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Ionic liquid-based quasi-solid-state electrolyte for supercapacitor application

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Abstract

Quasi-solid-state electrolytes (QSSEs) via incorporating low-viscous ionic liquid (IL) into a copolymer matrix were fabricated for electric double-layer capacitors (EDLCs). It is found the IL amount brings about notable effects on the structure, physicochemical properties of the QSSE and electrochemical performance of the EDLC. The QSSE based on optimized polymer/IL mass ratio exhibits acceptable ionic conductivity, favorable thermal/structural stability and wide operation potential window. Consequently, the constructed EDLC yields a high gravimetric specific energy, rapid and reversible charge/discharge capability and outstanding capacitance retention over long-term cycling at the cut-off voltage of 3.0 V.

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The data generated and/or analysed during the current study are available from the corresponding author on reasonable request.

References

  1. H. Liu, H. Du, W. Zhao, X. Qiang, B. Zheng, Y. Li, B. Cao, Energy Storage Mater. 40, 490 (2021)

    Article  Google Scholar 

  2. S. Luo, H. Guo, S. Zhang, Z. Wang, X. Li, W. Peng, J. Wang, G. Yan, J. Clean. Prod. 326, 129266 (2021)

    Article  CAS  Google Scholar 

  3. Y. Yuan, Z. Li, X. Peng, K. Xue, M. Liu, Z. Fang, L. Wang, H. Du, H. Lu, Electrochim. Acta 410, 140052 (2022)

    Article  CAS  Google Scholar 

  4. J. Shi, R. Rao, W. Tian, X. Xu, X. Liu, Ceram. Int. 48, 5210 (2022)

    Article  CAS  Google Scholar 

  5. J. He, X. Liu, Y. Zhao, H. Du, T. Zhang, J. Shi, ACS Appl. Electron. Mater. 4, 735 (2022)

    Article  CAS  Google Scholar 

  6. H. Lu, F. Zeng, L. He, R. Feng, Y. Yuan, Z. Zhang, H. Liu, H. Du, B. Zheng, Electrochim. Acta 421, 140472 (2022)

    Article  CAS  Google Scholar 

  7. F. Wang, X. Wu, X. Yuan, Z. Liu, Y. Zhang, L. Fu, Y. Zhu, Q. Zhou, Y. Wu, W. Huang, Chem. Soc. Rev. 46, 6816 (2017)

    Article  CAS  Google Scholar 

  8. X. Zang, C. Shen, M. Sanghadasa, L. Lin, ChemElectroChem 6, 976 (2019)

    Article  CAS  Google Scholar 

  9. W. Raza, F. Ali, N. Raza, Y. Luo, K. Kim, J. Yang, S. Kumar, A. Mehmood, E. Kwon, Nano Energy 52, 441 (2018)

    Article  CAS  Google Scholar 

  10. A. Eftekhari, Energy Storage Mater. 9, 47 (2017)

    Article  Google Scholar 

  11. H. Su, H. Zhang, F. Liu, F. Chun, B. Zhang, X. Chu, H. Huang, W. Deng, B. Gu, H. Zhang, X. Zheng, M. Zhu, W. Yang, Chem. Eng. J. 322, 73 (2017)

    Article  CAS  Google Scholar 

  12. J. Tian, C. Cui, Q. Xie, W. Qian, C. Xue, Y. Miao, Y. Jin, G. Zhang, B. Guo, J. Mater. Chem. A 6, 3593 (2018)

    Article  CAS  Google Scholar 

  13. Z. Song, D. Zhu, L. Li, T. Chen, H. Duan, Z. Wang, Y. Lv, W. Xiong, M. Liu, L. Gan, J. Mater. Chem. A 7, 1177 (2019)

    Article  CAS  Google Scholar 

  14. D. Kang, K. Kim, S. Karade, H. Kim, J. Kim, J. Mater. Chem. A 384, 123308 (2020)

    CAS  Google Scholar 

  15. Z. Pan, J. Yang, Q. Zhang, M. Liu, Y. Hu, Z. Kou, N. Liu, X. Yang, X. Ding, H. Chen, J. Li, K. Zhang, Y. Qiu, Q. Li, J. Wang, Y. Zhang, Adv. Energy Mater. 9, 1802753 (2019)

    Article  CAS  Google Scholar 

  16. A. Sumboja, J. Liu, W. Zheng, Y. Zong, H. Zhang, Z. Liu, Chem. Soc. Rev. 47, 5919 (2018)

    Article  CAS  Google Scholar 

  17. D. Dubal, N. Chodankar, D. Kim, P. Gomez-Romero, Chem. Soc. Rev. 47, 2065 (2018)

    Article  CAS  Google Scholar 

  18. P. Pal, A. Ghosh, J. Power Sources 406, 128 (2018)

    Article  CAS  Google Scholar 

  19. Z. Wang, M. Zhu, Z. Pei, Q. Xue, H. Li, Y. Huang, C. Zhi, Mater. Sci. Eng. R 139, 100520 (2020)

    Article  Google Scholar 

  20. W. Liu, C. Yi, L. Li, S. Liu, Q. Gui, D. Ba, Y. Li, D. Peng, J. Liu, Angew Chem. Int. Ed. 60, 12931 (2021)

    Article  CAS  Google Scholar 

  21. M. Liu, D. Zhou, Y. He, Y. Fu, X. Qin, C. Miao, H. Du, B. Li, Q. Yang, Z. Lin, T. Zhao, F. Kang, Nano Energy 22, 278 (2016)

