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Enhanced dielectric properties of PVA/PEDOT:PSS/MnO2 based composites for electronic applications

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Abstract

Polymer composite (PC) films comprising polyvinyl alcohol (PVA) and poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) with manganese dioxide (MnO2) as filler were prepared by simple solution casting method. The structural confirmation of PCs was investigated by Fourier transform Infrared Spectroscopy (FTIR) and X-ray diffraction (XRD) techniques. The morphological and thermal properties were analyzed using scanning electron microscope (SEM) and thermogravimetric analysis (TGA). Under the frequency range, 50 Hz to 20 MHz, and temperature from 40 to 150 °C, the dielectric properties and Q-factor values for the as-synthesized PC films were investigated by an impedance analyzer. PVA/PEDOT:PSS/MnO2 having wt% 50:35:15 revealed high dielectric constant (ε) at 1949 and low dielectric loss(tanδ) at 8.13. The obtained results suggest that the titled PC films are effective materials for energy storage applications.

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References

  1. J.G. Mallete, A. Márquez, O. Manero, R. Castro-Rodrigues, Pol. Eng. Sci. 40, 2272–2278 (2000)

    Article  Google Scholar 

  2. D.I. Tishkevich, S. Grabchikov, S. Lastovskii, S. Trukhanov, T. Zubar, D. Vasin, A.V. Trukhanov, ACS Appl. Energy Mater. 1, 1695–1702 (2018)

    Article  CAS  Google Scholar 

  3. D.I. Tishkevich, S.S. Gracchikov, L.S. Tsybulskaya, V.S. Shendyukov, S.S. Perevoznikov, S.V. Trukhanov, E.L. Trukhanov, J. Alloys Compd. 735, 1943–1948 (2018)

    Article  CAS  Google Scholar 

  4. D.I. Tishkevich, A.I. Vorobjova, D. Vinnik, Solid State Phenom. 299, 100–106 (2020)

    Article  Google Scholar 

  5. Y. Slimani, N.A. Algarou, M.A. Almessiere, A. Sadaqat, M.G. Vakhitov, D.S. Klygach, D.I. Tishkevich, A.V. Trukhanov, S. Guner, A.S. Hakeem, I.A. Auwal, A. Baykal, A. Manikandan, I. Ercan, Arab. J. Chem. 14, 102992 (2021)

    Article  CAS  Google Scholar 

  6. A.V. Trukhanov, D.I. Tishkevich, S.V. Podgornaya, E. Kaniukov, M.A. Darwish, T.I. Zubar, A.V. Timofeev, E.L. Trukhanova, V.G. Koshishin, S.V. Trukhanov, Nanomaterials 12, 868 (2022)

    Article  CAS  Google Scholar 

  7. E.M. ShehaMona, M. NasrMabrouk, K.E. Mansy, J. Adv. Res. 6, 563–569 (2015)

    Article  Google Scholar 

  8. A. Bouzidi, W. Jilani, I.S. Yahia, H.Y. Zahran, M.A. Assiri, J. Inorg. Organomet. Poly Mat. 30, 3940–3952 (2020)

    Article  CAS  Google Scholar 

  9. R. Ambrosio, A. Carrillo, M.L. Mota, K. Torre, R. Torrealba, M. Moreno, H. Vazquez, J. Flores, I. Vivaldo, Polymer 10, 1370 (2018)

    Article  Google Scholar 

  10. F.E. Sayed, M.I. Mohammed, I.S. Yahia, J. Mater. Sci. 31, 10408–10421 (2020)

    Google Scholar 

  11. S. Mallakpour, M. Lormahdiabadi, J. Polym. Res. 27, 259 (2020)

    Article  CAS  Google Scholar 

  12. P. Rani, M.B. Ahamed, K. Deshmukh, J. Appl. Polym. Sci. 137, 49392 (2020)

    Article  CAS  Google Scholar 

  13. H.N. Fard, G.B. Pour, M.N. Sarvi, P. Esmaili, Ionics 25, 2951–2963 (2019)

    Article  CAS  Google Scholar 

  14. K. Deshmukh, M.B. Ahamed, R.R. Deshmukh, S.K.K. Pasha, K.K. Sadasivuni, D. Ponnamma, K. Chidambaram, Euro Polym. J. 76, 14–27 (2016)

