Abstract
Four different kinds of carbon materials were synthesized successfully from saussurea involucrata, cotton stalk and cellulose by two activation methods (KOH-chemical activation method and mixed molten-salt synthesis). Carbon structures, electrochemical and flexible properties are studied. The saussurea involucrata-based flexible symmetric all-solid states supercapacitor exhibited high electrochemical performances, including high specific capacitance (129 F g−1 at 2 mV s−1) and excellent cycle stability (∼ 85% capacitance retention even after 10,000 cycles). More importantly, it also displays excellent bending endurance, the specific capacitance is almost unchanged after 100 bends. This study shows promising materials in symmetric all-solid state supercapacitor applications.
Similar content being viewed by others
Data availability
The datasets generated during and analyzed during the current study are available from the corresponding author on reasonable request.
References
X. Zhang, F. Tian, X. Lan, Y. Liu, W. Yang, J. Zhang et al., Building P-doped MoS2/g-C3N4 layered heterojunction with a dual-internal electric field for efficient photocatalytic sterilization. Chem. Eng. J. 429, 132588 (2022)
S. Bao, Y. Wang, Z. Wei, W. Yang, Y. Yu, Highly efficient recovery of heavy rare earth elements by using an amino-functionalized magnetic graphene oxide with acid and base resistance. J. Hazard. Mater. 424, 127370 (2022)
X. Zhang, W. Yang, M. Gao, H. Liu, K. Li, Y. Yu, Room-temperature solid phase surface engineering of BiOI sheets stacking g-C3N4 boosts photocatalytic reduction of Cr(VI). Green Energy Environ. 7(1), 66–74 (2022)
X. Zhang, F. Tian, M. Gao, W. Yang, Y. Yu, L-Cysteine capped Mo2C/Zn0.67Cd0.33S heterojunction with intimate covalent bonds enables efficient and stable H2-Releasing photocatalysis. Chem. Eng. J. 428, 132628 (2022)
Y. Yang, A mini-review: emerging all-solid-state energy storage electrode materials for flexible devices. Nanoscale 12(6), 3560–3573 (2020)
P. Zhang, F. Wang, S. Yang, G. Wang, M. Yu, X. Feng, Flexible in-plane micro-supercapacitors: progresses and challenges in fabrication and applications. Energy Stor. Mater. 28, 160–187 (2020)
C.B. Guilherme, A.C. Rodrigues, A. Cuña, P.A. Claudia, B.M. Ribeiro, Process of converting human hair into hollow carbon filament for electrochemical capacitor. Matéria. 26 (2021).
J. Zhou, S. Yuan, C. Lu, M. Yang, Y. Song, Hierarchical porous carbon microtubes derived from corn silks for supercapacitors electrode materials. J. Electroanal. Chem. 878, 114704 (2020)
J. Wang, X. Zhang, Z. Li, Y. Ma, L. Ma, Recent progress of biomass-derived carbon materials for supercapacitors. J. Power Sources. 451, 227794 (2020)
X. Liang, R. Liu, X. Wu, Biomass waste derived functionalized hierarchical porous carbon with high gravimetric and volumetric capacitances for supercapacitors. Microporous Mesoporous Mater. 310, 110659 (2021)
K. Chaitra, R.T. Vinny, P. Sivaraman, N. Reddy, C.Y. Hu, K. Venkatesh et al., KOH activated carbon derived from biomass-banana fibers as an efficient negative electrode in high performance asymmetric supercapacitor. J Energy Chem. 26(1), 56–62 (2017)
D. Yu, Y. Ma, M. Chen, X. Dong, KOH activation of wax gourd-derived carbon materials with high porosity and heteroatom content for aqueous or all-solid-state supercapacitors. J. Colloid Interface Sci. 537, 569–578 (2019)
K. Chen, S. Weng, J. Lu, J. Gu, G. Chen, O. Hu et al., Facile synthesis of chitosan derived heteroatoms-doped hierarchical porous carbon for supercapacitors. Microporous Mesoporous Mater. 320, 111106 (2021)
H. Yang, J. Zhou, M. Wang, S. Wu, W. Yang, H. Wang, From basil seed to flexible supercapacitors: green synthesis of heteroatom-enriched porous carbon by self-gelation strategy. Int. J. Energy Res. 44(6), 4449–4463 (2020)
P.-A. Le, V.-T. Nguyen, S.K. Sahoo, T.Y. Tseng, K.-H. Wei, Porous carbon materials derived from areca palm leaves for high performance symmetrical solid-state supercapacitors. J. Mater. Sci. 55(24), 10751–10764 (2020)
W. Chen, X. Wang, C. Liu, M. Luo, P. Yang, X. Zhou, Rapid single-step synthesis of porous carbon from an agricultural waste for energy storage application. Waste Manag. 102, 330–339 (2020)
