

  54. M. Kim, Y.K. Kim, J. Kim et al., Fabrication of a polyaniline/MoS2 nanocomposite using self-stabilized dispersion polymerization for supercapacitors with high energy density. RSC Adv. 6, 27460–27465 (2016). https://doi.org/10.1039/C6RA00797J

    Article  CAS  Google Scholar 

  55. J. Manuel, T. Salguero, R.P. Ramasamy, Synthesis and characterization of polyaniline nanofibers as cathode active material for sodium-ion battery. J. Appl. Electrochem. 49, 529–537 (2019). https://doi.org/10.1007/S10800-019-01298-Y/FIGURES/10

    Article  CAS  Google Scholar 

  56. T. Munawar, M.N. Rehman, ur, Nadeem MS, et al., Facile synthesis of Cr-Co co-doped CdO nanowires for photocatalytic, antimicrobial, and supercapacitor applications. J. Alloys Compd. 885, 160885 (2021). https://doi.org/10.1016/J.JALLCOM.2021.160885

    Article  CAS  Google Scholar 

  57. S. Moopri Singer Pandiyarajan, G.K. Veerasubramani, R.M. Bhattarai et al., Designing an interlayer-widened MoS2-Packed nitrogen-rich carbon nanotube core-shell structure for redox-mediated quasi-solid-state supercapacitors. ACS Appl. Energy Mater. 4, 2218–2230 (2021). https://doi.org/10.1021/ACSAEM.0C02739/ASSET/IMAGES/LARGE/AE0C02739_0009.JPEG

    Article  CAS  Google Scholar 

  58. J.H. Kim, K.H. Lee, L.J. Overzet, G.S. Lee, Synthesis and electrochemical properties of spin-capable carbon nanotube sheet/MnOx composites for high-performance energy storage devices. Nano Lett. 11, 2611–2617 (2011). https://doi.org/10.1021/NL200513A/SUPPL_FILE/NL200513A_SI_001.PDF

    Article  CAS  Google Scholar 

  59. M. Dirican, M. Yanilmaz, A.M. Asiri, X. Zhang, Polyaniline/MnO2/porous carbon nanofiber electrodes for supercapacitors. J. Electroanal. Chem. 861, 113995 (2020). https://doi.org/10.1016/J.JELECHEM.2020.113995

    Article  CAS  Google Scholar 

  60. J.R.I. Jaidev, A.K. Mishra, S. Ramaprabhu, Polyaniline–MnO2 nanotube hybrid nanocomposite as supercapacitor electrode material in acidic electrolyte. J Mater Chem 21, 17601–17605 (2011). https://doi.org/10.1039/C1JM13191E

    Article  CAS  Google Scholar 

  61. F. Meng, X. Yan, Y. Zhu, P. Si, Controllable synthesis of MnO2/polyaniline nanocomposite and its electrochemical capacitive property. Nanoscale Res Lett 8, 1–8 (2013). https://doi.org/10.1186/1556-276X-8-179/FIGURES/6

    Article  Google Scholar 

  62. M.W. Ahmad, S. Anand, A. Fatima et al., Facile synthesis of copper oxide nanoparticles-decorated polyaniline nanofibers with enhanced electrochemical performance as supercapacitor electrode. Polym. Adv. Technol. 32, 4070–4081 (2021). https://doi.org/10.1002/PAT.5414

    Article  CAS  Google Scholar 

  63. S. Rai, R. Bhujel, J. Biswas, B.P. Swain, An eco-friendly method for synthesis of Cu2O/rGO/PANI composite using citrus maxima juice for supercapacitor application. J. Mater. Sci. Mater. Electron. 32, 27937–27949 (2021). https://doi.org/10.1007/S10854-021-07175-9/TABLES/2

    Article  CAS  Google Scholar 

  64. S. Palsaniya, H.B. Nemade, A.K. Dasmahapatra, Hierarchical PANI-RGO-ZnO ternary nanocomposites for symmetric tandem supercapacitor. J. Phys. Chem. Solids 154, 110081 (2021). https://doi.org/10.1016/J.JPCS.2021.110081