    Article  CAS  Google Scholar 

  15. K. Deshmukh, M.B. Ahamed, K.K. Sadasivuni, D. Ponnamma, M.A.A. AlMaadeed, S.K.K. Pasha, R.R. Deshmukh, K. Chidambaram, Mater. Chem. Phys. 186, 188–201 (2017)

    Article  CAS  Google Scholar 

  16. K. Deshmukh, M.B. Ahamed, A.R. Polu, K.K. Sadasivuni, S.K.K. Pasha, D. Ponnamma, M.A.A. Al-Maadeed, R.R. Deshmukh, K. Chidambaram, J. Mater. Sci. 27, 11410–11424 (2016)

    CAS  Google Scholar 

  17. T. Zhang, K. Li, C. Li, S. Ma, H.H. Hng, L. Wei, Adv. Elect. Mater. 3, 1600554 (2017)

    Article  Google Scholar 

  18. A. Yamasaki, T. Shinbo, K. Mizoguchi, J. Appl. Poly. 64, 1061–1065 (1997)

    Article  CAS  Google Scholar 

  19. B. Karthikeyan, Physica B 364, 328–332 (2005)

    Article  CAS  Google Scholar 

  20. K. Deshmukh, S. Sankaran, M.B. Ahamed, S.K.K. Pasha, K.K. Sadasivuni, D. Ponnamma, M.A.A. AlMaadeed, K. Chidambaram, Int. J. Nanosci. 16, 1760005 (2017)

    Google Scholar 

  21. F. Hamidouche, M.M.S. Sanad, Z. Ghebache, N. Boudieb, J. Mol. Struct. 1251, 131964 (2022)

    Article  CAS  Google Scholar 

  22. F. Hamidouche, Z. Ghebache, N. Boudieb, M. Sanad, N.E. Djelali, J. Inorg. Organometall. Polym. Mater. 31, 704–715 (2021)

    Article  CAS  Google Scholar 

  23. C.I. Idumah, Syn. Met. 273, 116674 (2021)

    Article  CAS  Google Scholar 

  24. J.H. Oh, G.W. George, A.D. Martinez, L.C. Moores, M.J. Green, Polymer 230, 124077 (2021)

    Article  CAS  Google Scholar 

  25. P. Li, K. Sun, J. Ouyang, ACS Appl. Mater. Interfaces 7, 18415–18423 (2015)

    Article  CAS  Google Scholar 

  26. C. Chen, A. Kine, R.D. Nelson, J.C. LaRue, Synth. Met. 206, 106–114 (2015)

    Article  CAS  Google Scholar 

  27. B. Baruah, A. Kumar, Synth. Met 245, 74–86 (2018)

    Article  CAS  Google Scholar 

  28. W. Yao, L. Li, Z. Bai, Y. Jiang, L. Xu, J. Yan, Y. Wan, R. Tan, H. Liu, P. Liu, Int. J. Electrochem. Sci. 15, 9135–9145 (2020)