T. Ma, X. Zhang, Y. Wang, Tassel tree flowers-derived hierarchically porous carbons with high surface area for high-performance flexible all-solid-state symmetric supercapacitors. J Energy Storage. 26, 101014 (2019)
D. Yu, Y. Ma, M. Chen, X. Dong, KOH activation of wax gourd-derived carbon materials with high porosity and heteroatom content for aqueous or all-solid-state supercapacitors. J. Colloid Interface Sci. 537, 569–578 (2018)
Y. Mao, N.S. Kumar, A. Dhar, A.M. Poulose, R.L. Vekariya, Economic designing of high-performance flexible supercapacitor based on cotton leaf derived porous carbon and natural ocean water. J Energy Storage. 40(47), 102784 (2021)
X. Tian, H. Ma, Z. Li, S. Yan, L. Ma, F. Yu et al., Flute type micropores activated carbon from cotton stalk for high performance supercapacitors. J. Power Sources. 359, 88–96 (2017)
X. Kang, C. Wang, J. Yin, Hierarchically porous carbons derived from cotton stalks for high-performance supercapacitors. ChemElectroChem 4(10), 2599–2607 (2017)
X. Tian, S. Zhu, J. Peng, Y. Zuo, G. Wang, X. Guo et al., Synthesis of micro- and meso-porous carbon derived from cellulose as an electrode material for supercapacitors. Electrochim. Acta. 241, 170–178 (2017)
Z. Chen, X. Peng, X. Zhang, S. Jing, L. Zhong, R. Sun, Facile synthesis of cellulose-based carbon with tunable N content for potential supercapacitor application. Carbohydr. Polym. 170, 107–116 (2017)
X. Zhang, Z. Li, X. Tian, Y. Ma, L. Ma, Highly ordered micropores activated carbon from long fiber biomass for high energy density supercapacitors. ChemistrySelect 6(45), 13015–13023 (2021)
X.J. Wei, Y.B. Li, S.Y. Gao, Biomass-derived interconnected carbon nanoring electrochemical capacitors with high performance in both strongly acidic and alkaline electrolytes. J. Mater. Chem. A 5(1), 181–188 (2017)
C.J. Wang, D.P. Wu, H.J. Wang, Z.Y. Gao, F. Xu, K. Jiang, Nitrogen-doped two-dimensional porous carbon sheets derived from clover biomass for high performance supercapacitors. J Power Sources. 363, 375–383 (2017)
S. Liu, J. Xu, J. Zhu, Y. Chang, H. Wang, Z. Liu et al., Leaf-inspired interwoven carbon nanosheet/nanotube homostructures for supercapacitors with high energy and power densities. J. Mater. Chem. A. 5(37), 19997–20004 (2017)
V. Veeramani, M. Sivakumar, S.M. Chen, R. Madhu, H.R. Alamri, Z.A. Alothman et al., Lignocellulosic biomass-derived, graphene sheet-like porous activated carbon for electrochemical supercapacitor and catechin sensing. Rsc Adv. 7(72), 45668–45675 (2017)
A.A. Mohammed, C. Chen, Z. Zhu, Low-cost, high-performance supercapacitor based on activated carbon electrode materials derived from baobab fruit shells. J Colloid Interface Sci. 538, 308–319 (2019)
X.Y. Chen, C. Chen, Z.J. Zhang, D.H. Xie, Gelatin-derived nitrogen-doped porous carbon via a dual-template carbonization method for high performance supercapacitors. J. Mater. Chem. A 1(36), 10903–10911 (2013)
S. Liu, Y. Xu, J. Wu, J. Huang, Celery-derived porous carbon materials for superior performance supercapacitors. Nanoscale Adv. 3(18), 5363–5372 (2021)
N. Zhao, P. Zhang, D. Luo, W. Xiao, L. Deng, F. Qiao, Direct production of porous carbon nanosheets/particle composites from wasted litchi shell for supercapacitors. J. Alloys Compd. 788, 677–684 (2019)
G. Lin, Q. Wang, X. Yang, Z. Cai, Y. Xiong, B. Huang, Preparation of phosphorus-doped porous carbon for high performance supercapacitors by one-step carbonization. RSC Adv. 10(30), 17768–17776 (2020)
Y.W. Zhu, S. Murali, M.D. Stoller, K.J. Ganesh, W.W. Cai, P.J. Ferreira et al., Carbon-based supercapacitors produced by activation of graphene. Science 332(6037), 1537–1541 (2011)
G. Gou, F. Huang, M. Jiang, J. Li, Z. Zhou, Hierarchical porous carbon electrode materials for supercapacitor developed from wheat straw cellulosic foam. Renew. Energ. 149, 208–216 (2020)
J. Zhu, D. Xu, C. Wang, W. Qian, J. Guo, F. Yan, Ferric citrate-derived N-doped hierarchical porous carbons for oxygen reduction reaction and electrochemical supercapacitors. Carbon 115, 1–10 (2017)