    Article  CAS  Google Scholar 

  65. B. Purty, R.B. Choudhary, R. Kandulna, R. Singh, Remarkable enhancement in electrochemical capacitance value of Ag-ZnO/PANI composite for supercapacitor application. AIP Conf. Proc. 2115, 030588 (2019). https://doi.org/10.1063/1.5113427

    Article  CAS  Google Scholar 

  66. R. Karthik, S. Thambidurai, Synthesis of RGO–Co doped ZnO/PANI hybrid composite for supercapacitor application. J. Mate. Sci. Mater. Electron. 28, 9836–9851 (2017). https://doi.org/10.1007/S10854-017-6738-4/FIGURES/10

    Article  CAS  Google Scholar 

  67. B P P, D N A, M S R, Kumar K Y, Synthesis of polyaniline/α-Fe2O3 nanocomposite electrode material for supercapacitor applications. Mater. Today Commun. 12, 72–78 (2017). https://doi.org/10.1016/J.MTCOMM.2017.07.002

    Article  Google Scholar 

  68. Z. Qiu, Y. Peng, D. He et al., Ternary Fe3O4@C@PANi nanocomposites as high-performance supercapacitor electrode materials. J. Mater. Sci. 53, 12322–12333 (2018). https://doi.org/10.1007/S10853-018-2451-9/FIGURES/7

    Article  CAS  Google Scholar 

  69. X. Liu, J. Wang, G. Yang, In situ growth of the Ni3V2O8@PANI composite electrode for flexible and transparent symmetric supercapacitors. ACS Appl. Mater. Interfaces 10, 20688–20695 (2018). https://doi.org/10.1021/ACSAMI.8B04609/ASSET/IMAGES/LARGE/AM-2018-04609R_0006.JPEG

    Article  CAS  Google Scholar 

  70. Naveed ur Rehman M, Munawar T, Nadeem MS, et al., Facile synthesis and characterization of conducting polymer-metal oxide based core-shell PANI-Pr2O–NiO–Co3O4 nanocomposite: as electrode material for supercapacitor. Ceram. Int. 47, 18497–18509 (2021). https://doi.org/10.1016/J.CERAMINT.2021.03.173

    Article  Google Scholar 

  71. S. Phokha, S. Hunpratub, N. Chanlek et al., Synthesis, characterization and electrochemical performance of carbon/Ni-doped CeO2 composites. J. Alloys Compd. 750, 788–797 (2018). https://doi.org/10.1016/J.JALLCOM.2018.04.053

    Article  CAS  Google Scholar 

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Acknowledgements

The authors are very thankful to Bahauddin Zakariya University, Multan, for financial support under project number DR & EL/D-545. The authors would like to acknowledge the financial support of Taif University Researchers Supporting Project number (TURSP-2020/189), Taif University, Taif, Saudi Arabia.

Funding

This study was funded by Bahauddin Zakariya University,R&D545, Muhammad Naeem Ashiq, Taif University, TURSP-2020/189, K. H. Mahmoud.

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Authors and Affiliations

  1. Institute of Chemical Sciences, Bahauddin Zakariya University, Multan, 60800, Pakistan

    Sajid Abbas, Sumaira Manzoor, Abdul Ghafoor Abid, Ghazala Yasmeen, Suryyia Manzoor & Muhammad Naeem Ashiq

  2. Department of Chemistry, Government College University, Lahore, Pakistan

    Muhammad Abdullah

  3. Department of Physics, College of Khurma University College, Taif University, Taif, Saudi Arabia

    K. H. Mahmoud & A. SA. Alsubaie

  4. State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy and Power Engineering, Xian Jiaotong University, Xjtu, People’s Republic of China

    Muhammad Shuaib Khan

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Abbas, S., Manzoor, S., Abdullah, M. et al. One-pot synthesis of reduced graphene oxide-based PANI/MnO2 ternary nanostructure for high-efficiency supercapacitor applications. J Mater Sci: Mater Electron 33, 25355–25370 (2022). https://doi.org/10.1007/s10854-022-09242-1

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