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Investigation of PTFE-based ultra-low dielectric constant composite substrates with hollow silica ceramics

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Abstract

Polytetrafluoroethylene was composited with low dielectric constant hollow SiO2 powders to obtain an ultra-low dielectric constant high-frequency microwave composite substrate. The analysis of XPS, contact angle testing, and SEM observation were conducted to study the surface characteristics of phenyltrimethoxysilane (Z6124)-modified hollow silica and 1 H,1 H,2 H,2 H-perfluorooctyltriethoxysilane (F8261)-modified hollow silica. The content of hollow silica ranged from 35 to 55 vol% and the effects of hollow silica filling content on water absorption, morphology, and dielectric properties were investigated in detail. The composite material with 45 vol% hollow SiO2 modified by 5 wt.% Z6124 performed excellent dielectric properties of ultra-low dielectric constant (1.94) and low dielectric loss (0.0019) at a high frequency of 10 GHz. Moreover, it also has acceptable water absorption (0.19%) and well coefficient of thermal expansion (CTE ~ 55.5 ppm/°C). The ultra-low dielectric constant composite is beneficial to improve signal transmission speed, which is potential for microwave substrates application.

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The data presented in this study are available on request from the corresponding author.

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Acknowledgements

The authors would like to thank Southwest University of Science and Technology (Mianyang, Sichuan, People’s Republic of China) for their assistance and support in material testing in this work.

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Authors and Affiliations

  1. National Engineering Center of Electromagnetic Radiation Control Materials, University of Electronic Science and Technology of China, Xiyuan Road, Chengdu, 611731, People’s Republic of China

    Yunxin Wang, Zhengyi Yang, Hanyu Wang, Enzhu Li & Ying Yuan

  2. State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Xiyuan Road, Chengdu, 611731, People’s Republic of China

    Yunxin Wang, Zhengyi Yang, Hanyu Wang, Enzhu Li & Ying Yuan

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  1. Yunxin Wang
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  2. Zhengyi Yang
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  5. Ying Yuan
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Contributions

YW and YY participated in the conceptualization; Data curation: YW; Formal analysis: YW; Methodology: YW, ZY, HW, EL, and YY; Project administration: YY; Supervision: YY; Writing—original draft: YW and HW; Writing—review and editing: ZY and YY. All authors read and approved the final manuscript.

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Correspondence to Ying Yuan.

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Wang, Y., Yang, Z., Wang, H. et al. Investigation of PTFE-based ultra-low dielectric constant composite substrates with hollow silica ceramics. J Mater Sci: Mater Electron 33, 4550–4558 (2022). https://doi.org/10.1007/s10854-021-07646-z

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  • DOI: https://doi.org/10.1007/s10854-021-07646-z

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