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Nanoarchitectonics of hierarchical PbS material for all-solid-state asymmetric supercapacitor

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Abstract

Present article reports morphology controlled synthesis of lead sulfide (PbS) thin films using cost-effective chemical method. The structural, morphological, and electrochemical studies of the samples were carried out. Rock-salt phase cubic structure formation is affirmed by XRD analysis. SEM micrograph describes the evolution of an exotic, anisotropic, 3D hierarchical dendritic architecture into microflowers as a function of reaction time. The optimized sample shows specific capacitance of 360 F g−1 at a scan rate of 5 mV s−1. The all-solid-state asymmetric PbS//MnO2 supercapacitor device shows cycling stability of 71% over 1000 cycles highlights the significance of hierarchical PbS nanostructures in supercapacitors.

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All data generated or analyzed during this study are included in this published article (and its supplementary information files).

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Acknowledgements

All the authors are thankful to Physics Instrumentation Facility Centre (PIFC), Department of Physics, Shivaji University, Kolhapur for providing sample characterization facilities.

Funding

The authors have not disclosed any funding.

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Author notes

  1. T. S. Bhat and A. V. Shinde have contributed equally to this work.

Authors and Affiliations

  1. Thin Film Materials Laboratory, Department of Physics, Shivaji University, Kolhapur, 416 004, Maharashtra, India

    T. S. Bhat, A. A. Alat & P. S. Patil

  2. School of Nanoscience and Biotechnology, Shivaji University, Kolhapur, 416 004, India

    T. S. Bhat

  3. Department of Physics, Vivekanand College, Kolhapur, 416004, Maharashtra, India

    A. V. Shinde

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  1. T. S. Bhat
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Contributions

Conceptualization: TSB. Methodology: AAA. Formal analysis and investigation: TSB, AVS. Writing—original draft preparation: TSB. Writing—review and editing: TSB, AVS. Funding acquisition: PSP. Resources: PSP. Supervision: PSP.

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Correspondence to P. S. Patil.

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Bhat, T.S., Shinde, A.V., Alat, A.A. et al. Nanoarchitectonics of hierarchical PbS material for all-solid-state asymmetric supercapacitor. J Mater Sci: Mater Electron 33, 10368–10378 (2022). https://doi.org/10.1007/s10854-022-08024-z

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  • DOI: https://doi.org/10.1007/s10854-022-08024-z

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