    Article  Google Scholar 

  29. S. Park, C.W. Lee, J.M. Kim, Org. Electron. 58, 1–5 (2018)

    Article  CAS  Google Scholar 

  30. J. Ouyang, Smart Mater. 2, 263–281 (2021)

    Google Scholar 

  31. O. Carr, G. Gozzi, L.F. Santos, R.M. Faria, D.L. Chinaglia, Transl. Mater. Res. 2, 015002 (2015)

    Article  Google Scholar 

  32. Y. Wang, Y. Ding, X. Guo, G. Yu, Nano Res 12, 1978–1987 (2019)

    Article  CAS  Google Scholar 

  33. M. Moharam, M.M.S. Sanad, E.M.E. Sayed, M.E. Ibrahim, IOP Conf. Ser. Mater. Sci. Eng. 762, 012002 (2020)

    Article  CAS  Google Scholar 

  34. Y. Wang, Y.Z. Zhang, Y.Q. Gao, G. Sheng, J.E. Elshof, Nano Energy 68, 104306 (2020)

    Article  CAS  Google Scholar 

  35. H.E. Wang, D. Qian, Mater. Chem. Phys. 109, 399–403 (2008)

    Article  CAS  Google Scholar 

  36. M. Sanad, A. Toghan, Appl. Phys. 127, 1–15 (2021)

    Article  Google Scholar 

  37. K. Dai, L. Lu, C. Liang, J. Dai, Q. Liu, Y. Zhang, G. Zhu, Z. Liu, Electrochim Acta 116, 111–117 (2014)

    Article  CAS  Google Scholar 

  38. M. Jayashree, M. Parthibavarman, R. Boopathiraja, S. Prabhu, R. Ramesh, J. Mater. Sci. 31, 6910–6918 (2020)

    CAS  Google Scholar 

  39. M.M.S. Sanad, A.K. Yousef, M.M. Rashad, A.H. Naggar, A.Y.E. Sayed, Physica B 579, 411889 (2020)

    Article  CAS  Google Scholar 

  40. S. Pradhan, D. Goswami, D. Ganguly, S.K. Ghorai, D. Ratna, S. Chattopadhyay, Polym. Test 90, 106716 (2020)

    Article  CAS  Google Scholar 

  41. R. Yuksel, H.E. Unalan, Int. J. Energy Res. 39, 2042–2052 (2015)

    Article  CAS  Google Scholar 

  42. R. Ranjusha, K.M. Sajesh, S. Roshny, V. Lakshmi, P. Anjali, T.S. Sonia, A.S. Nair, K.R.V. Subramanian, S.V. Nair, K.P. Chennazhi, A. Balakrishnan, Microporous Mesoporous Mater. 186, 30–36 (2014)

    Article  CAS  Google Scholar 

  43. M.K. Mohanapriya, K. Deshmukh, M.B. Ahamed, K. Chidambaram, S.K.K. Pasha, Mater. Today 3, 1864–1873 (2016)

    Google Scholar 

  44. M.K. Mohanapriya, K. Deshmukh, K. Chidambaram, M.B. Ahamed, K.K. Sadasivuni, D. Ponnamma, M.A.A. AlMaadeed, R.R. Deshmukh, S.K. Khadheer Pasha, J. Mater. Sci. 28, 6099–6111 (2017)

    CAS  Google Scholar 

  45. P. Rani, M.B. Ahamed, K. Deshmukh, J. Mater. Sci. 32, 764–779 (2021)

    CAS  Google Scholar 

  46. K. Deshmukh, M.B. Ahamed, K.K. Sadasivuni, D. Ponnamma, R.R. Deshmukh, S.K.K. Pasha, M.A.A. AlMaadeed, K. Chidambaram, J. Polym. Res. 23, 159 (2016)

    Article  Google Scholar 

  47. Y.F. Zhang, M.M. Guo, Y. Zhang, C.Y. Tang, C. Jiang, Y. Dong, W.C. Law, F.P. Du, Polym. Test 81, 106213 (2020)

    Article  CAS  Google Scholar 

  48. J. Yu, W. Gu, H. Zhao, G. Ji, Sci. China Mater. 64, 1723–1732 (2021)

    Article  CAS  Google Scholar 

  49. S. Palsaniya, H.B. Nemade, A.K. Dasmahapatra, Carbon 150, 179–190 (2019)

    Article  CAS  Google Scholar 

  50. S. Mallakpour, F. Motirasoul, Ultrasonography 40, 410–418 (2018)

    CAS  Google Scholar 

  51. X. Li, C. Zhou, L. Shen, W. Zhou, J. Xu, C. Luo, J. Hou, R. Tan, F. Jiang, Int. J. Electrochem. Sci. 14, 4632–4642 (2019)

