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Influence of carboxylic acids on structural, optical, thermal, and electrical properties of ferroelectric glycine phosphite single crystals

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Abstract

Glycine phosphite (GPI), a semi-organic nonlinear optical NLO material, has been synthesized at room temperature. Slow evaporation method has been adopted to grow the single crystals of GPI and acetic acid, benzoic acid, formic acid, oxalic acid, and succinic acid-doped GPI crystals. The synthesized crystals are exposed to x-ray diffraction XRD, Fourier transform infrared (FTIR), and differential scanning calorimetry analysis DSC. The effects of doping on the structural parameters are analyzed. All the functional groups are identified by the corresponding peaks in the FTIR spectra. The UV–Vis spectrum shows that the materials have good optical transparency. The energy band gap values are found to be in the range of 5.1–5.4 eV for all the crystals. The mechanical stability of the grown crystals changes with different doping acids. The thermal studies were also affected by the addition of doping acids to the GPI crystal. Growth patterns and defect formation were studied by means of chemical etching. The dielectric constant and loss were evaluated from 300 to 410 K. It confirms that the dielectric constant value of GPI is higher than the acid-doped crystals.

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The datasets generated during and/or analyzed during the current study are available from the corresponding author on request.

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Acknowledgements

The authors express their gratitude to Princess Nourah bint Abdulrahman University Researchers Supporting Project (Grant No. PNURSP2022R61), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia. One of the authors SSS is grateful to the Department of Science and Technology, New Delhi, India, for the financial assistant thorough DST-WOS-A project (SR/WOS-A/PM/109/2016).

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Authors and Affiliations

  1. Department of Physics, PSGR Krishnammal College for Women, Coimbatore, 641004, India

    S. Shanmuga Sundari & P. Meena

  2. Department of Chemistry, PSGR Krishnammal College for Women, Coimbatore, 641004, India

    N. Arunadevi & P. Kanchana

  3. Department of Physics, KPR Institute of Engineering and Technology, Coimbatore, Tamil Nadu, India

    E. Ranjith Kumar

  4. Plant Production Department, College of Food and Agriculture Sciences, King Saud University, Riyadh, 11451, Saudi Arabia

    Hosam O. Elansary

  5. Department of Food Industries, Faculty of Agriculture, Damietta University, Damietta, Egypt

    Eman A. Mahmoud

  6. Department of Physics, Faculty of Science, Princess Nourah bint Abdulrahman University, P.O.Box 84428, 11681, Riyadh, Saudi Arabia

    Shaimaa A. M. Abdelmohsen

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  1. S. Shanmuga Sundari
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  2. N. Arunadevi
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  3. P. Kanchana
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  4. P. Meena
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  5. E. Ranjith Kumar
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  7. Eman A. Mahmoud
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  8. Shaimaa A. M. Abdelmohsen
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All the authors of the current manuscript contributed equally.

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Correspondence to E. Ranjith Kumar.

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Sundari, S.S., Arunadevi, N., Kanchana, P. et al. Influence of carboxylic acids on structural, optical, thermal, and electrical properties of ferroelectric glycine phosphite single crystals. J Mater Sci: Mater Electron 33, 17421–17433 (2022). https://doi.org/10.1007/s10854-022-08443-y

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