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Homogeneous nanocube (Fe, Ni) S2 electrode material from Fe–Ni PBA for high-performance hybrid supercapacitors

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Abstract

Prussian blue analogs (PBAs) are multifunctional precursors for the synthesis of a series of transition metal nanomaterials. In this study, high-performance supercapacitor hybrid electrode materials [(Fe, Ni) S2] are obtained by a facile hydrothermal sulfidation method, where the Fe–Ni PBA is introduced as the precursor. The nanocube structure which is similar to the Fe–Ni PBA precursor is remained and delivers the structure with a large number of cracks, resulting in a larger specific surface area and good conductivity. The (Fe, Ni) S2 electrode material possesses a high specific capacitance of 1249.1 F g−1 at the current density of 1 A g−1, good rate capability (915.31 F g−1 at 20 A g−1), and the excellent cyclic stability (retention rate of 91.6%) after 5000 cycles. The two-electrode system condition test shows that the energy density of ASD reached 39.97 Wh kg−1 when the power density is 0.85 kW kg−1 including the material is a potential supercapacitor electrode material.

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Acknowledgements

The authors gratefully acknowledge the support of the Basic Research Program of Education Committee of Chongqing Province, China (No. KJQN201903205) and the National Natural Science Foundation of China (Grant No. 21676034).

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Authors and Affiliations

  1. College of Chemistry & Chemical Engineering, Chongqing University, Chongqing, 400044, People’s Republic of China

    Tingting Li, Shenna Fu, Li Ma, Yanling Yang, Taichun Wu, Shuang Wei, Qinglan Fu, Fei Xie & Wang Zhan

  2. Chemical Pollution Control Chongqing Applied Technology Extension Center of Higher Vocational Colleges, Chongqing Industry Polytechnic College, Chongqing, 401120, People’s Republic of China

    Shenna Fu

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  1. Tingting Li
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Contributions

TL contributed to conceptualization, methodology, validation, investigation, software, writing of the original draft, writing, reviewing, and editing of the manuscript, and visualization. SF contributed to writing, reviewing, and editing of the manuscript, software, formal analysis, funding acquisition, and visualization. LM contributed to resources collection, supervision, funding acquisition, validation, investigation, formal analysis, and writing, reviewing, and editing of the manuscript. YY contributed to resources collection, supervision, project administration, funding acquisition, and validation. TW contributed to resources collection, investigation, and writing, reviewing, and editing of the manuscript. SW contributed to resources collection, investigation, and writing, reviewing, and editing of the manuscript. QF contributed to resources collection, investigation, and writing, reviewing, and editing of the manuscript. FX: contributed to resources collection and funding acquisition. WZ contributed to resources collection.

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Correspondence to Shenna Fu or Li Ma.

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Ethics Committee approval was obtained from the Institutional Ethics Committee of Chongqing University to the commencement of the study.

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Li, T., Fu, S., Ma, L. et al. Homogeneous nanocube (Fe, Ni) S2 electrode material from Fe–Ni PBA for high-performance hybrid supercapacitors. J Mater Sci: Mater Electron 33, 22319–22331 (2022). https://doi.org/10.1007/s10854-022-09011-0

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