    Article  CAS  Google Scholar 

  52. Y. Chen, J. Xu, Y. Yang, Y. Zhao, W. Yang, X. Mao, M. Xin, S. Li, Electrochim Acta 193, 199–205 (2016)

    Article  CAS  Google Scholar 

  53. P. Komalavalli, I. B. S. Banu, M. H. Mamat, M. S. Anwar, S. Hussain, S. S. Basha, R. Rajesh, 2022, 5, 529–536

  54. A. Monshi, M.R. Foroughi, M.R. Monshi, World J. Nano Sci. Eng. 2, 154–160 (2012)

    Article  Google Scholar 

  55. M.M.S. Sanad, M.M. Rashad, E.A.A. Aal, M.F.E. Shahat, Ceram. Int. 39, 1547–1554 (2013)

    Article  CAS  Google Scholar 

  56. D.I. Tishkevich, T.I. Zubar, A.L. Zhaludkevich, I.U. Razanau, T.N. Vershinina, A.A. Bondaruk, E.K. Zheleznova, M. Dong, M.Y. Hanfi, M.I. Sayyed, M.V. Silibin, S.V. Trukhanov, A.V. Trukhanov, Nanomaterials 12, 1642 (2022)

    Article  CAS  Google Scholar 

  57. G. Ma, D. Yang, D. Su, X. Mu, J.F. Kennedy, J. Nie, Polym. Adv. Technol. 21, 189–195 (2010)

    Article  CAS  Google Scholar 

  58. K. Deshmukh, M.B. Ahamed, R.R. Deshmukh, P.R. Bhagat, S.K.K. Pasha, A. Bhagat, R. Shirbhate, F. Telare, C. Lakhani, Polym. Plas Techol. Eng. 55, 231–241 (2016)

