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Effect of nano CdS/Mg on linear and nonlinear optical characteristic of PVA/PVP/PEG film

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Abstract

Pure and loaded 80%PVA/10%PVP/10%PEG-blended polymers with different ratios of nanoCdS/Mg (prepared in air and nitrogen environments) were prepared using thermolysis and casting procedures. Rietveld refinement was used to investigate the ratios between the hexagonal wurtzite and cubic zinc-blende phases in nanoCdS/Mg prepared under different conditions. The effect of preparation environment on the lattice parameter, crystallite size, and microstrain of the nanofiller was also explored. X-ray diffraction confirmed the incorporation of the nanofiller in the blended polymer matrix. The influence of the nanofiller on the linear and nonlinear optical parameters of the blended polymers was investigated using the diffused reflectance spectroscopy technique. The optical band gap of pure blended polymer was reduced from 5.32 eV to 4.48 eV and 4.16 eV as the blend filled with 10% CdS/Mg (air) and 5% CdS/Mg (N2), respectively. The refractive indices of pure and filled blends with nanofillers exhibited normal and anomalous dispersions depended on the measured wavelength range. The nonlinear optical parameters were improved as the blends filled with CdS/Mg (N2 or air). All pure and filled blends emitted two violet and two blue colors, regardless the amount and the conditions of the preparation of the nanofiller.

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Acknowledgements

The authors are grateful to the Deanship of Scientific Research, King Saud University for funding through Vice Deanship of Scientific Research Chairs.

Funding

This funding was provided by King Saud University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Research Chair of Exploitation of Renewable Energy Applications in Saudi Arabia, Physics & Astronomy Department, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia

    A. M. El-naggar

  2. Physics Department, Faculty of Science, Ain Shams University, Cairo, Egypt

    Zein K. Heiba & Mohamed Bakr Mohamed

  3. Physics & Astronomy Department, College of Science, King Saud University, 11451, Riyadh, Saudi Arabia

    A. M. Kamal

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  1. A. M. El-naggar
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  2. Zein K. Heiba
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  3. Mohamed Bakr Mohamed
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  4. A. M. Kamal
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All authors have contributed, discussed the results, and approved the final manuscript.

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Correspondence to Mohamed Bakr Mohamed.

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El-naggar, A.M., Heiba, Z.K., Mohamed, M.B. et al. Effect of nano CdS/Mg on linear and nonlinear optical characteristic of PVA/PVP/PEG film. J Mater Sci: Mater Electron 33, 17235–17248 (2022). https://doi.org/10.1007/s10854-022-08600-3

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  • DOI: https://doi.org/10.1007/s10854-022-08600-3

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