    Article  CAS  Google Scholar 

  22. R. Muchakayala, S. Song, J. Wang, Y. Fan, M. Bengeppagari, J. Chen, M. Tan, J. Ind. Eng. Chem. 59, 79 (2018)

    Article  CAS  Google Scholar 

  23. L. Dagousset, G. Pognon, G. Nguyen, F. Vidal, S. Jus, P. Aubert, J. Power Sources 391, 86 (2018)

    Article  CAS  Google Scholar 

  24. V. Chaudoy, F. Tran Van, M. Deschamps, F. Ghamouss, J. Power Sources 342, 872 (2017)

    Article  CAS  Google Scholar 

  25. T. Bandara, A. Weerasinghe, M. Dissanayake, G. Senadeera, M. Furlani, I. Albinsson, B. Mellander, Electrochim. Acta 266, 276 (2018)

    Article  CAS  Google Scholar 

  26. M.M. Noor, M.A. Careem, S.R. Majid, A.K. Arof, Mater. Res. Innov. 15, s157 (2011)

    Article  Google Scholar 

  27. X. Li, H. Li, R. Feng, L. He, H. Lu, Front. Mater. 8, 633460 (2021)

    Article  Google Scholar 

  28. Z. Song, H. Duan, L. Miao, L. Ruhlmann, Y. Lv, W. Xiong, D. Zhu, L. Li, L. Gan, M. Liu, Carbon 168, 499 (2020)

    Article  CAS  Google Scholar 

  29. P. Pal, A. Ghosh, Electrochim. Acta 278, 137 (2018)

    Article  CAS  Google Scholar 

  30. M. Tripathi, S.K. Tripathi, Ionics 23, 2735 (2017)

    Article  CAS  Google Scholar 

  31. M. Tripathi, S.M. Bobade, M. Gupta, Y. Kumar, Macromol. Symp. 388, 1900029 (2019)

    Article  CAS  Google Scholar 

  32. G.A. Tiruye, D. Muñoz-Torrero, J. Palma, M. Anderson, R. Marcilla, J. Power Sources 326, 560 (2016)

    Article  CAS  Google Scholar 

  33. W. Lu, K. Henry, C. Turchi, J. Pellegrino, J. Electrochem. Soc. 155, A361 (2008)

    Article  CAS  Google Scholar 

  34. G.P. Pandey, S.A. Hashmi, Y. Kumar, Energy Fuels 24, 6644 (2010)

    Article  CAS  Google Scholar 

  35. Y. Kumar, G.P. Pandey, S.A. Hashmi, J. Phys. Chem. C 116, 26118 (2012)

    Article  CAS  Google Scholar 

  36. H. Lu, L. He, X. Li, W. Zhang, J. Che, X. Liu, Z. Hou, H. Du, Y. Qu, J. Mater. Sci. Mater. Electron. 30, 13933 (2019)

    Article  CAS  Google Scholar 

  37. H. Wang, L. Zhi, K. Liu, L. Dang, Z. Liu, Z. Lei, C. Yu, J. Qiu, Adv. Funct. Mater. 25, 5420 (2015)

    Article  CAS  Google Scholar 

  38. L. Zhi, T. Li, H. Yu, S. Chen, L. Dang, H. Xu, F. Shi, Z. Liu, Z. Lei, Carbon 113, 100 (2017)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 51604221 and 51704222), and the Key Project of Natural Science Basic Research Plan of Shaanxi Province (No. 2022JZ-25).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Xi’an University of Science and Technology, Xi’an, 710054, China

    Hai Lu, Rui Feng, Peichun Wang, Zhiyun Zhang & Huiling Du

  2. School of Metallurgical Engineering, Xi’an University of Architecture and Technology, Xi’an, 710055, China

    Yan Yuan

  3. Xi’an Herong New Energy Technology Co., Ltd, Xi’an, 710200, China

    Xiangyuan Li

Authors
  1. Hai Lu
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  2. Rui Feng
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  3. Peichun Wang
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  4. Yan Yuan
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  5. Zhiyun Zhang
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  6. Huiling Du
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  7. Xiangyuan Li
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Contributions

HL—Conception and design of study, revision of the manuscript and funding acquisition. RF—investigation, acquisition of data and drafting the manuscript. PW—participated in investigation. YY—data discussion and funding acquisition. ZZ—conceptualization and methodology. HD—funding acquisition and supervision. XL—participated in data analysis and/or interpretation.

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Correspondence to Hai Lu or Yan Yuan.

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The authors have no relevant financial or non-financial interests to disclose.

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Lu, H., Feng, R., Wang, P. et al. Ionic liquid-based quasi-solid-state electrolyte for supercapacitor application. J Mater Sci: Mater Electron 33, 16828–16836 (2022). https://doi.org/10.1007/s10854-022-08553-7

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  • DOI: https://doi.org/10.1007/s10854-022-08553-7

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