    Article  CAS  Google Scholar 

  59. S.J. Lue, J.Y. Chen, J.M. Yeng, J. Macromol. Sci. B 47, 39–51 (2007)

    Article  Google Scholar 

  60. V. Hebbar, R.F. Bhajantri, H.B. Ravikumar, S. Ningaraju, J. Phys. Chem. Solids 126, 242–256 (2019)

    Article  CAS  Google Scholar 

  61. H. Du, Z. Song, J. Wang, Z. Liang, Y. Shen, F. You, Sens. Actuators A 228, 1–8 (2015)

    Article  CAS  Google Scholar 

  62. D.A. Nasrallah, M.A. Ibrahim, J. Polym. Res. 29, 1–20 (2022)

    Article  Google Scholar 

  63. D. Singh, N.L. Singh, P. Kulriya, A. Tripathi, D.M. Phase, J. Compos. Mater. 44, 3165–3178 (2010)

    Article  CAS  Google Scholar 

  64. T. Anjitha, T. Anilkumar, G. Mathew, M.T. Ramesan, Polym. Compos. 40, 2802–2811 (2019)

    Article  CAS  Google Scholar 

  65. A. Gupta, V. Choudhary, Compos. Sci. Technol. 71, 1563–1568 (2011)

    Article  CAS  Google Scholar 

  66. G.S. Wang, L.Z. Nie, S.H. Yu, RSC Adv. 2, 6216–6221 (2012)

    Article  CAS  Google Scholar 

  67. V. Mydhili, S. Manivannan, Polym. Bull. 76, 4735–4752 (2019)

    Article  CAS  Google Scholar 

  68. S. More, R. Dhokne, S. Moharil, Polym. Bull. 75, 909–923 (2018)

    Article  CAS  Google Scholar 

  69. A.S. Roy, S. Gupta, S. Sindhu, A. Parveen, P.C. Ramamurthy, Composites B 47, 314–319 (2013)

    Article  CAS  Google Scholar 

  70. S. Sugumaran, C.S. Bellan, Optik 125, 5128–5133 (2014)

    Article  CAS  Google Scholar 

  71. V. Siva, D. Vanitha, A. Murugan, A. Shameem, S.A. Bahadur, Compos. Commun. 23, 100567 (2021)

    Article  Google Scholar 

  72. A.H. Majeed, E.T.B.A. Tikrity, D.H. Hussain, Polym. Polym. Compos. 29, 1089–1100 (2021)

    CAS  Google Scholar 

  73. S.B. Basturk, C.E.J. Dancer, T. McNally, J. Appl. Polym. Sci. 138, 50521 (2021)

    Article  CAS  Google Scholar 

  74. A.S. Zeraati, S.A. Mirkhani, U. Sundararaj, J. Phys. Chem. 121, 8327–8334 (2017)

    Google Scholar 

  75. A. Hashim, M.A. Habeeb, Q.M. Jebur, Egypt J. Chem. 62, 735–749 (2019)

    Google Scholar 

  76. M. Vikulova, A. Tsyganov, A. Bainyashev, D. Artyukhov, A. Gorokhovsky, D. Muratov, N. Gorshkov, J. Appl. Polym. Sci. 138, 51168 (2021)

    Article  CAS  Google Scholar 

  77. M.M.S. Sanad, M.M. Rashad, E.A.A. Aal, K. Powers, Mater. Chem. Phys. 162, 299–307 (2015)

    Article  CAS  Google Scholar 

  78. M.M.S. Sanad, M.M. Rashad, E.A.A. Aal, M.F.E. Shahat, J Euro Ceram. Soc. 32, 4249–4255 (2012)

    Article  CAS  Google Scholar 

  79. M.M.S. Sanad, M.M. Rashad, E.A.A. Aal, M.F.E. Shahat, K. Powers, J. Mater. Sci. 25, 2487–2493 (2014)

    CAS  Google Scholar 

  80. K.D. Satapathy, K. Deshmukh, M.B. Ahamed, K.K. Sadasivuni, D. Ponnamma, S.K.K. Pasha, M.A.A. Al-Maadeed, J. Ahmed, Adv. Mater. Lett. 8(3), 288–294 (2017)

    Article  CAS  Google Scholar 

  81. K. Deshmukh, M.B. Ahamed, S. Sankaran, S.K.K. Pasha, K.K. Sadasivuni, D. Ponnamma, M.A.A. Al-Maadeed, Mater. Today 5, 8744–8752 (2018)

    CAS  Google Scholar 

  82. M.K. Mohanapriya, K. Deshmukh, K.K. Sadasivuni, G. Thangamani, K. Chidambaram, M.B. Ahamed, S.K.K. Pasha, Mater. Today 9, 199–216 (2019)

    CAS  Google Scholar 

  83. A. Pasha, A.S. Roy, M.V. Murugendrappa, O.A.A. Hartomy, S. Khasim, J. Mater. Sci. 27, 8332–8339 (2016)

    CAS  Google Scholar 

  84. G.M. Joshi, M.T. Cuberes, Ionics 19, 947–950 (2013)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, B. S. Abdur Rahman Crescent Institute of Science and Technology, Vandalur, Chennai, 600048, India

    J. Gokul Raja & M. Basheer Ahamed

  2. Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark, NJ, 07102, USA

    Chaudhery Mustansar Hussain

  3. Department of Physical Sciences, Saveetha University, Chennai, 602105, India

    Paavai Era

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The corresponding author confirms that the authors mentioned in this paper have equally contributed to bringing out this work and also in the preparation of this manuscript.

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Raja, J.G., Ahamed, M.B., Hussain, C.M. et al. Enhanced dielectric properties of PVA/PEDOT:PSS/MnO2 based composites for electronic applications. J Mater Sci: Mater Electron 33, 22883–22898 (2022). https://doi.org/10.1007/s10854-022-09058-z

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