W. Lu, X. Cao, L. Hao, Y. Zhou, Y. Wang, Activated carbon derived from pitaya peel for supercapacitor applications with high capacitance performance. Mater. Lett. 264, 127339 (2020)
F.R.M.S. Raj, N.V. Jaya, G. Boopathi, D. Kalpana, A. Pandurangan, S-doped activated mesoporous carbon derived from the Borassus flabellifer flower as active electrodes for supercapacitors. Mater. Chem. Phys. 240, 122151 (2020)
J. Song, S. Guo, D. Ren, H. Liu, L. Kou, J. Su et al., Rice husk-derived SiOx@carbon nanocomposites as a high-performance bifunctional electrode for rechargeable batteries. Ceram. Int. 46(8), 11570–11576 (2020)
S. Sankar, A.T.A. Ahmed, A.I. Inamdar, H. Im, Biomass-derived ultrathin mesoporous graphitic carbon nanoflakes as stable electrode material for high-performance supercapacitors. Mater. Des. 169, 107688 (2019)
Z. Shang, X. An, H. Zhang, M. Shen, F. Baker, Y. Liu et al., Houttuynia-derived nitrogen-doped hierarchically porous carbon for high-performance supercapacitor. Carbon 161, 62–70 (2020)
M. Shanmuga Priya, P. Divya, R. Rajalakshmi, A review status on characterization and electrochemical behaviour of biomass derived carbon materials for energy storage supercapacitors. Sustain. Chem. Pharm. 16, 100243 (2020)
J. Wang, Z. Li, S. Yan, X. Yu, Y. Ma, L. Ma, Modifying the microstructure of algae-based active carbon and modelling supercapacitors using artificial neural networks. RSC Adv. 9(26), 14797–14808 (2019)
J.C. Wang, S. Kaskel, KOH activation of carbon-based materials for energy storage. J. Mater. Chem. 22(45), 23710–23725 (2012)
C. Casiraghi, A. Hartschuh, H. Qian, S. Piscanec, C. Georgi, A. Fasoli et al., Raman spectroscopy of graphene edges. Nano Lett. 9(4), 1433–1441 (2009)
G.L. Sun, B. Li, J.B. Ran, X.Y. Shen, H. Tong, Three-dimensional hierarchical porous carbon/graphene composites derived from graphene oxide-chitosan hydrogels for high performance supercapacitors. Electrochim. Acta. 171, 13–22 (2015)
T. Purkait, G. Singh, M. Singh, D. Kumar, R.S. Dey, Large area few-layer graphene with scalable preparation from waste biomass for high-performance supercapacitor. Sci Rep. 7, 15239 (2017)
L. Yang, J. Wang, S. Wang, X. Guan, X. Guan, G. Wang, Biomass-derived multi-heteroatom-doped carbon materials for high-performance solid-state symmetric supercapacitors with superior long-term cycling stability. Ionics 26(8), 4141–4151 (2020)
H.Y. Chung, G.T. Pan, Z.Y. Hong, C.T. Hsu, C.M. Huang, Biomass-derived porous carbons derived from soybean residues for high performance solid state supercapacitors. Molecules 25(18), 4050 (2020)
J. Tian, T. Zhang, D. Talifu, A. Abulizi, Y. Ji, Porous carbon materials derived from waste cotton stalk with ultra-high surface area for high performance supercapacitors. Mater. Res. Bull. 143, 111457 (2021)
F. Yu, Z. Ye, W. Chen, Q. Wang, H. Wang, H. Zhang et al., Plane tree bark-derived mesopore-dominant hierarchical carbon for high-voltage supercapacitors. Appl. Surf. Sci. 507, 145190 (2020)
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (No. 11774255) and the National Key R&D Program of China (No. 2020YFC2004602).
Funding
Funding was provided by National Natural Science Foundation of China (11774255) and National Key R&D Program of China (973 Program) (2020YFC2004602).
Author information
Authors and Affiliations
Contributions
All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by XZ, MZ, YM and LM. The first draft of the manuscript was written by XZ, MZ and YM. ZC, TY and JL do the test of SEM. All authors read and approved the final manuscript. The whole manuscript was instructed by YM and LM.
Corresponding authors
Ethics declarations
Conflict of interest
The work described was original research that has not been published previously, and not under consideration for publication elsewhere, in whole or in part. The authors have no relevant financial interests to disclose.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Zhang, X., Zhao, M., Chen, Z. et al. The application of biomass-based carbon materials in flexible all-solid supercapacitors. J Mater Sci: Mater Electron 33, 15422–15432 (2022). https://doi.org/10.1007/s10854-022-08449-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-022-08449-6