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Enhanced near-ambient temperature energy storage and electrocaloric effect in the lead-free BaTi0.89Sn0.11O3 ceramic synthesized by sol–gel method

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Abstract

Lead-free perovskite materials with high performance have high potential in clean energy storage applications and developments of electrocaloric devices. This work reports structural, dielectric, ferroelectric, energy storage, and electrocaloric properties near the ambient temperature in barium stannate titanate (BaTi0.89Sn0.11O3, BTS11) ceramic prepared by a sol–gel method. A single perovskite structure formation was confirmed using the X-ray diffraction analysis. Average grain size of 18.5 µm was found by the mean of the SEM micrograph with a density of 5.91 g/cm3. The multiphase coexistence at very near ambient temperature was proved using temperature-dependent micro-Raman measurements and differential scanning calorimetry. The BTS11 ceramic exhibits a high dielectric constant of 15,460 and a low dielectric loss (< 0.055) in a broad temperature range. Moreover, a high energy storage density of 122 mJ/cm3 was shown with an efficiency of 79%, a maximum value of electrocaloric temperature change (ΔT) of 0.86 K, and finally, an electrocaloric responsivity (ΔT/ΔE) of 0.24 K.mm/kV at the external electric field change of 35 kV/cm near ambient temperature. The enhanced dielectric, ferroelectric, and electrocaloric properties make BTS11 ceramics a great candidate for solid-state cooling technology and high energy storage applications near ambient temperature.

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Acknowledgements

The authors gratefully acknowledge the generous financial support of the European Union Horizon 2020 Research and Innovation actions MSCA-RISE-ENGIMA (No. 778072) and MSCA-RISE-MELON (No. 872631) and ARRS project J1-9147 and program P1-0125 and CNRST Priority Program PPR 15/2015 and the ministry of Science and Higher Education of the Russian Federation, grant agreement No 075-15-2021-953.

Funding

This work was supported by CNRST Priority Program PPR 15/2015, by the European Union's Horizon 2020 research and Innovation actions MSCA-RISE-ENGIMA (No. 778072) and MSCA-RISEMELON (No. 872631) and ARRS project J1-9147, and by the Ministry of Science and Higher Education of the Russian Federation, grant agreement No 075–15-2021–953.

Author information

Authors and Affiliations

  1. IMED-Lab, FST, Cadi-Ayyad University, Marrakech, Morocco

    Marwa Zahid, Youness Hadouch, M’barek Amjoud, Daoud Mezzane & Abdelhadi Alimoussa

  2. LPMC, University of Picardie Jules Verne, Amiens, France

    Youness Hadouch & Daoud Mezzane

  3. ICMCB, University of Bordeaux, 33600, Pessac, France

    Mohamed Gouné

  4. IM2NP, Aix Marseille University, 13397, Marseille, France

    Khalid Hoummada

  5. Faculty of Physics, Southern Federal University, Rostov-on-Don, 344090, Russia

    Anna G. Razumnaya

  6. Jožef Stefan Institute, JamovaCesta 39, 1000, Ljubljana, Slovenia

    Brigita Rožič & Zdravko Kutnjak

Authors
  1. Marwa Zahid
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  2. Youness Hadouch
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  3. M’barek Amjoud
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Contributions

MZ: Conceptualization, Formal Analysis, Investigation, Data curation, Methodology, and Writing—original draft. YH: Conceptualization, Investigation, Data curation, and Methodology. MA: Supervision, Writing—review & editing. DM: Project administration, Supervision, and Funding acquisition. MG: Supervising, Validation, Funding acquisition, Writing—review & editing. KH: Data curation, Validation, and Review & editing. AA: Validation, Data curation, and review & editing. AGR: Investigation, Data curation, and review & editing. BR: Resources, Validation, and Writing—review & editing. ZK: Project administration, Resources, Validation, Funding acquisition, and Writing—review & editing.

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Correspondence to Marwa Zahid.

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Relevance summary

In the submitted manuscript, the successful synthesis of barium stannate titanate ceramics by sol–gel method and the study of their structural, dielectric, ferroelectric, energy storage, and electrocaloric properties are reported. In addition, we confirm that this work is original and has not been published elsewhere, nor it is currently under consideration for publication elsewhere.

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Zahid, M., Hadouch, Y., Amjoud, M. et al. Enhanced near-ambient temperature energy storage and electrocaloric effect in the lead-free BaTi0.89Sn0.11O3 ceramic synthesized by sol–gel method. J Mater Sci: Mater Electron 33, 12900–12911 (2022). https://doi.org/10.1007/s10854-022-08233-6

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